Recovering clean metal and particulates from metal matrix composites

• US 5,080,715 A
• Filed: 11/05/1990
• Issued: 01/14/1992
• Est. Priority Date: 11/05/1990
• Status: Expired due to Fees

• Current Assignee: Alcan Incorporated (Rio Tinto Limited)
• Original Assignee: Alcan Incorporated (Rio Tinto Limited)
• Inventors: Riverin, Gaston, Provencher, Robert
• Primary Examiner(s): ROSENBERG, PETER
• Application Number:
  US07/609,434
• Time in Patent Office: 435 Days
• Field of Search: 75/708, 75/680, 75/683, 266/217
• US Class Current: 75/708
• CPC Class Codes: C22B 21/062 using salt or fluxing agents C22B21/064, C22B21/066, and C22B21/068 take precedence
• CPC Class Codes: C22B 21/064 using inert or reactive gases C22B21/066 and C22B21/068 take precedence
• CPC Class Codes: Y02P 10/20 Recycling

Abstract

A process is described for removing all reinforcing particles contained in metal matrix composite scrap materials. This new technique involves providing a treatment vessel for holding a melt of an aluminum matrix composite to be recycled. Heating means are provided for heating the contents of the vessel to a temperature in the range of 700°-750° C. Mixing of the melt is carried out by means of a power driven vaned rotary impeller and this impeller is operated under different conditions for different stages of the process. In the first mixing stage, the impeller is operated under vortex-forming conditions and a fluxing salt is added to the melt while a gas is injected through a gas outlet beneath the surface of the melt and near the rotating impeller. This causes the salt to rapidly mix with the melt and the inlet gas, providing a uniform distribution through the melt of gas bubbles each surrounded by a layer of liquid salt. As a second stage of the treatment process, the impeller is operated at a high differential velocity between the impeller and the melt. These conditions cause collisions between the salt-coated bubbles and wetted reinforcing particles such as to de-wet the reinforcing particles and cause the reinforcing particles and salt flux to rise to the surface of the melt. The surface layer that is formed is essentially a powder which can easily be removed leaving a substantially pure metal with its chemical composition unchanged.

Claims

1. A process for recovering substantially pure aluminum or aluminum alloy from an aluminum matrix composite containing solid reinforcing particles, comprising the steps of:

(a) providing a melt of the aluminum matrix composite in a treatment vessel,

(b) heating the melt in the vessel to maintain a temperature in the range of 700°

-750°

C.,

(c) mixing the melt with a vaned rotary impeller,

(d) treating the melt while mixing firstly under vortex-forming conditions by adding afluxing salt to the melt and injecting a gas through a gas outlet beneath the surface of the melt and near the rotating impeller whereby the salt is rapidly mixed with the melt and the inert gas, providing a uniform distribution through the melt of gas bubbles each surrounded by a layer of liquid salt,

(e) treating the mixture from part (d) by secondly mixing while operating the impeller at a higher differential velocity between the impeller and the melt than the differential velocity of the first mixing to thereby cause collisions between the salt coated bubbles and wetted reinforcing particles such as to de-wet the reinforcing particles and cause the reinforcing particles and salt flux to rise to the surface of the melt in the form of a layer of dry powder and

(f) recovering a melt of substantially pure aluminum or aluminum alloy.

2. A process according to claim 1 wherein the salt comprises an alkali metal halide salt.

3. A process according to claim 2 wherein the salt is a chloride or fluoride mixture.

4. A process according to claim 2 wherein the salt comprises a mixture of NaCl+KCl.

5. A process according to claim 1 wherein the salt is added in an amount of 0.05 to 1.5 percent by weight.

6. A process according to claim 5 wherein the gas is an inert gas.

7. A process according to claim 6 wherein the reinforcing particles are alumina or silicon carbide.

8. A process according to claim 1 wherein the treatment vessel has a substantially circular cross-section and the ratio of the impeller diameter:

vessel diameter is about 1;

2.5 to 1;

4.

9. A process according to claim 8 wherein for the first mixing stage the impeller is positioned approximately centrally in the vessel.

10. A process according to claim 9 wherein for the secondary mixing stage the impeller is positioned axially off-center.

11. A process according to claim 10 wherein the impeller is rotated at about 200 rpm in the first mixing stage and about 250 rpm in the second mixing stage.

12. A process according to claim 1 wherein the layer of dry powder is removed from the surface of the melt.

13. A process according to claim 12 wherein the salt is leached out of the powder, leaving substantially pure reinforcing particles.

14. A process according to claim 13 wherein the reinforcing particles are ceramic particles.