Carbon dioxide adsorbent and method for producing the adsorbent

• US 5,087,597 A
• Filed: 07/19/1990
• Issued: 02/11/1992
• Est. Priority Date: 07/19/1990
• Status: Expired due to Fees

• Current Assignee: Armada de La Republica de Venezuela
• Original Assignee: Armada de La Republica de Venezuela, Universidad Central de Venezuela
• Inventors: Sepulveda, Gonzalo, Molleja, Gregorio, Martinez, German, Esparragoza, Leon, Leal, Orlando, Bolivar, Carmelo
• Primary Examiner(s): Shine, W. J.
• Assistant Examiner(s): McGinty, Douglas J.
• Application Number:
  US07/554,551
• Time in Patent Office: 572 Days
• Field of Search: 55/68, 502/62, 502/401, 502/405, 502/407, 502/411, 502/84, 502/80, 423/230
• US Class Current: 502/62
• CPC Class Codes: B01J 20/06 comprising oxides or hydroxides of metals not provided for in group B01J20/04
• CPC Class Codes: B01J 20/103 comprising silica
• CPC Class Codes: B01J 20/12 Naturally occurring clays or bleaching earth
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: B01J 20/28014 characterised by their form
• CPC Class Codes: B01J 20/28019 Spherical, ellipsoidal or cylindrical
• CPC Class Codes: B01J 20/28061 being in the range 100-500 m2/g
• CPC Class Codes: B01J 20/28069 Pore volume, e.g. total pore volume, mesopore volume, micropore volume
• CPC Class Codes: B01J 20/28083 being in the range 2-50 nm, i.e. mesopores
• CPC Class Codes: B01J 20/3007 Moulding, shaping or extruding
• CPC Class Codes: B01J 20/3204 Inorganic carriers, supports or substrates
• CPC Class Codes: B01J 20/3217 Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
• CPC Class Codes: B01J 20/3257 the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
• CPC Class Codes: B01J 20/3425 of sorbents or filter aids comprising organic materials
• CPC Class Codes: B01J 20/3483 by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
• CPC Class Codes: B01J 2220/42 Materials comprising a mixture of inorganic materials materials coated or impregnated on a carrier B01J20/32
• CPC Class Codes: B01J 2220/64 In a syringe, pipette, e.g. tip or in a tube, e.g. test-tube or u-shape tube in columns B01J2220/58
• CPC Class Codes: B01J 2220/66 Other type of housings or containers not covered by B01J2220/58 - B01J2220/64

Abstract

A reversible adsorbent for carbon dioxide, which can be used as a decontaminant of closed environments, has been devised. It consists of a novel material formed by a surface modified silica gel with active sites for the chemisorption of CO₂ at room temperature combined with a clay which acts as an agglomerant in a preferred weight ratio of 80/20. The carbon dioxide is liberated under heating at 110° C. The surface area of the material ranges between about 120 and about 240 m² /g with a total pore volume between about 0.4 and about 0.8 cc/g where about 80% of the total pore volume contains pores of a diameter between about 60 Å and about 180 Å. The material is capable of adsorbing between about 7.5 and 11.7 cc of dry CO₂ per gram and can be regenerated between about 70° and about 150° C. without losing any adsorptive capacity. Dry carbon dioxide is chemisorbed as a surface ammonium carbamate which becomes a surface bicarbonate in the presence of water.

Claims

1. A method for producing a reversible adsorbent having between about 2.0 and 3.0 molecules of modifying agent per square nanometer and displaying near infrared bands at 7220, 6720, 6557, 5970-5480, 5270, 4945 and 4545 cm^-1 for use in the removal of carbon dioxide comprising the steps of:

providing a silica gel;

providing a clay material;

mixing said silica gel with said clay material to obtain a material containing between about 10 wt. % and about 30 wt. % of clay;

forming an extruded solid material from said silica gel-clay material; and

treating said extruded solid material in a solution containing a surface modifying agent so as to modify chemically the surface of said extruded solid material and thereby form said reversible adsorbent for removing carbon dioxide.

