Method for reduction of sulfur products for gases by injection of powdered alkali sorbent at intermediate temperatures

• US 5,084,256 A
• Filed: 08/09/1990
• Issued: 01/28/1992
• Est. Priority Date: 05/29/1986
• Status: Expired due to Fees

• Current Assignee: Electric Power Research Institute Incorporated
• Original Assignee: Electric Power Research Institute Incorporated
• Inventors: Beittel, Roderick, McElroy, Michael W., Offen, George R., Bortz, Steven J.
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): BOLAM, BRIAN
• Application Number:
  US07/565,869
• Time in Patent Office: 537 Days
• Field of Search: 423/244
• US Class Current: 423/243.08
• CPC Class Codes: B01D 53/501 by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
• CPC Class Codes: B01D 53/508 by treating the gases with solids

Abstract

A method is provided for reducing the sulfur content of exhaust (flue) gas from a combustion installation manufacturing process, or chemical process comprising the step of injecting dry powder alkali hydrate sorbent directly into intermediate temperature (800°-1200° F.) combustion/process gases. The alkali hydrate sorbent reacts rapidly with the sulfur-containing gases in this temperature regime to produce primarily alkali sulfites. The unreacted portion of the sorbent largely remains in the form of an alkali hydrate and may react further with residual sulfur, especially in the presence of water, at lower temperatures. A novel combustion chamber is also provided having an injection means for injecting alkali hydrate sorbent into a combustion volume where the temperature is in the range of 800°-1200° F., to cause a predetermined reaction of the alkali hydrate sorbent with SO₂ and the combustion gases to produce primarily alkali sulfites with the unreacted sorbent remaining substantially as alkali hydroxide.

Claims

1. A method for reducing the sulfur content of a combustion gas from a combustion installation comprising the step of injecting a dry powdered sorbent selected from the group consisting of calcium hydrate, magnesium hydrate, dolomite hydrate and mixtures thereof, into sulfur-containing gases at a location in said combustion installation where combustion gases are between 800 and 1200 degrees F., without said injection significantly decreasing the temperature of said gases, said injection of dry powdered sorbent providing during the residence time of said gases within said combustion installation a chemical reaction of said sorbent with SO₂ and the combustion gases that converts at least 25 percent of said sorbent to sulfite, with the remaining unreacted sorbent being substantially alkali hydroxide.

2. The process according to claim 1 wherein said sorbent has a surface area greater than 20 square meters per grams.

3. The process according to claim 1 wherein said sorbent has a porosity greater than 0.3 cubic centimeters per gram for all the pores with a diameter less than 0.25 microns.

4. The process according to claim 1 wherein 90 percent by weight of said sorbent has a diameter smaller than 3 microns.

5. A process according to claim 1 wherein said sorbent is injected coflowing with said combustion gas.

6. A process according to claim 1 wherein said sorbent is injected counterflowing with said combustion gas.

7. A process according to claim 1 wherein said sorbent is injected cross-flowing with said combustion gas.

8. A process according to claim 1 wherein said sorbent is injected into said sulfur-containing gases as an aqueous solution or particulate suspension.

9. A process according to claim 1 wherein said sorbent is injected into said sulfur-containing gases as an aqueous solution.

10. A process according to claim 1 wherein said sorbent is injected into said sulfur-containing gases as a particulate suspension.

11. A process according to claim 1 further including the steps of reducing the temperature of said volume of gas to 150-350 degrees F temperature range and humidifying the mixture comprising alkali sulfite, alkali hydroxide and said gas to provide further reduction of SO₂ by means of the reaction of said alkali hydroxide with the remaining SO₂.