Mixed fiber composite structures high surface area-high conductivity mixtures

• US 5,080,963 A
• Filed: 05/24/1989
• Issued: 01/14/1992
• Est. Priority Date: 05/24/1989
• Status: Expired due to Term

• Current Assignee: Auburn University
• Original Assignee: Auburn University
• Inventors: Kohler, David A., Zabasajja, John N., Tatarchuk, Bruce J., Rose, Millard F., Krishnagopalan, Aravamuthan
• Primary Examiner(s): Lesmes, George F.
• Assistant Examiner(s): Brown, Christopher
• Application Number:
  US07/356,861
• Time in Patent Office: 965 Days
• Field of Search: 428/225, 428/293, 428/457, 428/539.5, 428/545, 428/608, 428/288, 428/296, 428/311.1, 428/303, 428/401, 427/121, 264/60, 264/61, 264/63, 204/242, 204/252, 204/254, 204/282, 204/290 R, 204/294, 429/234, 429/235
• US Class Current: 442/343
• CPC Class Codes: B22F 3/002 Manufacture of articles essentially made from metallic fibres
• CPC Class Codes: D04H 1/42 characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
• CPC Class Codes: H01G 11/26 characterised by their structure, e.g. multi-layered, porosity or surface features
• CPC Class Codes: H01G 11/38 Carbon pastes or blends; Binders or additives therein
• CPC Class Codes: H01G 11/40 Fibres
• CPC Class Codes: H01G 11/52 Separators
• CPC Class Codes: H01G 11/70 characterised by their structure
• CPC Class Codes: H01G 11/72 specially adapted for integration in multiple or stacked hybrid or EDL capacitors
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors
• CPC Class Codes: Y10S 428/902 High modulus filament or fiber
• CPC Class Codes: Y10S 428/929 Electrical contact feature
• CPC Class Codes: Y10T 428/12424 Mass of only fibers
• CPC Class Codes: Y10T 428/12444 Embodying fibers interengaged or between layers [e.g., paper, etc.]
• CPC Class Codes: Y10T 428/298 Physical dimension
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer
• CPC Class Codes: Y10T 442/618 Blend of chemically different inorganic microfibers
• CPC Class Codes: Y10T 442/624 Microfiber is carbon or carbonaceous

Abstract

A new class of composites results from a matrix of carbon fibers, including graphite fibers, interwoven in a network of fused metal fibers. The composites can be fabricated to have varying surface area, void volume, and pore size while maintaining high electrical conductivity. Composites are readily prepared from a preform of a dispersion of carbon fibers, metal fibers, and an organic binder such as cellulose, by heating the preform at a temperature sufficient to fuse the metal fibers and to volatilize at least 90% of the binder with a loss of less than about 25%, and usually under 10%, by weight of carbon fiber.

Claims

1. A composite comprising a matrix consisting essentially of carbon fibers interlocked in a network of fused metal fibers.

2. The composite of claim 1 where the composite contains from about 1% to about 98% by weight of carbon fibers.

3. The composite of claim 1 where the carbon fibers have a diameter from about 20 nm to about 1 mm.

4. The composite of claim 1 where the carbon fibers have a surface area between 1 and about 1500 square meters per gram.

5. The composite of claim 4 where the carbon fibers have a surface area between about 50 and 1350 square meters per gram.

6. The composite of claim 5 where the carbon fibers have a surface area between about 250 and about 1000 square meters per gram.

7. The composite of claim 1 further characterized in having a surface area from about 0.001 to about 1350 square meters per gram.

8. The composite of claim 1 where the metal fibers have a diameter from about 1 to about 10 microns.

9. The composite of claim 1 containing from about 20 to about 98% carbon fibers.

10. The composite of claim 1 where the metal is selected from the group consisting of aluminum, titanium, vanadium, chromium, iron, cobalt, nickel, copper, zinc, zirconium, niobium, molybdenum, ruthenium, rhodium, palladium, silver, cadmium, indium, tin, hafnium, tantalum, tungsten, rhenium, osmium, platinum, gold, antimony, beryllium, iridium, silicon, and combinations thereof.

11. The composite of claim 1 where the metal is conducting alloy.

12. The composite of claim 11 where the conducting alloy is selected from the group consisting of constantan, hastelloy, nichrome, inconel, monel, carpenter'"'"'s metal, stainless steels, other steels, and other iron alloys.

13. The composite of claim 12 where the conducting alloy is a stainless steel.

14. An electrode comprising a composite bonded to an electrically conducting material, where the composite comprises a matrix consisting essentially of carbon fibers interlocked in a network of fused metal fibers.

15. The electrode of claim 14 where the composite contains from about 1 to about 98% by weight of carbon fibers.

16. The electrode of claim 14 where the carbon fibers have a diameter from about 20 nm to about 1 mm.

17. The electrode of claim 14 further characterized in having a surface area from about 0.001 to about 1350 square meters per gram.

18. The electrode of claim 14 where the carbon fibers have a surface area between 1 and about 1500 square meters per gram.

19. The electrode of claim 18 where the carbon fibers have a surface area between about 50 and 1350 square meters per gram.

20. The electrode of claim 19 where the carbon fibers have a surface area between about 250 and about 1000 square meters per gram.

21. The electrode of claim 14 where the metal fibers have a diameter from about 1 to about 14 microns.

22. The electrode of claim 14 containing from about 20 to about 98% carbon.

23. The electrode of claim 14 where the metal is selected from the group consisting of aluminum, titanium, vanadium, chromium, iron, cobalt, nickel, copper, zinc, zirconium, niobium, molybdenum, ruthenium, rhodium, palladium, silver, cadmium, indium, tin, hafnium, tantalum, tungsten, rhenium, osmium, platinum, gold, antimony, beryllium, iridium, silicon, and combinations thereof.

24. The electrode of claim 14 where the metal is a conducting alloy.

25. The electrode of claim 14 where the conducting alloy is selected from the group consisting of constantan, hastelloy, nichrome, inconel, monel, carpenter'"'"'s metal, stainless steels, other steels, and other iron alloys.

26. The electrode of claim 25 where the conducting alloy is a stainless steel.

27. The electrode of claim 14 where the electrically conducting material is a second metal and the composite is bonded to said second metal by sintering.