Coating composition

• US 5,076,841 A
• Filed: 05/31/1990
• Issued: 12/31/1991
• Est. Priority Date: 05/31/1990
• Status: Expired due to Fees

• Current Assignee: Shipley Company, Inc. (DuPont de Nemours, Inc.)
• Original Assignee: Shipley Company, Inc. (DuPont de Nemours, Inc.)
• Inventors: Knudsen, Philip D., Chen, Jensheng
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): EINSMANN, MARGARET V
• Application Number:
  US07/531,440
• Time in Patent Office: 579 Days
• Field of Search: 106/1.28, 106/1.25, 106/1.26
• US Class Current: 106/1.25
• CPC Class Codes: C23C 18/30 Activating or accelerating or sensitising with palladium or other noble metal
• CPC Class Codes: H05K 3/181 by electroless plating adhesives therefor H05K3/387
• CPC Class Codes: H05K 3/387 for electroless plating H05K3/4661 takes precedence

Abstract

The invention discloses a new electroless plating catalyst and a process of using the same for selective plating. The catalyst and process are especially adapted for formation of EMI shielding for electronic components. The electroless plating catalyst comprises particulates dispersed in a liquid film forming composition which particulates are coated with a hydrous oxide that is reduced to a catalytic metal in contact with an electroless plating solution.

Claims

1. A coating composition suitable for use as an electroless plating catalyst, said composition comprising a polymer solution having particles homogeneously dispersed therein said particles comprising an inert particulate carrier coated with a hydrous oxide of a metal insoluble in the polymer polution that is catalytic to electroless metal deposition when in a reduced form, said hydrous oxide having a metal content of from 0.5 to 50 grams per liter of coating composition.

2. The composition of claim 1 where the particles comprise a noble metal hydrous oxide adsorbed onto an inert particulate carrier.

3. The composition of claim 1 where the noble metal is silver.

4. The composition of claim 1 where the noble metal is palladium.

5. The composition of claim 1 where the composition is a varnish.

6. The composition of claim 1 where the polymer is selected from the group consisting of phenolics, epoxies, alkyds, polyesters, acrylics, polyurethanes and polyamides.

7. The composition of claim 1 where the metal concentration varies from about 1.0 to 25.0 grams per liter of solution.

8. The composition of claim 6 where the concentration varies from about 1.5 to 10.0 grams per liter of solution.

9. The composition of claim 1 where the weight ratio of the inert particulate carrier to the metal portion of the hydrous oxide varies from 1 to 1 to 50 to 1.

10. The composition of claim 9 where the ratio varies from 5 to 1 to 15 to 1.

11. The composition of claim 1 where the inert particulate carrier is chosen from the group of irregularly shaped particles selected from the group of carbon, glass, titania or silica.

12. The composition of claim 11 where the particulate carrier is silica.

13. The composition of claim 1 where the particle size of the inert particulate carrier ranges between 1 and 100 microns.

14. A coating composition suitable for use as an electroless plating catalyst, said composition comprising a polymer solution having particles homogeneously dispersed therein, said particles comprising a silver hydrous oxide insoluble in said polymer solution coated on an inert particulate carrier, said coating composition having silver present in a concentration of from 0.5 to 50 grams per liter of coating composition.

15. The composition of claim 14 where the concentration of silver varies from about 1.0 to 25.0 grams per liter of coating composition.

16. The composition of claim 14 where the polymer is selected from the group consisting of phenolics, epoxies, alkyds, polyesters, acrylics, polyurethanes and polyamides.

17. The composition of claim 14 where the weight ratio of the inert particulate carrier to the metallic silver portion of the silver hydrous oxide varies between from 1 to 1 to 50 to 1.

18. The composition of claim 17 where the ratio varies between 5 to 1 to 15 to 1.

19. The composition of claim 14 where the inert particulate carrier is chosen from the group of irregularly shaped particles selected from the group of carbon, glass, titania or silica.

20. The composition of claim 19 where the inert particulate carrier is silica.

21. The composition of claim 14 where the particle size of the inert particulate carrier ranges between 1 and 100 microns.