Method and apparatus for measuring thermal diffusivity by ac joule-heating

• US 5,080,495 A
• Filed: 08/28/1990
• Issued: 01/14/1992
• Est. Priority Date: 08/30/1989
• Status: Expired due to Term

• Current Assignee: AI-Phase Co., Ltd.
• Original Assignee: Mitsui Toatsu Chemicals Incorporated (Mitsui Chemicals)
• Inventors: Miyamoto, Akira, Shizuka, Kohei, Hyugaji, Teruo, Hashimoto, Toshimasa
• Primary Examiner(s): Cuchlinski, Jr., William A.
• Assistant Examiner(s): BENNETT, GEORGE B
• Application Number:
  US07/573,810
• Time in Patent Office: 504 Days
• Field of Search: 374/43, 374/44, 374/120, 374/119 X, 374/117
• US Class Current: 374/43
• CPC Class Codes: G01N 25/18 by investigating thermal conductivity by calorimetry G01N25/20; by measuring change of resistance of an electrically-heated body G01N27/18

Abstract

Disclosed is a method for measuring the thermal diffusivity in the thickness direction of a thin sample plate, which has the steps of forming a conductive thin layer on at least one surface of said thin sample plate to allow the thin film to function as an ac heater generating joule heat, applying an ac current modulated with a given modulation frequency to the ac heater (conductive thin layer) so as to produce ac joule-heating, generating an oscillation response corresponding to said ac joule-heating on the opposite surface of the ac heater, and measuring the phase shift between said oscillation response, and the ac joule-heating, thereby obtaining the thermal diffusivity in the thickness direction of said sample plate. Apparatus useful for the method are also disclosed.

Claims

1. A method for measuring the thermal diffusivity in the thickness direction of a thin sample plate of relatively non-conductive material which comprises the steps of:

forming a conductive thin layer on at least one surface of said thin sample plate to allow the thin layer to function as an ac heater generating joule heat;

applying an ac current modulated with a given modulation frequency to the ac heater so as to produce ac joule-heating;

generating an oscillation response corresponding to said ac joule-heating on the opposite surface of the ac heater; and

measuring the phase shift between said oscillation response and the ac joule-heating, thereby obtaining the thermal diffusivity in the thickness direction of said sample plate.

2. The method of measuring the thermal diffusivity of the sample plate according to claim 1 wherein the oscillation response is a temperature oscillation response.

3. The method for measuring the thermal diffusivity according to claim 2 which comprises the steps of:

forming a conductive thin layer on both surfaces of the thin sample plate to allow one of the thin layers to function as the ac heater generating joule heat and to allow the other thin layer to function as a resistance thermometer making use of the variation of the resistance with temperature;

the step of generating an oscillation response including generating a temperature oscillation response corresponding to said ac joule-heating in said resistance thermometer; and

the step of measuring the phase shift including measuring the phase shift between the temperature oscillation response and the ac joule heating for at least two points in said modulation frequency range, thereby obtaining the thermal diffusivity in the thickness direction of said sample plate from the relationship between the phases shifts and said modulation frequency.

4. The method for measuring thermal diffusivity according to claim 3 wherein the sample plate is a plate fabricated from relatively non-conductive material selected from high molecular materials (polymers), organic dyestuff, mineral ores, glasses and ceramics.

5. The method for measuring thermal diffusivity according to claim 3 wherein the thin layers functioning as the ac heater and the resistance thermometer are formed by sputtering.

6. The method for measuring thermal diffusivity according to claim 3 wherein the temperature dependence of the thermal diffusivity is measured at desired temperatures by heating or cooling the sample.

11. The method for measuring thermal diffusivity according to claim 2 which comprises:

providing a cell equipped with a sound signal detector;

incorporating said sample plate which has the conductive thin layer functioning as the ac heater on the one surface and which has an opposite surface that serves as the measurement surface, into said cell in such a way that the measurement surface constitutes a part of the inner walls of said cell;

said step of generating an oscillation response including generating a temperature oscillation response corresponding to said ac joule-heating on said measurement surface, thereby inducing a periodic sound wave; and

said step of measuring the phase shift including measuring the phase shift between the ac joule heating and the periodic sound wave with a sound signal detector for at least two points in said modulation frequency range, thereby obtaining the thermal diffusivity in the thickness direction of the sample plate from the relationship between the phase shifts and said modulation frequency.

13. The method for measuring thermal diffusivity according to claim 11 wherein the thin layer functioning as the ac heater is formed by sputtering.

18. A method for measuring thermal conductivity of a thin sample plate comprising measuring the thermal diffusivity of the sample plate according to the method described in claim 3 and obtaining thermal conductivity using a specific heat and density of said sample plate.

