Methods of curing partially polymerized parts

• US 5,076,974 A
• Filed: 11/08/1988
• Issued: 12/31/1991
• Est. Priority Date: 04/18/1988
• Status: Expired due to Term

• Current Assignee: 3D Systems, Inc. (3D Systems Corporation)
• Original Assignee: 3D Systems (3D Systems Corporation)
• Inventors: Parker, Brent, Spence, Stuart T., Modrek, Borzo
• Primary Examiner(s): Tentoni, Leo B.
• Application Number:
  US07/268,429
• Time in Patent Office: 1,148 Days
• Field of Search: 264/22, 264/86, 264/234, 264/236, 264/344, 264/345, 264/347, 264/232, 264/340, 425/84, 425/174.4, 425/404, 425/445, 34/9, 34/12, 34/42, 34/89.1, 34/95, 34/243 R, 427/54.1, 427/53.1, 427/393.5, 250/432 R, 250/492.1, 430/327, 430/328, 430/394, 430/396, 522/910
• US Class Current: 264/401
• CPC Class Codes: B29C 64/135 the energy source being concentrated, e.g. scanning lasers or focused light sources
• CPC Class Codes: B33Y 40/20 Post-treatment, e.g. curing, coating or polishing
• CPC Class Codes: G05B 2219/49013 Deposit layers, cured by scanning laser, stereo lithography SLA, prototyping
• CPC Class Codes: Y10S 522/91 Treatment through an external filter or mask, nonphotograghic process

Abstract

An improved stereolithography system and method for curing a stereolithographically-produced part, including at least some material that is no more than partially transformed, by exposing the part to off-peak-absorptive wavelengths of synergistic stimulation to achieve a more uniform cure.

Claims

1. A method for curing a stereolithographically-produced, partially polymerized part comprising a material that absorbs reactive electromagnetic radiation most strongly at peak-absorptive wavelengths and less strongly at off-peak absorptive wavelengths, comprising the steps of:

providing a source of electromagnetic radiation, including both peak-absorptive and off-peak absorptive wavelengths, for curing said part; and

exposing said part to electromagnetic radiation while substantially screening the electromagnetic radiation at the peak-absorptive wavelengths, thereby curing the part with primarily off-peak absorptive wavelengths.

2. The method of claim 1 further comprising the step of immersing the part in water, wherein the screening is carried out by adding photoinitiator to the water.

3. The method of claim 1 further comprising the steps of immersing the part in water and maintaining the water in a substantially pure state.

4. The method of claim 1 further comprising providing an electromagnetic screen between the source of electromagnetic radiation and the part.

5. The method of claim 3 further comprising maintaining the water at a preselected temperature.

6. The method of claim 1 wherein said providing step comprises providing said source of electromagnetic radiation which is ultraviolet radiation, and said screening step comprises substantially screening the ultraviolet radiation at the peak-absorptive wavelengths.

7. The method of claim 6 further comprising the step of immersing the part in water, wherein the screening step comprises adding photoinitiator to the water.

8. The method of claim 7 further comprising the step of maintaining the water in a substantially pure state.

9. The method of claim 6 wherein the screening step comprises providing an electromagnetic screen between said source and the part.

10. The method of claim 7 further comprising the step of substantially maintaining the water at a preselected temperature.

11. A method for curing a stereolithographically-produced, partially polymerized part comprising a material that absorbs reactive electromagnetic radiation most strongly at peak-absorptive wavelengths and less strongly at off-peak absorptive wavelengths to further polymerize said part, comprising the steps of:

submerging the part in a liquid medium;

adding an absorbing substance, which absorbs electromagnetic radiation at peak-absorptive wavelengths more strongly than at off-peak absorptive wavelengths, to the liquid medium; and

exposing said part to electromagnetic radiation while said part is still submerged in said liquid medium, thereby curing the part with primarily off-peak absorptive wavelengths.

12. The method of claim 11 wherein said adding step comprises adding photoinitiator to the liquid medium.

13. The method of claim 11 wherein said adding step comprises adding said substance which is said photoinitiator to the liquid medium.

14. A method for curing a stereolithographically-produced, partially polymerized part comprising a material that absorbs reactive electromagnetic radiation most strongly at peak-absorptive wavelengths and less strongly at off-peak absorptive wavelengths to further polymerize said part, comprising the steps of:

exposing said part to electromagnetic radiation from a source; and

placing a screen, which filters peak-absorptive wavelengths more strongly than off-peak absorptive wavelengths from the electromagnetic radiation, between the part and said source of electromagnetic radiation, thereby curing the part primarily with off-peak absorptive wavelengths.