2. A method according to claim 1 wherein said forming step comprises:

controlling the water content of said silica gel-clay material between about 35 wt. % and about 50 wt. % so as to obtain a desired level of plasticity;

passing said silica gel-clay material through an extruder to form a silica gel-clay extrudate; and

drying said extrudate.

3. A method according to claim 2 wherein said drying step comprises drying said extrudate at a temperature between from about 27°

C. to about 270°

C. for a time period in the range of from about 1 hr. to about 4 hrs. so as to produce a material having a chemical composition containing from about 76 wt. % to about 92 wt. % SiO₂, from about 7 wt. % to about 20 wt. % Al₂ O₃, from about 0.6 wt. % to about 2.0 wt. % Fe₂ O₃ and the balance essentially impurities.

4. A method according to claim 1 wherein said treating step comprises treating said extruded solid material in said solution at a temperature between about 50°

C. to about 150°

C. for between about 4.5 hours to about 30 hours.

5. A method according to claim 1 further comprising:

triturating and milling said silica gel to a particle size between about 40 mesh and about 200 mesh prior to said mixing step; and

triturating and milling said clay to a particle size between about 20 mesh and about 400 mesh.

6. A method according to claim 1 wherein said silica gel providing step comprises providing a silica gel having a composition based on total dry weight which consists essentially of from about 96.0 to about 99.7 wt. % SiO₂, from about 0.05 to about 0.15 wt. % Al₂ O₃, from about 0.01 to about 0.03 wt. % TiO₂, from about 0.005 to about 0.015 wt. % Fe₂ O₃, from about 0.06 to about 0.08 wt. % CaO, from about 0.05 to about 0.07 wt. % Na₂ O;

from about 0.02 to about 0.04 wt. % ZrO₂ and from about 0.02 to 0.04 wt. % trace elements.

7. A method according to claim 1 wherein said clay providing step comprises providing a natural clay having a composition based on total dry weight which consists essentially of from about 3.0 to about 10.0 wt. % Fe₂ O₃, from about 40 to about 75 wt. % SiO₂, from about 10 to about 25 wt. % Al₂ O₃, from about 0.1 to about 0.8 wt. % MgO, from about 0.3 to about 2.6 wt. % K₂ O and from about 0.1 to about 1.5 wt. % Na₂ O.

8. A method according to claim 1 further comprising:

washing said surface modified material with at least one solvent at a temperature between about 25°

C. to about 100°

C. for a time period between about 0.3 hours to about 3.0 hours; and

drying said surface modified material in a continuous flow of nitrogen at a temperature of about 50°

C. to about 80°

C. for between about 20 to about 48 hours.

9. A method according to claim 4 further comprising:

agitating said extruded solid material in said solution at an agitation velocity between about 60 to about 200 rpm. during said treating step.

10. A method according to claim 9 wherein said agitating step comprises stirring said extruded material in said solution by bubbling pure deoxygenated nitrogen at a volume space velocity of between about 0.18 to about 0.80 h^-1.

11. A method according to claim 4 wherein:

said treating step further comprises treating said extruded material in a solution containing a modifying silane agent present in a concentration between about 5 vol. % and about 75 vol %.

12. A method according to claim 11 wherein said modifying silane agent is an aminoalkoxysilane.

13. A method according to claim 12 wherein said aminopolyalkoxysilane is selected from the group consisting of 3-aminopropyltriethoxysilane, N-2-Aminoethyl-3 aminopropyltrimethoxysilane and N-Methyl-3 aminopropyltrimethoxysilane.

14. A method according to claim 11 wherein the concentration of said silane modifying reagent ranged between about 13 and about 38 vol. %.

15. A method according to claim 8 wherein said washing step comprises washing said surface modified material with between about 1 to about 5 liters of said at least one solvent per kilogram.

16. A method according to claim 8 wherein said at least one solvent in said washing step is selected from the group consisting of liquid alkanes and aromatic hydrocarbons.

