Films of polypropylene blends and polyethylene blends and articles made therewith

• US 5,071,686 A
• Filed: 11/29/1985
• Issued: 12/10/1991
• Est. Priority Date: 11/29/1985
• Status: Expired due to Term

• Current Assignee: Pechiney Plastic Packaging Incorporated (Rio Tinto Limited)
• Original Assignee: Baxter International Inc.
• Inventors: Czuba, Leonard F., Gehrke, Russell P., Webster, R. Daniel, Johnson, Richard E. Jr., Genske, Roger P., Kim, Yong J.
• Primary Examiner(s): ROBINSON, ELLIS P
• Application Number:
  US06/802,908
• Time in Patent Office: 2,202 Days
• Field of Search: 428/516, 428/213, 428/35.7, 428/349, 525/240
• US Class Current: 428/35.7
• CPC Class Codes: B32B 2309/02 Temperature
• CPC Class Codes: B32B 2323/04 Polyethylene
• CPC Class Codes: B32B 2323/043 HDPE, i.e. high density polyethylene
• CPC Class Codes: B32B 2323/10 Polypropylene
• CPC Class Codes: B32B 2439/00 Containers; Receptacles
• CPC Class Codes: B32B 2439/80 Medical packaging
• CPC Class Codes: B32B 2553/00 Packaging equipment or accessories not otherwise provided for
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 23/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 23/12 Polypropene
• CPC Class Codes: C08L 23/14 Copolymers of propene C08L23/16 takes precedence
• CPC Class Codes: C08L 23/142 at least partially crystalline copolymers of propene with other olefins
• CPC Class Codes: C08L 23/16 Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
• CPC Class Codes: C08L 23/20 having four to nine carbon atoms
• CPC Class Codes: C08L 23/22 Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/06 : Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
• CPC Class Codes: C08L 2666/24 : Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 53/02 : of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: Y10T 428/1352 : Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/2495 : Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/2809 : including irradiated or wave energy treated component
• CPC Class Codes: Y10T 428/31913 : Monoolefin polymer

Abstract

Novel films are disclosed which contain blends of ethylene-based copolymers or other elastomers with polypropylene and polyethylene. Typical films have two-five layers wherein at least one layer is a blend of high density polyethylene with an ethylene-based copolymer or another elastomer and has additional layers of polypropylene blended with an ethylene-based copolymer or another elastomer.

Claims

1. A multiple layer film, comprising:

(a) first and third layers each of said first and third layers comprising compositions of (i) polypropylene polymer chosen from the group consisting of polypropylene homopolymer and polypropylene copolymer and (ii), as a second component, a polymer composition chosen from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers; and

(b) a second layer, the composition of said second layer comprising polyethylene;

said second layer being between said first and third layers.

2. A multiple layer film as in claim 1, wherein the composition of each of said first and third layers is about 20% by weight to about 95% by weight polypropylene and about 80% by weight to about 5% by weight of said second component.

3. A multiple layer film as in claim 1, wherein said polyethylene in said second layer is high density polyethylene and wherein the composition of said second layer further comprises a second component, said second component being chosen from the group consisting of ethylene butene-1 copolymer and ethylene propylene copolymer.

4. A multiple layer film as in claim 1, and wherein the composition of said second layer is about 65% by weight to about 95% by weight of said polyethylene and about 35% by weight to about 5% by weight of a second component selected from the group consisting of ethylene butene-1 copolymer and ethylene propylene copolymer.

5. A multiple layer film as in claim 4 wherein said polyethylene in said second layer is high density polyethylene.

6. A multiple layer film as in claim 1, wherein the composition of said second layer comprises a second component selected from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers.

7. A multiple layer film as in claim 1, wherein the composition of each of said first and third layers is about 45% by weight to about 65% by weight polypropylene and about 55% to about 35% by weight of said second component, and wherein the composition of said second layer is about 65% by weight to about 95% by weight of said polyethylene and about 35% by weight to about 5% by weight of a second component selected from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers.

8. A multiple layer film as in claim 1, and including a second component in said second layer, said second component being selected from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers, and wherein the composition of said second component in each of said first and third layers is essentially the same as the composition of said second component in said second layer.

