Defined and delaminated kaolin product

• US 5,085,707 A
• Filed: 06/14/1990
• Issued: 02/04/1992
• Est. Priority Date: 05/23/1988
• Status: Expired due to Term

• Current Assignee: Georgia Kaolin Company Incorporated
• Original Assignee: Georgia Kaolin Company Incorporated
• Inventors: Bundy, Wayne M., Manasso, John A., Berberich, Joseph P.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): Wright, Alan
• Application Number:
  US07/537,979
• Time in Patent Office: 600 Days
• Field of Search: 106/484, 106/486, 106/468, 501/144, 162/181.8
• US Class Current: 106/486
• CPC Class Codes: C01P 2004/32 Spheres
• CPC Class Codes: C01P 2004/51 Particles with a specific particle size distribution
• CPC Class Codes: C01P 2004/52 highly monodisperse size distribution
• CPC Class Codes: C01P 2004/61 Micrometer sized, i.e. from 1-100 micrometer
• CPC Class Codes: C01P 2004/62 Submicrometer sized, i.e. from 0.1-1 micrometer
• CPC Class Codes: C01P 2004/84 one phase coated with the other
• CPC Class Codes: C01P 2006/22 Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
• CPC Class Codes: C01P 2006/60 Optical properties, e.g. expressed in CIELAB-values
• CPC Class Codes: C01P 2006/80 Compositional purity
• CPC Class Codes: C04B 33/04 Clay; Kaolin
• CPC Class Codes: C09C 1/42 Clays
• CPC Class Codes: D21H 17/68 siliceous, e.g. clays
• CPC Class Codes: D21H 17/69 modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
• CPC Class Codes: D21H 19/40 siliceous, e.g. clays
• CPC Class Codes: D21H 19/42 at least partly organic
• CPC Class Codes: D21H 21/52 Additives of definite length or shape

Abstract

A defined and delaminated kaolin composition exhibiting high opacity is produced by defining and delaminating a base kaolin clay so as to reduce its colloidal content. The defined and delaminated kaolin composition may also be treated with hexamethylenediamine and aluminum sulfate to further enhance opacity. Whether treated or untreated, the defined and delaminated kaolin composition functions superiorly in paper coating formulations, alone or blended with known coating clays, improving the opacity, print gloss, sheet gloss and printability of paper sheet coated therewith.

Claims

1. A kaolin paper coating composition comprising a suspension in water of defined and delaminated uncalcined kaolin clay particles having a narrow particle size distribution such that at least 70% of the kaolin particles therein have a particle size of at least 0.3 microns and less than 2 microns in equivalent spherical diameter, said kaolin particles being produced by delaminating and defining a base kaolin clay which is an uncalcined kaolin having a brightness of at least 89, so as to remove a substantial portion of the colloidal particle content from the base kaolin clay, and having increased opacifying and gloss properties when compared to the base kaolin clay.

2. A coating composition as recited in claim 1 comprising a blend of

a. about 40% to about 55% by weight of dry clay of a delaminated but undefined uncalcined kaolin clay;

b. about 10% to about 20% by weight of dry clay of a No. 1 kaolin coating clay; and

c. about 30% to about 50% by weight of dry clay of said defined and delaminated uncalcined kaolin clay.

3. A coating composition as recited in claim 1 consisting essentially of

a. about 20% by weight of dry clay of a No. 1 kaolin coating clay, a No. 2 kaolin coating clay, and mixtures thereof;

and

b. about 80% by weight of dry clay of said defined and delaminated uncalcined kaolin clay.

4. A coating composition suitable for coating paper sheets which is a blend comprising

a. a defined and delaminated uncalcined kaolin clay having a narrow particle size distribution such that at least 70% of the kaolin particles by weight are between 0.3 microns and 2 microns equivalent spherical diameter, said kaolin clay being produced by defining and delaminating a base kaolin clay which is an uncalcined kaolin having a brightness of at least 89 so as to remove a substantial portion of the colloidal particle content from the base kaolin clay;

and

b. up to 20% by weight of at least one kaolin clay selected from the group consisting of a delaminated but undefined uncalcined kaolin clay, a No. 1 kaolin coating clay, a No. 2 kaolin coating clay, and mixtures thereof.

5. A coating composition as recited in claim 4 wherein said defined and delaminated uncalcined kaolin clay as an aqueous slurry is surface and hexamethylenediamine subsequent to delaminating and defining.

6. A coating composition as recited in claim 5 wherein said defined and delaminated uncalcined kaolin clay comprises at least about 30% by weight of the kaolin clay in said blend.

7. A coating composition as recited in claim 6 consisting essentially of

a. about 40% to about 55% by weight of dry clay of a delaminated but undefined uncalcined kaolin clay;

b. about 10% to about 20% by weight of dry clay of a No. 1 kaolin coating clay; and

c. about 30% to about 50% by weight of dry clay of said defined, delaminated and treated uncalcined kaolin clay.

8. A coating composition as recited in claim 6 consisting essentially of

a. about 20% by weight of dry clay of a No. 1 kaolin coating clay, a No. 2 Kaolin coating clay, and mixtures thereof;

and

b. about 80% by weight of dry clay of said defined, delaminated and treated uncalcined kaolin clay.