Light modulating material and method for preparing same

• US 5,087,387 A
• Filed: 11/16/1990
• Issued: 02/11/1992
• Est. Priority Date: 08/28/1987
• Status: Expired due to Term

• Current Assignee: Kent State University
• Original Assignee: Kent Research Corporation (Kent Display Systems Incorporated)
• Inventors: Mullen, Patrick W., Nobile, Frederick E.
• Primary Examiner(s): Stoll, Robert L.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US07/616,747
• Time in Patent Office: 452 Days
• Field of Search: 252/299.1, 252/582, 252/589, 350/347 V, 350/350 R, 350/350 S, 428/1
• US Class Current: 252/299.5
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal

Abstract

An improved light modulating material for use in electro-optic and thermo-optic display devices is produced by forming a homogeneous solution comprising an acrylic resin containing active hydrogen groups, a liquid crystal material, a diisocyanate or epoxide, and a solvent. The homogeneous solution is preferably applied to a conductive substrate and the solvent is then evaporated, causing phase separation resulting in formation of a liquid crystal phase dispersed within a solid polymer matrix. Application of an electric field to the substrate causes the liquid crystal material to align, which in turn causes the coating to switch from substantially translucent to substantially transparent. If the electric field is removed the light modulating material again becomes substantially translucent. Switching times can be improved by incorporating a titanate or zirconate organometallic material into the light modulating material.

Claims

1. A light modulating material comprising a liquid crystal phase formed within a polymer matrix, the polymer matrix comprising:

an acrylic resin having active hydrogen groups selected from the group consisting of hydroxy-functional acrylic resins;

an organometallic material selected from the group consisting of titanates, zirconates and mixtures thereof; and

a cross-linking agent selected from the group consisting of diisocyanates for reacting with the hydroxy-functional acrylic resin to form a urethane acrylic copolymer;

the light modulating material being capable of reversibly switching between a substantially translucent state and a substantially transparent state when subjected to an electric or magnetic field.

2. The light modulating material of claim 1, wherein the organometallic material comprises a titanate selected from the group consisting of neopentyl (diallyl) oxy, tri (dodecyl) benzene-sulfonyl titanate;

neopentyl (diallyl) oxy, tri (N-ethylenediamino) ethyl titanate; and

mixtures thereof.

3. The light modulating material of claim 1, wherein the organometallic material comprises a zirconate selected from the group consisting of neopentyl (diallyl) oxy, tri (dodecyl) benzene-sulfonyl zirconate;

neopentyl (diallyl) oxy, tri (N-ethylene diamino) ethyl zirconate; and

mixtures thereof.

4. A light modulating material comprising a liquid crystal phase formed within a polymer matrix comprising a urethane-acrylic copolymer, and an organometallic material selected from the group consisting of titanates, zirconates and mixtures thereof, the material being capable of reversibly switching between a substantially translucent state and a substantially transparent state when subjected to an electrical or magnetic field.

5. A light modulating material comprising a liquid crystal phase formed within a polymer matrix, the polymer matrix comprising:

an acrylic resin having active hydrogen groups selected from the group consisting of carboxy-functional acrylic resins; and

a cross-linking agent selected from the group consisting of epoxides for reacting with the carboxy-functional acrylic resin to form an epoxy-acrylic copolymer;

the light modulating material being capable of switching between a substantially translucent state and a substantially transparent state when subjected to an electrical or magnetic field.

6. The light modulating material of claim 5, wherein the liquid crystal phase is formed upon phase separation resulting from evaporation or cooling of a homogeneous solution comprising liquid crystal material and the acrylic resin.

7. The light modulating material of claim 6, wherein the liquid crystal phase has optic axes which are normally randomly oriented to scatter light and provide a substantially translucent appearance for said light modulating material, the optic axes being aligned by the application of a field to render the light modulating material substantially transparent.

8. The light modulating material of claims 5, 6, or 7 wherein the polymer matrix further comprises an epoxy-acrylic copolymer.

9. The light modulating material of claim 5, further comprising an organometallic material selected from the group consisting of titanates, zirconates and mixtures thereof.