19. A method for measuring thermal conductivity of a thin sample plate comprising measuring the thermal diffusivity of the sample plate according to the method described in claim 4 and obtaining thermal conductivity using a specific heat and density of said sample plate.

20. A method for measuring thermal conductivity of a thin sample plate comprising measuring the thermal diffusivity of the sample plate according to the method described in claim 5 and obtaining thermal conductivity using a specific heat and density of said sample plate.

21. A method of measuring thermal conductivity of a thin sample plate comprising measuring the thermal diffusivity of the sample plate according to the method described in claim 11 and obtaining thermal conductivity using a specific heat and density of said measurement sample.

23. A method for measuring thermal conductivity of a thin sample plate comprising measuring the thermal diffusivity of the sample plate according to the method described in claim 13 and

24. The method for measuring thermal diffusivity according to claim 3, wherein the thin layers functioning as the ac heater and the resistance thermometer are formed by vapor deposition.

25. The method for measuring thermal diffusivity according to claim 3, wherein the thin layers functioning as the ac heater and the resistance thermometer are formed by coating.

26. The method for measuring thermal diffusivity according to claim 3, wherein the thin layers functioning as the ac heater and the resistance thermometer are formed by adhesion.

27. The method for measuring thermal diffusivity according to claim 3, wherein the thin layers functioning as the ac heater and the resistance thermometer are formed by applying pressure.

29. The method for measuring thermal diffusivity according to claim 11, wherein the thin layer functioning as the ac heater is formed by vapor deposition.

30. The method for measuring thermal diffusivity according to claim 11, wherein the thin layer functioning as the ac heater is formed by coating.

31. The method for measuring thermal diffusivity according to claim 11, wherein the thin layer functioning as the ac heater is formed by applying pressure.

32. The method of measuring the thermal diffusivity of a sample plate according to claim 1, wherein the oscillation response is a periodic sound wave.

7. A method for measuring thermal conductivity of a thin sample plate comprising measuring the thermal diffusivity of the sample plate according to the method described in claim 7 and obtaining thermal conductivity using a specific heat and density of said sample plate.

8. An apparatus for measuring thermal diffusivity in the thickness direction of a thin sample plate provided with conductive thin layers on both surfaces which comprises:

an ac current generation means for applying an ac current with a given amplitude of modulation to one of the conductive thin layers;

a dc current supplying means for applying a given dc current to the other conductive thin film which is temperature dependent; and

a lock-in amplifier for amplifying a voltage which varies in accordance with changes in resistance of said temperature dependent conductive thin layer.

9. The apparatus for measuring thermal diffusivity according to claim 8 which further comprises a cell for accommodating the thin sample plate.

10. The apparatus for measuring thermal diffusivity according to claim 9 which further comprises a means for heating or cooling the sample in the cell, thereby giving the temperature dependence of the thermal diffusivity by changing the measurement atmosphere temperature.

12. The method for measuring thermal diffusivity according to claim 12 wherein the sample plate is a plate fabricated from a relatively non-conductive material selected from high molecular compounds (polymers), organic dyestuffs, mineral ores, glasses and ceramics.

14. The method for measuring thermal diffusivity according to claim 12 wherein the thermal diffusivity is temperature dependent, the temperature dependence of the thermal diffusivity being measured at desired temperatures by heating or cooling the sample.

15. A method for measuring thermal conductivity of a thin sample plate comprising measuring the thermal diffusivity of the sample plate according to the method described in claim 14 and obtaining thermal conductivity using the specific heat and density of said sample plate.

22. A method for measuring thermal conductivity of a thin sample plate comprising measuring the thermal diffusivity of the sample plate according to the method described in claim 12 and obtaining thermal conductivity using a specific heat and density of said measurement sample.

28. The method for measuring thermal diffusivity according to claim 12, wherein the thin layers functioning as the ac heater is formed by adhesion.

16. An apparatus for measuring thermal diffusivity in the thickness direction of a thin sample plate, on one surface of which is formed a conductive thin layer functioning as an ac heater and an opposite surface of which serves as a measurement surface, which comprises:

an ac current generation means for applying an ac current with a given amplitude of modulation to the conductive thin layer;

a cell having a sound signal detector in an interior thereof which outputs output signals, said cell having inner walls and being capable of incorporating the sample plate in such a way that the measurement surface of said sample plate comprises a part of the inner walls of the cell; and

a lock-in amplifier for amplifying the output signals of said sound signal detector.

17. The apparatus for measuring thermal diffusivity according to claim 16 which further comprises a means for heating or cooling the sample in the cell to change a measurement atmosphere temperature in the cell so that a temperature dependence on the thermal diffusivity can be measured.