Bonded adsorbent structures and respirators incorporating same

• US 5,078,132 A
• Filed: 04/26/1991
• Issued: 01/07/1992
• Est. Priority Date: 08/28/1985
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Rekow, Peter O., Braun, David L.
• Primary Examiner(s): Burr, Edgar S.
• Assistant Examiner(s): Asher, Kimberly L.
• Application Number:
  US07/692,238
• Time in Patent Office: 256 Days
• Field of Search: 128/205.27, 128/205.28, 128/205.29, 128/206.12, 128/206.19, 128/206.21, 128/206.28
• US Class Current: 128/206.12
• CPC Class Codes: A62B 23/02 for respirators
• CPC Class Codes: A62D 9/00 Composition of chemical substances for use in breathing apparatus
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: B01J 20/28011 Other properties, e.g. density, crush strength
• CPC Class Codes: B01J 20/2803 Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
• CPC Class Codes: B01J 20/28042 Shaped bodies; Monolithic structures

Abstract

Shaped porous filtering structures of substantially uniform thickness and density particularly suited for filtration of gases and vapors comprising spaced adsorbent granules unified into a solid, self-sustaining, unitary, impact-resistant body by adherent binder particles, respirators incorporating such structures as the gas and vapor filtration elements and methods for making the shaped porous filtering structures are disclosed.

Claims

1. A respirator comprising:

a facepiece adapted for peripheral sealing contact with at least that portion of a human head which includes the nose and mouth;

associated fastening means for holding said respirator in position on the head; and

at least one porous filtering structure having a panel-like shape, mounted in the respirator across a path for air to be drawn or blown inwardly through the respirator, the filtering structure;

having two opposed large-area surfaces with dimensions larger than the structure'"'"'s thickness;

being a unified and impact-resistant structure;

said filtering structure comprising spaced individual adsorbent granules bonded to one another by uniformly distributed, adherent binder particles disposed between said granules wherein said binder particles were in a liquefied state during bonding of the structure, and at least 85 weight percent of the binder particles have diameters larger than 400 mesh.

2. A respirator of claim 1 wherein the facepiece is made of a elastomeric material.

3. A respirator of claim 1 in which the two opposed large-area surfaces of the porous filtering structure are curved.

4. A respirator of claim 1 wherein said respirator is capable of passing 85 lpm of air therethrough at a pressure drop of not over 40 mm of water.

5. A respirator of claim 1 wherein said respirator has a breakthrough time against a challenge of carbon tetrachloride vapor at a concentration of 1000 ppm at a flowrate of 64 lpm of at least 50 minutes.

6. A respirator of claim 1 wherein at least 85 weight percent of the binder particles are larger than 200 mesh.

7. A respirator of claim 1 wherein at least 85 weight percent of the binder particles have diameters in the range of 40 to 400 mesh.

8. A respirator of claim 1 wherein the binder particles are polymeric materials which achieve contact angles of 45°

to 135°

between the temperature whereat the binder particles begin to exhibit surface tension smoothening, and the temperature whereat the binder particles flow out as a film on a heated surface.

9. A respirator of claim 1 wherein the binder particles are selected from the group consisting of polyurethane, ethylene-vinyl acetate, and polyethylene.

10. A respirator of claim 1 wherein the adsorbent granules have an average particle size in the range of 6 to 80 mesh.

11. A respirator of claim 1 wherein the adsorbent granules have an average particle size in the range of 12 to 40 mesh.

12. A respirator of claim 1 wherein said absorbent granules and said binder particles have a size ratio in the range of 1.2 to 3.0.

13. A respirator of claim 1 in which the adsorbent granules comprise carbon.

14. A respirator of claim 1 wherein the adsorbent granules comprise carbon, the binder particles comprise polyurethane, and at least 85 weight percent of the binder particles have diameters in the range of 40 to 400 mesh.

15. A respirator of claim 1 wherein the porous filtering structure is a molded, panel-like shape comprising a mixture of said absorbent particles and said binder particles said mixture preheated until surface tension effects draw said binder particles into a smoothly curved droplet on a heated surface.

17. A respirator of claim 1 wherein the porous filtering structure contains about 65 to 90 weight percent adsorbent granules and about 10 to 35 weight percent binder particles.

18. A respirator of claim 1 wherein the porous filtering structure contains about 80 weight percent adsorbent granules and about 20 weight percent binder particles.

16. A respirator of claim wherein the porous filtering structure has an adsorbent density of from 80 percent to 110 percent of an equivalent loose packed bed as determined by ASTM D-2854-70.

19. In combination, a powered air-purifying respirator and at least one porous filtering structure having a panel-like shape adapted to be mounted across a path for air to enter the respirator, the filtering structure;

having two opposed large-area surfaces with dimensions larger than the structure'"'"'s thickness;

being a unified and impact resistant structure;

said filtering structure comprising spaced individual adsorbent granules bonded to one another by uniformly distributed, adherent binder particles disposed between said granules wherein said binder particles were in a liquefied state during bonding of the structure, and at least 85 weight percent of the binder particles have diameters larger than 400 mesh.