Thermoplastic resin composition

• US 5,071,912 A
• Filed: 02/12/1990
• Issued: 12/10/1991
• Est. Priority Date: 03/26/1988
• Status: Expired due to Term

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Maruyama, Takashi, Furuta, Motonobu
• Primary Examiner(s): Ziegler, Jacob
• Application Number:
  US07/478,404
• Time in Patent Office: 666 Days
• Field of Search: 525/68, 525/905, 525/148, 525/152, 525/92
• US Class Current: 525/68
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 51/06 grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
• CPC Class Codes: C08L 59/00 Compositions of polyacetals; Compositions of derivatives of polyacetals of polyvinyl acetals C08L29/14
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• CPC Class Codes: C08L 71/123 not modified by chemical after-treatment
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 81/02 Polythioethers; Polythioether-ethers
• CPC Class Codes: C08L 81/06 Polysulfones; Polyethersulfones
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

Disclosed is a thermoplastic resin composition, comprising:

(a) a polyphenylene ether resin or a resin composition containing a polyphenylene ether,

(b) (i) a modified propylene polymer obtainable by grafting a propylene polymer with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with the styrene-based monomer or (ii) a composition containing said modified propylene polymer and a propylene polymer, and

(c) two or more rubbery substances, at least one rubbery substance being compatible with the component (a), and at least one rubbery substance being not compatible with the component (a). The thermoplastic resin composition has good moldability and yields molded articles having well-balanced physical properties.

Claims

1. A thermoplastic resin composition, comprising:

(a) a polyphenylene ether resin or a resin composition containing a polyphenylene ether,

(b) (i) a modified propylene polymer obtained by grafting a propylene polymer with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with the styrene-based monomer or (ii) a composition containing said modified propylene polymer and a propylene polymer, and

(c) two or more rubbery substances, at least one rubbery substance being compatible with the component (a), and at least one rubbery substance being not compatible with the component (a).

2. A thermoplastic resin composition as claimed in claim 1, wherein the proportion of the component (a) to the sum of the components (a) and (b) is 1 to 90% by weight, the proportion of the component (b) to the sum of the components (a) and (b) is 99 to 10% by weight, and the proportion of the component (c) to the sum of the components (a) and (b) is 1 to 50 parts by weight per 100 parts by weight of (a) plus (b).

3. A thermoplastic resin composition as claimed in claim 1, wherein said rubbery substances are composed of a rubbery substance which is compatible with the component (a) and have at least one alkenyl aromatic chain in the same molecule, and a rubbery substance which is not compatible with the component (a) and does not have alkenyl aromatic chain in the same molecule.

4. A thermoplastic resin composition as claimed in claim 1, wherein said, polyphenylene ether (a) is a polyphenylene ether obtained by oxidative polymerization of at least one phenol compound represented by the general formula (1) ##STR10## wherein R₁, R₂, R₃, R₄ and R₅, each independently represents a hydrogen atom, a halogen atom, a hydrocarbon group or a substituted hydrocarbon group, or a hydrocarbyloxy group or a substituted hydrocarbyloxy group, provided that at least one of R₁, R₂, R₃, R₄ and R₅ is a hydrogen atom.

6. A thermoplastic resin composition as claimed in claim 1, wherein said propylene polymer in the component (b) is a highly crystalline polypropylene which has an isotactic pentad fraction of 0.970 or higher, defined as an isotactic pentad fraction in a boiling heptane-insoluble portion of the propylene polymer.

7. A thermoplastic resin composition as claimed in claim 1, wherein said propylene polymer in the component (b) is a highly crystalline polypropylene which has an isotactic pentad fraction of 0.970 or higher, defined as an isotactic pentad fraction in a boiling heptane-insoluble portion of the propylene polymer, and a content of boiling heptane-soluble portion being not higher than 5.0% by weight and a content of a 20°

C. xylene-soluble portion being not higher than 2.0% by weight.

8. A thermoplastic resin composition as claimed in claim 1, wherein said propylene polymer in the component (b) is obtained by blending a propylene polymer with a vinyloycloalkane polymer having 6 or more carbon atoms and contains 0.05 to 10000 ppm by weight of vinylcycloalkane units.

9. A thermoplastic resin composition as claimed in claim 3, wherein said rubbery substance compatible with the component (a) and having at least one alkenyl aromatic chain in the same molecule is at least one rubber selected from the group consisting of styrene-butadiene copolymer, styrene-butadiene-styrene copolymer, styrene-ethylene-butylene-styrene copolymer, styrene-isoprene copolymer and styrene-ethylene-propylene copolymer.

10. A thermoplastic resin composition as claimed in claim 3, wherein said rubbery substance not compatible with the component (a) and not having alkenyl aromatic chain in the same molecule is an ethylene-α

-olefin copolymer rubber or a modified product thereof.

11. A thermoplastic resin composition as claimed in claim 10, wherein said ethylene-α

-olefin copolymer rubber is an ethylene-α

-olefin copolymer rubber which has an ethylene content of 15 to 85% by weight, a Mooney viscosity (ML₁₊₄, 121°

C.) of 5 to 120, and a glass transient point of not higher than -10°

C.

12. Molded articles which are made of the thermoplastic resin composition claimed in claim 1.

13. Automotive parts which are made of the thermoplastic resin composition claimed in claim 1.

14. Automotive parts as claimed in claim 10 which is selected from the group consisting of a bumper, instrument panel, fender, trim, door panel, wheel cap, side protector, side seal garnish, trunk lid, hood, quarter panel, air intake, lower apron, spoiler, front grille, radiator grille, mirror housing, air cleaner, core material of a seat, glove box, console box, cooling fan, sirocco fan, brake oil tank, lamp housing and roof.

5. A thermoplastic resin composition as claimed in claim I, wherein said monomer copolymerizable with the styrene-based monomer in the component (b) is at least one monomer selected from the group consisting of maleic anhydride, methyl methacrylate, glycidyl acrylate, glycidyl methacrylate, 2-aminoethyl methacrylate, and 2-hydroxyethyl methacrylate.