Aqueous coating composition based on specific two-component polyurethanes and to a process for its production

• US 5,075,370 A
• Filed: 08/18/1989
• Issued: 12/24/1991
• Est. Priority Date: 09/01/1988
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Gruber, Hermann, Probst, Joachim, Kubitza, Werner
• Primary Examiner(s): Kight, III, John
• Assistant Examiner(s): Sergent, Rabon
• Application Number:
  US07/395,849
• Time in Patent Office: 858 Days
• Field of Search: 524/591
• US Class Current: 524/591
• CPC Class Codes: C08G 18/0819 containing anionic or anionogenic groups
• CPC Class Codes: C08G 18/6229 Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
• CPC Class Codes: C08G 18/6254 Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
• CPC Class Codes: C08G 18/6287 Polymers of sulfur containing compounds having carbon-to-carbon double bonds
• CPC Class Codes: C08G 18/706 the liquid medium being water

Abstract

The present invention is directed to a two-component coating composition which contains as binder components

a) a polyol component containing at least one hydroxyl-containing polymer having chemically incorporated carboxylate and/or sulfonate groups and based on olefinically unsaturated compounds and

b) a polyisocyanate component having a viscosity at 23° C. of about 50 to 10,000 mPa.s and based on at least one organic polyisocyanate

in quantities corresponding to an NCO/OH equivalent ratio of about 0.5:1 to 5:1, characterized in that component a) is an aqueous solution and/or dispersion of a polymer containing hydroxyl groups in which the polyisocyanate component b) is present in emulsified form.

The present invention also relates to a process for the production of this coating composition which is characterized in that a polyisocyanate component having a viscosity at 23° C. of about 50 to 10,000 mPa.s and based on at least one organic polyisocyanate is emulsified in an aqueous solution or dispersion of one or more polymer resins containing hydroxyl groups and chemically incorporated sulfonate and/or carboxylate groups in a quantity which makes them soluble and/or dispersible in water, the quantitative ratios between the two components corresponding to an NCO/OH equivalent ratio, based on the isocyanate groups of the polyisocyanate component and the incorporated hydroxyl groups of the polymer component, of about 0.5:1 to 5:1.

Claims

1. A two-component coating composition wherein the binder components comprise

a) a polyol component comprising an aqueous solution and/or dispersion of at least one polyacrylate containing hydroxyl groups and prepared from olefinically unsaturated compounds, said polyacrylate containing chemically incorporated groups comprising a member selected from the group consisting of carboxylate groups, sulfonate groups and mixtures of carboxylate and sulfonate groups in a quantity which is sufficient to make said polyacrylate soluble and/or dispersible in water and

b) a polyisocyanate component containing free isocyanate groups and having a viscosity at 23°

C. of about 50 to 10,000 mPa.s and comprising at least one organic polyisocyanate,

wherein components a) and b) are present in quantities corresponding to an NCO;

OH equivalent ratio of 0.5;

1 to 5;

1 and component b) is present in emulsified form in component a).

2. The coating composition of claim 1 wherein said polyacrylate has an average molecular weight M_n of about 500 to 50,000, a hydroxyl value of 16.5 to 264 mg KOH/g of said polyacrylate, an acid value of 0 to 150 mg KOH/g of said polyacrylate and a content of said chemically incorporated groups of 5 to 417 milliequivalents per 100 g of said polyacrylate.

3. The coating composition of claim 2 wherein said polyisocyanate component exclusively contains aliphatically or cycloaliphatically bound isocyanate groups.

4. The coating composition of claim 1 wherein said polyisocyanate component exclusively contains aliphatically or cycloaliphatically bound isocyanate groups.

5. A process for the production of a two-component coating composition which comprises emulsifying

a) a polyisocyanate component containing free isocyanate groups and having a viscosity at 23°

C. of about 50 to 10,000 mPa.s and comprising at least one organic polyisocyanate

b) in a polyol component comprising an aqueous solution and/or dispersion of at least one polyacrylate containing hydroxyl groups and prepared from olefinically unsaturated compounds, said polyacrylate containing chemically incorporated groups comprising a member selected from the group consisting of carboxylate groups, sulfonate groups and mixtures of sulfonate and carboxylate groups in a quantity which is sufficient to make said polyacrylate soluble and/or dispersible in water,

wherein components a) and b) are present in quantities corresponding to an NCO;

OH equivalent ratio of 0.5;

1 to 5;

1.

6. The process of claim 5 wherein said polyacrylate has an average molecular weight M_n of about 500 to 50,000, a hydroxyl value of 16.5 to 264 mg KOH/g of said polyacrylate, an acid value of 0 to 150 mg KOH/g of said polyacrylate and a content of said chemically incorporated groups of 5 to 417 milliequivalents per 100 g of said polyacrylate.

7. The process of claim 6 wherein said polyisocyanate component exclusively contains aliphatically or cycloaliphatically bound isocyanate groups.

8. The process of claim 5 wherein said polyisocyanate component exclusively contains aliphatically or cycloaliphatically bound isocyanate groups.