Olefin polymerization catalyst

• US 5,077,357 A
• Filed: 10/22/1990
• Issued: 12/31/1991
• Est. Priority Date: 10/22/1990
• Status: Expired due to Term

• Current Assignee: Union Carbide Chemicals & Plastics Technology Corporation (Dow, Inc.)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Job, Robert C.
• Primary Examiner(s): GARVIN, PATRICK
• Application Number:
  US07/600,898
• Time in Patent Office: 435 Days
• Field of Search: 526/119, 526/124
• US Class Current: 526/119
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 110/06 Propene
• CPC Class Codes: C08F 2500/18 Bulk density
• CPC Class Codes: C08F 4/651 Pretreating with non-metals or metal-free compounds
• CPC Class Codes: C08F 4/6548 magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546

Abstract

An improved olefin polymerization process employs an olefin polymerization catalyst produced from a polymerization procatalyst made from a magnesium alkoxide, a titanium tetraalkoxide, a tetravalent titanium halide, a phenolic compound and an alkanol. The procatalyst precursor is contacted with a tetravalent titanium halide and an electron donor to form the procatalyst which is subsequently converted to the olefin polymerization catalyst by contact with a cocatalyst and a selectivity control agent.

Claims

1. In the process of polymerizing lower α

-olefin by contacting lower α

-olefin under polymerization conditions in the presence of an olefin polymerization catalyst formed from a titanium-based procatalyst, an organoaluminum cocatalyst and a selectivity control agent, the improvement of using as the procatalyst the olefin polymerization procatalyst produced by contacting an olefin procatalyst precursor obtained by heating a reaction mixture consisting essentially of a magnesium alkoxide wherein the alkoxide moieties independently have up to 4 carbon atoms inclusive, a titanium alkoxide wherein the alkoxide moieties independently have up to 4 carbon atoms inclusive, a titanium halide, a phenolic compound selected from phenol or phenol substituted with a group free from active hydrogen atoms which is ortho-para directing for aromatic ring substitution and an alkanol and removing alkanol from the resulting liquid mixture, with a tetravalent titanium halide, a halohydrocarbon and an electron donor.

2. The process of claim 1 wherein the tetravalent titanium halide is titanium tetrahalide.

3. The process of claim 2 wherein the electron donor is an alkyl ester of an aromatic monocarboxylic or dicarboxylic acid.

4. The process of claim 3 wherein the titanium tetrahalide is a titanium tetrachloride.

5. The process of claim 4 wherein the halohydrocarbon is chlorobenzene.

6. The process of claim 5 wherein the ester is ethyl benzoate or diisobutyl phthalate.

7. In the process of polymerizing propylene by contacting propylene under polymerization conditions in the presence of an olefin polymerization catalyst formed from a titanium-based procatalyst, an organoaluminum cocatalyst and a selectivity control agent, the improvement of using as procatalyst the olefin polymerization procatalyst produced by contacting an olefin polymerization procatalyst precursor obtained by heating a reaction mixture consisting essentially of magnesium ethoxide, titanium ethoxide, titanium tetrachloxide, a phenolic compound selected from phenol or phenol substituted by alkyl, alkoxy, halo or dialkylamino and ethanol and removing ethanol from the resulting liquid mixture, with titanium tetrachloride, a halohydrocarbon and an alkyl ester of an aromatic monocarboxylic or dicarboxylic acid.

8. The process of claim 7 wherein the ester is ethyl benzoate or diisobutyl phthalate.

9. The process of claim 8 wherein the halohydrocarbon is chlorobenzene.

10. The process of claim 9 wherein the ester is ethyl benzoate.

11. The process of claim 9 wherein the ester is diisobutyl phthalate.