Porous membrane formed from interpenetrating polymer network having hydrophilic surface

• US 5,079,272 A
• Filed: 11/30/1989
• Issued: 01/07/1992
• Est. Priority Date: 11/30/1989
• Status: Expired due to Term

• Current Assignee: Millipore Corporation (Merck & Co., Inc.)
• Original Assignee: Millipore Corporation (Merck & Co., Inc.)
• Inventors: Allegrezza, Anthony E. Jr., Bellantoni, Ellen C.
• Primary Examiner(s): Kight, III, John
• Assistant Examiner(s): COONEY, JOHN M
• Application Number:
  US07/444,086
• Time in Patent Office: 768 Days
• Field of Search: 521/134, 521/64, 525/903
• US Class Current: 521/134
• CPC Class Codes: B01D 2323/30 Cross-linking
• CPC Class Codes: B01D 2323/385 involving radiation
• CPC Class Codes: B01D 2325/36 Hydrophilic membranes
• CPC Class Codes: B01D 67/0006 by chemical reactions in-situ polymerisation, polycondensation, cross-linking or reaction for manufacturing composite membranes B01D69/125
• CPC Class Codes: B01D 67/00111 Polymer pretreatment in the casting solutions
• CPC Class Codes: B01D 67/0083 Thermal after-treatment
• CPC Class Codes: B01D 69/141 Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
• CPC Class Codes: B01D 71/34 Polyvinylidene fluoride
• CPC Class Codes: Y10S 525/903 Interpenetrating network

Abstract

A porous membrane is formed from an interpenetrating polymer network of a hydrophobic polymer and a polymerized and crosslinked hydrophilic monomeric composition. A solution of the polymer and monomeric composition is cast, exposed to ultraviolet radiation, coagulated and dried. The resulting dried membrane is annealed in order to render its surface hydrophilic.

Claims

1. A porous membrane having a water wettable surface which comprises a porous interpenetrating polymer network of a hydrophobic fluorinated hydrocarbon polymer and a hydrophilic cross-linked polymer, formed from a monomer selected from the group consisting of an hydroxylalkyl acrylate, an hydroxylalkyl methacrylate and N-vinylpyrrolidone, said membrane having a hydrophilic surface formed from said hydrophobic polymer in semi-crystalline form and said hydrophilic polymer, said surface being entirely wettable with an aqueous liquid within a time period of less than about 1 minute.

2. The porous membrane of claim 1 wherein said membrane has a maximum pore size between about 0.01 and 0.1 microns.

3. The porous membranes of claim 2 wherein said membrane has an isopropyl alcohol bubble point of between about 40 psi and about 140 psi, a water flux of above about 3500 gallons per foot per day at 25 psi for a membrane having a bubble point of about 40 psi, a water flux of above about 1000 gallons per foot per day at 25 psi for a membrane having a bubble point of about 80 psi, and a water flux above about 1000 gallons per foot per day at 25 psi for a membrane having a bubble point of about 140 psi.

4. The membrane of any one of claims 1, 2 or 3 wherein the hydrophobic polymer is polyvinylidene fluoride.

5. The porous membrane of any one of claims 1, 2, or 3 wherein said hydrophilic polymer is formed from an hydroxylalkyl acrylate.