Temperature regulating reactor apparatus and method

• US 5,080,872 A
• Filed: 01/09/1989
• Issued: 01/14/1992
• Est. Priority Date: 09/26/1985
• Status: Expired due to Fees

• Current Assignee: Amoco Corporation (BP PLC)
• Original Assignee: Amoco Corporation (BP PLC)
• Inventors: Stasi, Michael A., Blanks, Robert F., Jezl, James L.
• Primary Examiner(s): Johnston, Jill
• Application Number:
  US07/295,226
• Time in Patent Office: 1,100 Days
• Field of Search: 422/148, 422/197, 422/201, 422/211
• US Class Current: 422/201
• CPC Class Codes: B01J 2208/00141 Coils
• CPC Class Codes: B01J 8/0285 Heating or cooling the reactor for tubular reactors in furnaces B01J8/062
• CPC Class Codes: C01B 3/344 using non-catalytic solid particles
• CPC Class Codes: C07C 1/0485 Set-up of reactors or accessories; Multi-step processes
• CPC Class Codes: C07C 2521/06 Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
• CPC Class Codes: C07C 2521/08 Silica
• CPC Class Codes: C07C 2521/10 Magnesium; Oxides or hydroxides thereof
• CPC Class Codes: C07C 2523/12 of actinides
• CPC Class Codes: C07C 2523/14 of germanium, tin or lead
• CPC Class Codes: C07C 2523/34 Manganese
• CPC Class Codes: C07C 2523/75 Cobalt

Abstract

A reactor apparatus and method useful in regulating temperature in a heterogeneous reaction system is provided. The apparatus includes an elongated tube reactor packed with a bed of solid particles through which a reactant fluid phase is passed. A plurality of heat transfer medium passage tubes are disposed in the bed of solid particles with adjacent tubes spaced relative to each other about the longitudinal axis of the reactor and with the tubes being substantially transverse to reactant flow through the reactor. The temperature in the system may, in turn, be regulated by effecting flow of a heat transfer medium through the passage tubes.

Claims

1. A reactor apparatus useful in regulating temperature in a heterogeneous reaction system, said apparatus comprising a reactor packed with a bed of solid particles through which a reactant fluid phase of said heterogeneous reaction system is passed, and having a plurality of heat transfer medium passage means disposed in said bed of solid particles with said passage means being substantially transverse to reactant flow through said reactor with adjacent passage means being in spaced relationship relative to each other about the longitudinal axis of said reactor.

2. The apparatus of claim 1 wherein said bed of solid particles comprises a catalytic material.

3. The apparatus of claim 2 wherein the heterogeneous reaction system comprises a synthesis gas conversion system wherein said fluid phase comprises synthesis gas and said catalyst comprises a Fischer-Tropsch catalyst.

4. The apparatus of claim 1 wherein at least one set of adjacent passage means are in staggered relationship relative to each other.

5. The apparatus of claim 4 wherein a first of said adjacent passage means forms a fluid flow passageway complimentary to a second of said adjacent passage means with the second of said adjacent passage means having a tube heat transfer surface aligned with said fluid flow passageway of the first of said adjacent passage means.

6. The apparatus of claim 1 wherein at least one of said passage means comprises a tube configured in a shape selected from the group consisting of a unidirectional spiral coil, a serpentine tube and a sandwiched spiral coil comprising two spiral coil portions interposed in the same tube axial plane with the two tube portions being connected with an S-shaped connector.

7. The apparatus of claim 1 wherein at least one of said passage means comprises a tube comprising a plurality of interconnected spaced tube segments with said solid particles being of a size up to about one-half the space between adjacent segments of said tube.

8. A reactor apparatus useful in regulating temperature in a heterogeneous reaction system during conversion of a gaseous feed comprising synthesis gas to C₂₊ hydrocarbon, said apparatus comprising a reactor packed with a bed of particles comprising Fischer-Tropsch catalyst and having a plurality of tubes imbedded in said bed of particles, with said tubes having a heat transfer medium passing therethrough and being substantially transverse to feed flow through said reactor.

9. The reactor of claim 8 wherein at least one set of adjacent tubes are in staggered relationship relative to each other.

10. The apparatus of claim 9 wherein a first of said adjacent tubes forms a fluid flow passageway complimentary to a second of said adjacent tubes with said second of said adjacent tubes having a tube heat transfer surface aligned with said fluid flow passageway of said first of said adjacent tubes.

11. The apparatus of claim 8 wherein at least one of said tubes is configured in a shape selected from the group consisting of a unidirectional spiral coil, a serpentine tube and a sandwiched spiral coil comprising two spiral coil portions interposed in the same tube axial plane with the two tube portions being connected with an S-shaped connector.

12. The apparatus of claim 8 wherein at least one of said tubes comprises a plurality of interconnected spaced tube segments with said solid particles being of a size up to about one-half the space between adjacent segments of said tube.