10. An electro-optic device comprising the light modulating material of claim 8.

11. A thermo-optic device comprising the light modulating material of claims 5, 6, or 7.

12. A light modulating material comprising a liquid crystal phase formed within a polymer matrix, the polymer matrix comprising an epoxy-acrylic copolymer formed by reacting a carboxy-functional acrylic resin with an epoxide within the polymer matrix, the light modulating material being capable of reversibly switching between a substantially translucent state and a substantially transparent state when subjected to an electrical or magnetic field.

13. A light modulating material comprising a liquid crystal phase interspersed with a urethane cross-linked hydroxy functionalized polymer, said polymer being formed by reacting hydroxy functional groups pendent from the polymeric chain with a cross-linking agent selected from the group consisting of isocyanates, the light modulating material being capable of reversibly switching between a translucent state and a transparent state when subjected to an electrical field or a magnetic field.

14. The light modulating material of claim 13, wherein the liquid crystal phase is formed by phase separation resulting from removal of solvent from a solution including liquid crystal, the hydroxy functionalized polymer and the isocyanate cross-linking agent.

15. The light modulating material of claim 13, wherein the liquid crystal phase is formed by phase separation resulting from cooling of a solution including liquid crystal, the hydroxy functionalized polymer and the isocyanate cross-linking agent.

16. The light modulating material of claim 13, wherein the liquid crystal phase has optic axes which are normally randomly oriented for scattering light, the optic axes being alignable by the application of a magnetic or electric field to render the light modulating material light transmissive.

17. The light modulating material of claim 13, wherein the hydroxy functionalized polymer comprises an acrylic polymer with pendent hydroxy groups.

18. The light modulating material of claim 13, wherein the liquid crystal phase comprises a nematic material.

19. The light modulating material of claim 13, wherein the liquid crystal phase comprises a nematic material and a chiral mesogenic material.

20. The light modulating material of claim 13, wherein the liquid crystal phase comprises a smectic material.

21. The electro-optic device comprising the light modulating material of claim 13.

22. A thermo-optic device comprising the light modulating material of claim 13.

23. The light modulating material of claim 13, further comprising an organometallic material selected from the group of titanates, zirconates and mixtures thereof.

24. The light modulating material of claim 13 wherein the liquid crystal phase comprises microdroplets dispersed in the urethane cross-linked hydroxy functionalized polymer.

25. A method of making a light modulating material comprising the steps of:

forming a solution of liquid crystal, hydroxy functionalized polymer and isocyanate cross-linking agent;

phase separating a liquid crystal phase from the polymer phase; and

,

allowing the isocyanate cross-linking agent to react with the hydroxy groups of the hydroxy functionalized polymer to form a urethane cross-linked hydroxy functionalized polymer interspersed with the liquid crystal phase.

26. The method of claim 25, wherein the isocyanate cross-linking agent, liquid crystal, and hydroxy functionalized polymer are dissolved in a solvent and the liquid crystal phase is phase separated by removal of the solvent.

27. The method of claim 25, wherein the hydroxy functionalized polymer, liquid crystal and isocyanate cross-linking agent are heated to form a solution and then allowed to cool to phase separate the liquid crystal phase.

28. The method of making a light modulating material comprising the steps of:

forming a solution of liquid crystal, carboxy functionalized polymer and epoxide cross-linking agent;

phase separating the liquid crystal phase from the polymer phase; and

allowing the epoxide cross-linking agent to react with the carboxy groups of the polymer to form an epoxy cross-linked carboxy functionalized polymer interspersed with the liquid crystal phase.

29. The method of claim 28, wherein the epoxy cross-linking agent, liquid crystal, and carboxy functionalized polymer are dissolved in a solvent and the liquid crystal is phase separated by removal of the solvent.

30. The method of claim 28, wherein the epoxy cross-linking agent, liquid crystal, and carboxy functionalized polymer are heated to form a solution and then allowed to cool to phase separate the liquid crystal.

31. A light modulating material comprising a liquid crystal phase interspersed with an epoxy cross-linked carboxy functionalized polymer, said polymer being formed by reacting carboxy functional groups pendent from the polymeric chain with a cross-linking agent selected from the group consisting of epoxides, the light modulating material being capable of reversibly switching between a translucent state and a transparent state when subjected to an electric field or a magnetic field.

32. The light modulating material of claim 31, further comprising an organometallic material selected from the group consisting of titanates, zirconates and mixtures thereof.

33. The light modulating material of claim 31, wherein the liquid crystal phase comprises microdroplets dispersed in the epoxy cross-linked carboxy functionalized polymer.