Process for the radioactive decontamination of an oil

• US 5,075,044 A
• Filed: 06/30/1987
• Issued: 12/24/1991
• Est. Priority Date: 07/07/1986
• Status: Expired due to Term

• Current Assignee: Electricitã© De France
• Original Assignee: Electricite de France Service International
• Inventors: Augem, Jean-Michel
• Primary Examiner(s): Locker, Howard J.
• Application Number:
  US07/068,354
• Time in Patent Office: 1,638 Days
• Field of Search: 252/628, 252/626, 252/635, 252/631, 405/128, 405/129, 210/679, 210/680, 210/688, 210/690, 210/682, 210/691, 210/908, 210/909, 210/912, 210/754, 208/252, 208/265, 208/281, 208/181, 208/183, 208/271, 208/275, 208/279, 208/310 Z, 208/266
• US Class Current: 588/9
• CPC Class Codes: G21F 9/12 by absorption; by adsorption; by ion-exchange
• CPC Class Codes: Y10S 210/912 Heavy metal

Abstract

According to the invention, the oil is passed through a pulverulent material, such as an earth or clay, in the presence of an acid. The pulverulent material can be placed beforehand on a filter or can be mixed with the oil before filtration. If necessary, the oil is recycled through the filter up to complete decontamination.

Application to the radioactive decontamination of oils used in the nuclear industry.

Claims

1. A process for the radioactive decontamination of an oil containing radioelements, comprising the steps of:

(a) mixing said oil with a pulverulent material in the presence of an acid selected from the group consisting of hydrochloric acid, phosphoric acid, and sulfuric acid to form a mixture thereof;

(b) passing the mixture through a filter able to retain at least part of the pulverulent material; and

(c) repeating step (b) the number of times necessary to obtain a decontaminated oil filtrate and separating said decontaminated oil filtrate from the pulverulent material together with said radioelements.

7. A process according to claim 1, 2, or 3, wherein the pulverulent material comprises diatomaceous earth or bentonite.

8. A process according to claim 1, 2, or 3, wherein the pulverulent material has a grain size below 0.5 mm.

9. A process according to claim 1, 2, or 3, wherein the pulverulent material is between 0.05 and 5% of the mass of the oil to be treated.

10. A process according to claim 1, 2, or 3, wherein the aqueous concentration of the acid used is equal to or above 70%.

11. A process according to claim 1, 2, or 3, wherein the oil is heated before passing it through the pulverulent material.

12. A process according to claim 1, 2, or 3, wherein said acid is an acid reagent added directly to the oil.

13. A process according to claim 1, 2, or 3, wherein said acid is an acid component of said pulverulent material.

14. A process according to claim 1, 2, or 3, wherein said radioelements are selected from the group consisting of xenon 133, manganese 54, cobalt 58, cobalt 60, niobium 95, iodine 131, cesium 134, cesium 137 and cerium 144.

15. A process according to claim 14, wherein the activity level of said radioelements present in the oil prior to decontamination is in the range of from about 3.7×

10⁶ Bq/m³ to about 3.7×

10⁴ Bq/m³.

2. A process for the radioactive decontamination of oil containing radioelements comprising the steps of:

(a) placing the pulverulent material on an upstream face of a filter for contact with said oil in the presence of an acid selected from the group consisting of hydrochloric acid, phosphoric acid, and sulfuric acid;

(b) passing the oil through said filter covered with the pulverulent material; and

(c) repeating step (b) the number of times necessary to obtain a decontaminated oil filtrate and separating said decontaminated oil filtrate from the pulverulent material together with said radioelements.

3. A process for the radioactive decontamination of an oil containing radioelements, comprising contacting said oil with a pulverulent material while reacting a portion of the oil with an acid to provide filterable reaction products including tars having radioelements fixed thereto, and filtering said oil to separate said pulverulent material, reaction products and any other filterable constituents present in the oil from a filtrate of decontaminated oil, said acid being selected from the group consisting of hydrochloric acid, phosphoric acid and sulfuric acid.

4. A process according to claim 3, wherein said other filterable constituents include particles in suspension in the oil which contain radioelements and particles precipitated by the acid in the oil which contains radioelements.

5. A process according to claim 4, wherein said oil is substantially free of water contaminants.

6. A process according to claim 5, including the step of heating the oil to remove water contaminants prior to the step of reacting a portion of the oil within the acid.