9. A multiple layer film as in claim 1, and wherein a fourth layer is adhered to said third layer, the composition of said fourth layer comprising polyethylene.

10. A multiple layer film of claim 9 or 21 wherein a fifth layer is adhered to said fourth layer, the composition of said fifth layer comprising polypropylene.

11. A multiple layer film of claim 9 or 10 wherein said second and fourth layers comprise high density polyethylene.

12. A multiple layer film as in any one of claims 3-7, 21 or 22 wherein the corresponding second components in adjacent layers are different materials.

13. A multiple layer film of any one of claims 1-10, or 21-34, said film being coextruded.

14. A package made with a film of any one of claims 1-10, or 21-34.

15. A package made with a film of claim 13, said package having been exposed to retort conditions of at least about 250°

F. for a period of at least about 10 minutes.

16. A flexible container capable of housing a medical product to be maintained and extracted under sterile conditions, said container having been made with a film of any one of claims 1-10, or 21-34.

17. A multiple layer film of any one of claims 1-9 wherein said first layer comprises approximately 60% of the total thickness of said film.

18. A multiple layer film of claim 9 or 10 wherein said first layer comprises approximately 60% of the total thickness of said multiple layer film.

19. A multiple layer film of any of claims 1-8 wherein said second layer comprises approximately 20% of the total thickness of said film.

20. A multiple layer film of any one of claims 1-8 wherein said third layer comprises approximately 20% of the total thickness of said film.

21. A multiple layer film as in claim 9, the composition of said second layer comprising, as a second component, a composition providing elastomeric properties, and chosen from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers, and the composition of said fourth layer comprising, as a second component, a composition providing elastomeric properties, and chosen from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers.

22. A multiple layer film as in claim 10, the composition of said fifth layer comprising, as a second component, a composition providing elastomeric properties, and chosen from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers.

23. A multiple layer film comprising:

(a) a first layer, said first layer comprising a composition of (i) polypropylene polymer chosen from the group consisting of polypropylene homopolymer and polypropylene copolymer and (ii), as a second component, a polymer composition chosen from the group consisting of ethylene butene-1 copolymer and ethylene propylene copolymer;

(b) a second layer, the composition of said second layer comprising a polyethylene; and

(c) a third layer, the composition of said third layer comprising a polypropylene composition,

said second layer being disposed between said first and third layers.

24. A multiple layer film as in claim 23 wherein the composition of said second layer is about 65% by weight to about 95% by weight of said polyethylene and about 35% by weight to about 5% by weight of a second component providing elastomeric properties.

25. A multiple layer film as in claim 23 or 24 wherein said polyethylene in said second layer is high density polyethylene.

26. A multiple layer film as in claim 24 wherein the composition of said second component in said second layer is selected from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers.

27. A multiple layer film as in claim 23 wherein a fourth layer is adhered to said first layer, the composition of said fourth layer comprising polyethylene.

28. A multiple layer film as in claim 27 wherein a fifth layer is adhered to said fourth layer, the composition of said fifth layer comprising polypropylene.

29. A multiple layer film comprising:

(a) a first layer comprising a polypropylene composition;

(b) a second layer, the composition of said second layer comprising (i) polyethylene polymer chosen from the group consisting of polyethylene homopolymer and polyethylene copolymer and (ii), as a second component, a polymer composition providing elastomeric properties; and

(c) a third layer comprising a polypropylene composition, said second layer being disposed between said first and third layers.

30. A multiple layer film as in claim 29 wherein the composition of said first layer is about 20% by weight to about 95% by weight polypropylene and about 80% by weight to about 5% by weight of a second component providing elastomeric properties.

31. A multiple layer film as in claim 29 wherein the composition of said third layer is about 20% by weight to about 95% by weight polypropylene and about 80% by weight to about 5% by weight of a second component providing elastomeric properties.

32. A multiple layer film as in any of claims 29-31 wherein said polyethylene in said second layer is high density polyethylene.

33. A multiple layer film as in claim 30 wherein the composition of said second component in said first layer is selected from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers.

34. A multiple layer film as in claim 30 wherein the composition of said second component in said third layer is selected from the group consisting of ethylene butene-1 copolymers and ethylene propylene copolymers.