Thermoplastic resin composition

• US 5,075,376 A
• Filed: 01/05/1990
• Issued: 12/24/1991
• Est. Priority Date: 01/12/1989
• Status: Expired due to Fees

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Maruyama, Takashi, Furuta, Motonobu, Hosoda, Satoru
• Primary Examiner(s): Ziegler, Jacob
• Application Number:
  US07/461,396
• Time in Patent Office: 718 Days
• Field of Search: 525/68, 525/92, 525/148, 525/152, 525/905
• US Class Current: 525/68
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 59/00 Compositions of polyacetals; Compositions of derivatives of polyacetals of polyvinyl acetals C08L29/14
• CPC Class Codes: C08L 61/06 of aldehydes with phenols
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• CPC Class Codes: C08L 71/123 not modified by chemical after-treatment
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 81/02 Polythioethers; Polythioether-ethers
• CPC Class Codes: C08L 81/06 Polysulfones; Polyethersulfones
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

Disclosed are thermoplastic resin compositions comprising:

(a) a polyphenylene ether resin or a resin composition containing a polyphenylene ether,

(b) (i) a modified propylene polymer obtainable by grafting a propylene polymer with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with the styrene-based monomer or (ii) a composition comtaining said modified propylene polymer and a propylene polymer, and

(c) a rubbery substance,

wherein the number mean particle size of the component (a) and (c) in the dispersion phase being from 0.01 to 20 μm, the proportion of the component (a) to the sum of the components (a) and (b) being 1 to 80% by weight, that of the component (b) to the sum of the components (a) and (b) being 99 to 20% by weight, and the proportion of the component (c) to the sum of the components (a) and (b) being 1 to 50 parts by weight per 100 parts by weight of (a) plus (b). The thermoplastic resin composition has good moldability and yields molded articles having well-balanced physical properties.

Claims

1. A thermoplastic resin composition, comprising:

(a) a polyphenylene ether resin or a resin composition containing a polyphenylene ether,

(b) (i) a modified propylene polymer obtained by grafting a propylene polymer with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with the styrene-based monomer or (ii) a composition containing said modified propylene polymer and a propylene polymer, and

(c) a rubbery substance, wherein the component (b) is in a state of matrix phase, and the components (a) and (c) each is in a state of dispersion phase.

2. A thermoplastic resin composition as claimed in claim 1, wherein each number mean particle size of the components (a) and (c) in the dispersion phase is from 0.01 to 2 μ

m.

3. A thermoplastic resin composition as claimed in claim 1, wherein the proportion of the component (a) to the sum of the components (a) and (b) is 1 to 80% by weight, that of the component (b) to the sum of the components (a) and (b) is 99 to 20% by weight, and the proportion of the component (c) to the sum of the components (a) and (b) is 1 to 50 parts by weight per 100 parts by weight of (a) plus (b).

4. A thermoplastic resin composition as claimed in claim 1, wherein said propylene polymer in the component (b) is a highly crystalline polypropylene which is a homopolymer of propylene, or a block copolymer of propylene containing a boiling heptane-insoluble portion having an isotactic pentad fraction of at least 0.970.

5. A thermoplastic resin composition as claimed in claim 1, wherein said propylene polymer in the component (b) is a highly crystalline polypropylene which is a homopolymer of propylene, or a block copolymer of propylene containing a boiling heptane-insoluble portion having an isotactic pentad fraction of at least 0.970 and a content of a boiling heptane-soluble portion being not higher than 5.0% by weight and a content of a 20°

C. xylene-soluble portion being not higher than 2.0% by weight.

6. A thermoplastic resin composition as claimed in claim 1, wherein said propylene polymer composition in the component (b) is a crystalline propylene polymer composition obtained by blending a propylene polymer with a polymer of a vinylcycloalkane having at least 6 carbon atoms, said composition containing 0.05 to 10,000 ppm by weight of a vinylcycloalkane unit.

7. A thermoplastic resin composition as claimed in claim 1, wherein said rubbery substance (c) is at least one rubber selected from the group consisting of ethylene-α

-olefin copolymer rubber or modified products thereof ethylene-α

-olefin-nonconjugated diene copolymer rubber or modified products thereof, butadiene styrene copolymer or hydrogenated products thereof, and epoxy group-containing copolymer.

8. A thermoplastic resin composition as claimed in claim 7, wherein said ethylene-α

-olefin copolymer rubber is an ethylene-α

-olefin copolymer rubber which has an ethylene content of 15 to 85% by weight, a Mooney viscosity (ML₁₊₄ 121°

C. of 5 to 120, and a glass transient point of not higher than -10°

C.

9. Molded articles which are made of the thermoplastic resin composition claimed in claim 1.

10. Automotive parts which are made of the thermoplastic resin composition claimed in claim 1.

11. Automotive parts as claimed in claim 10 which is selected from the group consisting of a bumper, instrument panel, fender, trim, door panel, wheel cap, side protector, side seal garnish, trunk lid, hood, quarter panel, air intake, lower apron, spoiler, front grille, radiator grille, mirror housing, air cleaner, core material of a seat, glove box, console box, cooling fan, sirocco fan, brake oil tank, lamp housing and roof.