Method and apparatus for remotely and portably measuring a gas of interest

• US 5,076,699 A
• Filed: 05/01/1989
• Issued: 12/31/1991
• Est. Priority Date: 05/01/1989
• Status: Expired due to Fees

• Current Assignee: Rosemount Analytical, Inc. (Emerson Electric Company)
• Original Assignee: Rosemount Analytical, Inc. (Emerson Electric Company)
• Inventors: Ryan, Frederick M., Gottlieb, Milton S.
• Primary Examiner(s): McGraw, Vincent P.
• Assistant Examiner(s): KEESEE, LACHARLES
• Application Number:
  US07/345,858
• Time in Patent Office: 974 Days
• Field of Search: 250/346, 250/354, 250/339, 250/351, 250/253, 250/343, 250/504 R, 250/493.1, 250/338.1, 250/338.5, 250/255, 356/352, 356/320, 356/309, 356/434, 356/437, 356/365, 372/18, 372/21, 372/32, 372/354, 370/1, 370/3
• US Class Current: 356/437
• CPC Class Codes: G01J 2003/2886 Investigating periodic spectrum
• CPC Class Codes: G01J 3/26 using multiple reflection, e.g. Fabry-Perot interferometer, variable interference filters
• CPC Class Codes: G01N 2021/3513 Open path with an instrumental source
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 2201/067 Electro-optic, magneto-optic, acousto-optic elements

Abstract

A remote gas measuring apparatus and method utilizes the optical absorption line characteristics to determine an amount of gas of interest as may exist in an area under study. The remote gas measuring apparatus includes a source of electromagnetic radiation that can be projected toward the area in question and a light collecting arrangement. The light signal received is coupled to a fast light switch modulator which modulates the light signal to a first frequency. A second modulating arrangement modulates the light signal to a second frequency and includes a birefringent etalon device having a periodic spacing equal to the periodicity of the absorption lines of the gas of interest. The second modulating means is further effective such that, when an electric field is applied thereto the transmission spectra associated with the light signal is shifted between spectra which coincide with the absorption lines and spectra which fall between the absorption lines. The light signal from the etalon device is then conditioned and input to a detector configuration which distinguishes between the light signal at the first frequency and the light signal at the second frequency in order to determine at least a quantity of the gas of interest.

Claims

1. An apparatus for rapid scanning of the concentration of a remote gas of interest using optical absorption line characteristics of such gas, said measuring apparatus comprising:

a broadband source of infrared radiation;

means for direction the broadband infrared radiation to a remote, reflection surface;

means for receiving a reflected portion of the infrared radiation, wherein the intensity of the reflected portion is subject to unpredictable change due to shifts in infrared radiation transmission direction crossing areas of varying concentration of the gas of interest and hitting reflective surfaces of differing albedo;

light modulator means optically coupled to said receiving means for modulating said reflected portion at a first frequency and outputting a modulated reflected portion;

means for modulating said modulated reflected portion at a second frequency related to the first frequency by an integral factor, said modulating means including a birefringent etalon device having a periodic spacing equal to the periodicity of the absorption lines of the gas of interest, said modulating mean further effective such that, with an electric filed applied thereto, the periodic transmission spectra of said birefringent etalon device is shifted between spectra which coincide with such absorption line characteristics and spectra which fall between such absorption line characteristics, and outputting a twice modulated reflected portion; and

means for distinguishing between said twice modulated reflected portion at such first frequency and at such second frequency and determining therefrom, at least a quantity of such gas of interest.

2. A remote gas measuring apparatus as set forth in claim 1 wherein said source of infrared radiation and said receiving means are contained within a hand held unit which can be manually operated such that infrared radiation can be projected in a scanning manner.

3. A remote gas measuring apparatus as set forth in claim 2 wherein said hand held unit is directed toward such area having a background surface against which such infrared radiation can be back reflected toward said receiving means.

4. A remote gas measuring apparatus as set forth in claim 1 wherein said light modulator means includes an input polarizer element and a second polarizer element which is oriented in the same direction of polarization as the input polarizer element.

5. A remote gas measuring apparatus as set forth in claim 4 wherein said light modulator means further includes an electro-optical modulator arrangement disposed between said input polarizer and said second polarizer elements and effective, upon the application of an electric field having associated therewith said first frequency, such that the polarization of said light signal is rotated to a different polarization which said second polarizer element blocks from passage therethrough.

6. A remote gas measuring apparatus as set forth in claim 1 wherein said means for modulating includes as an input element thereof, a polarizer element, said modulator means further including a second electrooptical modulator configuration disposed following said birefringent etalon device such that, after said light signal has passed through said birefringent etalon device, said light signal can be modulated to a second frequency whereby upon such modulation, such shifting in the periodic transmission spectra between spectra which coincide with such absorption lines and spectra which fall between such absorption lines can be achieved.

