Electroluminescent devices

• US 5,077,142 A
• Filed: 04/19/1990
• Issued: 12/31/1991
• Est. Priority Date: 04/20/1989
• Status: Expired due to Term

• Current Assignee: Idemitsu Kosan Company Limited
• Original Assignee: Ricoh Company Limited
• Inventors: Adachi, Chihaya, Hashimoto, Mitsuru, Tsutsui, Tetsuo, Sakon, Yohta, Saito, Shogo, Ohnuma, Teruyuki
• Primary Examiner(s): Seidleck, James J.
• Application Number:
  US07/511,407
• Time in Patent Office: 621 Days
• Field of Search: 428/690, 428/917, 313/504
• US Class Current: 428/690
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: H05B 33/14 characterised by the chemical or physical composition or the arrangement of the electroluminescent material , or by the simultaneous addition of the electroluminescent material in or onto the light source
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: Y10S 428/917 Electroluminescent

Abstract

Disclosed herein an electroluminescent device for converting an energy of an electric field applied directly to a light energy and capable of producing surface luminescent for a large area different from conventional incandescent lamps, fluorescent lamps or light emitting diodes.

Claims

1. An electroluminescent device comprising an anode, a cathode and one or a plurality of organic compound layers sandwiched therebetween, in which said organic compound layers comprise an organic compound, as the constituent ingredient, represented by the following formula (I):

##STR211## wherein B represents ##STR212## (in which X¹ is H, Cl, CH₃, OCH₃, C₂ H₅ or CN, and l is 1, 2 or

     3), ##STR213## (in which X² is H or OCH₃, and X³ is H, CH₃, ##STR214## (in which X⁴ is H or ##STR215## (in which D is O, S, or N, X⁵ is H or COOH,

X⁶ is H, CH₃, C₂ H₅ or ##STR216## and κ

is 0 or

     1), ##STR217## (in which X⁷ is H or O), ##STR218## (in which X⁸ is O or C(CN)₂), ##STR219## (in which X⁹ is H or CH₃), ##STR220## (in which X¹⁰ is O or C(CN)₂), ##STR221## (in which D is O, S or N,

Y¹ is H, and

i is 0 or

     1), ##STR222## (in which E is O or S), ##STR223## (in which E is O or S), ##STR224## (in which G is S or NH), ##STR225## (in which Z represents;

(1) substituted or unsubstituted (C₄ -C₆) cycloalkenes containing at least one double bond in the ring,

(2) (C₄ -C₆) cycloalkenes having an aromatic ring and containing one double bond in the ring,

(3) 5- or 9-membered heterocycles containing a double bond and at least one oxygen in the ring,

(4) 5-membered heterocycles having an aromatic ring, and containing one oxygen and at least one double bond in the ring,

(5) 6- or 7-membered heterocycles having C₄ or C₆ cycloalkene with at least one double bond, and containing two oxygen atoms in the ring,

(6) C₅, C₆ or C₁₁ heterocycles containing 1 or 2 sulfur atoms in the ring,

(7) 5- or 6-membered heterocycles containing 2 to 4 nitrogen atoms and at least one double bond in the ring,

(8) 5-, 6- or 8-membered heterocycles having an aromatic ring, and containing at least one double bond and 1 or 2 nitrogen atoms in the ring, or

(9) 5- or 6-membered heterocycles containing 1 or 2 nitrogen atoms and, optionally, oxygen atom in the ring;

Ar represents ##STR226## m represents an integer of 1 to 6; and

n represents an integer of 1 to 6.

2. An electroluminescent device according to claim 1, wherein at least one selected from the group consisting of electron transporting layer and hole transporting layer is further disposed between the anode and the cathode.

3. An electroluminescent device according to claim 1, wherein B represents ##STR227## (wherein X¹ and l are the same as defined above), ##STR228## (wherein X² and X³ are the same as defined above), ##STR229## (wherein X⁴ is the same as defined above), ##STR230## (wherein X⁹ is the same as defined above), ##STR231## (wherein D, Y¹ and i are the same as defined above), ##STR232## (wherein E is the same as defined above), or Z (which represents (1) substituted or unsubstituted (C₄ -C₆) cycloalkenes containing at least one double bond in the ring or (2) (C₄ -C₆) cycloalkenes having an aromatic ring and containing one double bond in the ring).

4. An electroluminescent device according to claim 1, wherein the thickness of the organic compound layer is not more than 2 μ

m.

5. An electroluminescent device according to claim 1, wherein said organic compound is selected from the group consisting of the compounds represented by the following formula:

##STR233## ##STR234## ##STR235##