13. The apparatus of claim 8 wherein said Fischer-Tropsch catalyst comprises a cobalt-containing component.

14. The apparatus of claim 13 wherein said cobalt-containing component is supported on a diatomaceous earth support.

15. The apparatus of claim 14 wherein said Fischer-Tropsch catalyst additionally comprises at least one of a magnesium-containing component, a thorium-containing component, a tin-containing component, a manganese-containing component or a zirconium-containing component.

16. A reactor apparatus useful in regulating temperature in a reaction system during conversion of a gaseous feed comprising carbon monoxide, hydrogen and nitrogen to C₂₊ hydrocarbons, said apparatus comprising a reactor containing a bed of solid particles comprising Fischer-Tropsch catalyst maintained at a pressure in the range of from about 1 to about 50 pounds per square inch gauge, said apparatus having a plurality of pancake-shaped tubes disposed in said bed of particles and having a heat transfer medium passing therethrough to maintain the temperature in said reactor in the range of from about 160°

C. to about 240°

C., with said tubes being substantially transverse to feed flow with at least one of said tubes comprising a plurality of interconnected spaced tube segments with said solid particles being of a size up to about one-half the space between adjacent segments of said tube.

17. The apparatus of claim 16 wherein at least one set of adjacent tubes are in staggered relationship relative to each other.

18. The apparatus of claim 17 wherein a first of said adjacent tubes forms a fluid flow passageway complimentary to a second of said adjacent tubes with said second of said adjacent tubes having a tube heat transfer surface aligned with said fluid flow passageway of said first of said adjacent tubes.

19. The apparatus of claim 16 wherein at least one of said tubes is configured in a shape selected from the group consisting of a unidirectional spiral coil, a serpentine tube and a sandwiched spiral coil comprising two spiral portions interposed in the same tube axial plane with the two tube portions being connected with an S-shaped connector.

20. The apparatus of claim 16 wherein said solid particles are of a size up to about one quarter the space between adjacent segments of said tube.

21. The apparatus of claim 16 wherein said apparatus comprises a plurality of sections with a first of said sections comprising at least one of said tubes having a first heat transfer medium passing therethrough and a second of said sections comprising at least a second of said tubes having a second heat transfer medium passing therethrough.

22. The apparatus of claim 21 wherein said first and second heat transfer mediums are the same material but at different heat transfer medium conditions.

23. The apparatus of claim 21 wherein said first of said sections comprises a greater number of tubes than said second of said sections.

24. The apparatus of claim 21 with an average bed temperature in a majority of said sections being approximately constant.

25. The apparatus of claim 24 wherein said average bed temperature in substantially all of said sections is approximately constant.

26. A method of regulating temperature in a heterogeneous reaction system, said method comprising the step of:

effecting flow of a heat transfer medium through passage means in a reactor apparatus comprising;

a reactor packed with a bed of solid particles through which a reactant fluid phase of said heterogeneous reaction system is passed, said apparatus including a plurality of heat transfer medium tubes disposed in said bed of solid particles with said passage means being substantially transverse to reactant flow through said reactor with adjacent passage means being in spaced relationship relative to each other about the longitudinal axis of said reactor.

27. The method of claim 26 wherein at least one set of adjacent passage tubes are in staggered relationship relative to each other.

28. The method of claim 27 wherein a first of said adjacent tubes forms a fluid flow passageway complimentary to the second of said adjacent tubes with a second of said adjacent tubes having a heat transfer surface aligned with said fluid flow passageway of the first of said adjacent tubes.

29. The method of claim 26 wherein at least one of said heat transfer medium passage tubes is configured in a shape selected from the group consisting of a unidirectional spiral coil, a serpentine tube and a sandwiched spiral coil comprising two spiral coil portions interposed in the same tube axial plane with the two tube portions being connected with an S-shaped connector.

30. The method of claim 26 wherein at least one of said heat transfer medium passage tubes comprises a plurality of interconnected spaced tube segments with said solid particles being of a size of up to about one-half the space between adjacent segments of said tube.

31. The method of claim 30 wherein said solid particles are of a size up to about one-quarter the space between adjacent segments of said tube.

32. The method of claim 26 wherein said apparatus comprises a plurality of sections with a first of said sections comprising at least one of said tubes having a heat transfer medium passing therethrough and a second of said sections comprising at least a second of said tubes having a second heat transfer medium passing therethrough.

33. The method of claim 32 wherein said first and second heat transfer mediums are the same material but at different heat transfer medium conditions.

34. The method of claim 32 wherein said first of said sections of said apparatus comprises a greater number of tubes than said second of said sections.

35. The method of claim 32 wherein said apparatus has an average bed temperature in the majority of said sections being approximately constant.

36. The method of claim 35 wherein said average bed temperature of said apparatus in substantially all of said sections is approximately constant.