7. A remote gas measuring apparatus as set forth in claim 1 wherein said distinguishing means, in determining such quantity of such gas of interest, first divides said light signal at said second frequency by said light signal at said first frequency thereby factoring out, an intensity value associated with said light signal at said first frequency.

8. A remote gas measuring apparatus as set forth in claim 7 wherein said distinguishing means further determine such quantity of such gas of interest by comparing such spectra which coincides with such absorption lines and such spectra which fall between such absorption lines.

9. A method of remotely measuring a gas of interest by its optical absorption line characteristics, said remote measuring method comprising the steps of:

directing a light beam to an area backed by a reflective surface, where such gas of interest may be such that a light signal representative of such absorption line characteristics can be back reflected toward a light signal receiving device;

collecting such back reflected light signal by such receiving device;

passing said light signal through a light modulating arrangement such that such light signal is modulated at a first frequency;

directing said light signal modulated at said first frequency through a birefringent etalon device which has associated therewith, a periodic spacing substantially equivalent to such absorption lines associated with such gas of interest;

applying an electric field to a modulating arrangement associated with such birefringent etalon to modulate such once modulated light signal between spectra which substantially coincide with such absorption lines and spectra which fall between such absorption lines, said electric field having associated therewith a second frequency distinct from such first frequency and related thereto by a whole integer factor other than one; and

distinguishing between such light signal at such first frequency and such light signal at such second frequency an determining therefrom at least a quantity of such gas of interest.

10. A remote gas measuring method as set forth in claim 9 further comprising the steps of polarizing such light beam prior to said passing of said light beam to such light modulator arrangement and conditioning such light signal after said step of directing said light signal through such birefringent etalon device such that certain known portions of such light signal are removed prior to said distinguishing step.

11. An apparatus for remotely measuring a gas of interest by is optical absorption line characteristics, said remote measuring apparatus comprising:

a source of electromagnetic radiation;

means for directing such electromagnetic radiation through such as of interest to a remote, reflective surface;

mans for receiving a reflected light signal produced as a result of such electromagnetic radiation passing through such gas of interest and having at least a portion thereof reflected in a direction toward said receiving means;

light modulator means optically coupled to said receiving mean for once modulating said light signal at a first frequency;

means for modulating said once modulated light signal at a second frequency related to said first frequency by a whole integer factor other than one, said modulating means including an interferometric device receptive of said light signal and having associated therewith, a periodic spacing equal to the periodicity of the absorption lines of such gas of interest, said interferometric device further having associated therewith, a second periodic spacing substantially equivalent to transmission spectra which fall between such absorption lines, to produce a twice modulated light signal;

wherein said interferometric device is modulated between said first and said second frequency be application of an electric field thereto, and

means for detecting at least an amount of such gas of interest as a function of the intensity of such periodic transmission spectra.

12. A measurement arrangement as set forth in claim 11 wherein said interferometric device is a compound Fabry-Perot birefringent etalon device having associated therewith, a first index of refraction and a path length which determine, in conjunction, such periodic transmission spectra which substantially coincides with such absorption lines associated with such gas of interest.

13. A measurement arrangement as set forth in claim 12 wherein said birefringent etalon device further has associated therewith, a second index of refraction which determines such periodic transmission spectra which falls between such absorption lines associated with said gas of interest.

14. A measurement arrangement as set forth in claim 13 wherein said second index of refraction can be selected from a range of values such that such periodic transmission spectra which falls between such absorption lines associated with the gas of interest, occur at a wavelength which essentially avoids interference from gases other than such gas of interest.

15. An apparatus for rapid scanning of the concentration of a remote gas using optical absorption line characteristics of the gas, the apparatus comprising:

a source of electromagnetic radiation;

means for directing the electromagnetic radiation toward a remote, reflective surface;

means for receiving reflected electromagnetic radiation from the remote surface;

a light switch optically coupled to said receiving means for producing polarized pulses of light at a first frequency from the reflected electromagnetic radiation;

a birefringent etalon optically coupled to the light switch, the etalon having periodic transmission spectra shiftable between first spectra which coincide with such absorption lien characteristics and second spectra which fall between such absorption line characteristics, to produce pulses containing the first spectra and pulses containing the second spectra;

means for distinguishing the pulses containing the first spectra and the pulses containing the second spectra;

means for correlating pulses of the first spectra and pulses of the second spectra in time;

means for determining gas concentration from correlated pulses of the first spectra and the second spectra.