17. A method according to claim 16 wherein said liquid alkane is selected from the group consisting of n-pentane, n-hexane, n-heptane and mixtures thereof.

18. A method according to claim 16 wherein said aromatic hydrocarbon is selected from the group consisting of benzene, toluene, o-,m-,p-xylene and mixtures thereof.

19. A method according to claim 1 wherein:

said silica gel providing step comprises providing a silica gel having a particle size between about 60 and about 80 mesh; and

said mixing step comprises mixing said silica gel with clay and obtaining a material containing between about 70 wt. % to about 90 wt. % silica gel.

20. A method according to claim 19 wherein said forming step comprises controlling the water content of said silica gel-clay material between about 42 wt. % and about 48 wt. %.

21. A method according to claim 20 further comprising:

drying said extruded material prior to said treating step at a temperature between about 27°

C. to about 270°

C. for a time period between about 1 hour to about 4 hours.

22. A method according to claim 20 further comprising:

drying said extruded material prior to said treating step at a temperature between about 100°

C. to about 250°

C. for a time period between about 2 to about 3 hours.

23. A method according to claim 22 wherein said treating step comprises agitating the mixture of said extruded solid material and said surface modifying reagent with an agitation velocity of from about 80 to about 120 rpm.

24. A method according to claim 23 wherein said agitating step comprises stirring said mixture with a flow of pure deoxygenated nitrogen at a volume space velocity in the range of from about 0.30 to about 0.50-h^-1.

25. A method according to claim 24 wherein said treating step comprises:

placing from about 5 to about 25 kilograms of said extruded material in a reactor;

adding between from about 1.2 to about 15.0 liters of said surface modifying reagent; and

transferring between about 5 to about 25 liters of a solvent to said reactor.

26. A method according to claim 8 wherein said drying step comprises drying said surface modified material in a first stage using a flow of pure, deoxygenated nitrogen using a volume space velocity between about 0.2 h^-1 to about 0.3 h^-1 at a temperature between about 60°

C. to about 70°

C. for a time period between about 20 hours to about 48 hours.

27. A method according to claim 26 wherein said drying step further comprises drying said surface modified material in a second stage in vacuo at a pressure between about 0.1 and about 10 millimeters of Hg at a temperature between about 80°

C. and about 140°

C. for a time period between about 1 hour to about 6 hours.

28. A method according to claim 27 wherein said second stage drying step comprises drying said material in vacuo at between about 1.0 to about 5.0 millimeters of Hg at a temperature between about 100°

C. to about 110°

C. for a time period between about 1 hour to about 3 hours.

29. A reversible adsorbent for use in the removal of carbon dioxide from a gas, said adsorbent comprising a silica gel whose surface has been modified by an aminoalkoxysilane, said silica gel having a chemical composition consisting essentially of from about 70 to 80 wt. % SiO₂, from about 10 to about 15 wt. % Al₂ O₃, from about 1.0 to 1.5 wt. % Fe₂ O₃ from about 8 to about 12 wt. % organic residue and from about 0.5 to about 0.9 wt. % trace impurities.

30. An adsorbent according to claim 29 further comprising said silica gel having a surface modified by aminoorganic residues chemically bonded in an amount between about 0.50 and about 1.26 mmoles per gram as determined by C, N, H microanalysis and near infrared spectroscopy.

31. An adsorbent according to claim 30 wherein said surface is modified with from about 0.50 to about 1.26 mmoles of --CH₂ CH₂ CH₂ NH₂ per gram of adsorbent.

32. An adsorbent according to claim 29 wherein said adsorbent shows near infrared bands at 7220, 6720, 6557, 5970-5480, 5270, 4945 and 4545 cm^-1.

33. An adsorbent according to claim 29 wherein said adsorbent has a surface area between about 120 and about 240 m² /g and a total pore volume between about 0.4 cc/g and about 0.8 cc/g where about 80% of the total pore volume contains pores having a diameter between about 60 Å

and about 180 Å

.

34. An adsorbent according to claim 29 wherein said modified surface has between about 2 and about 3 molecules of amino modifying agent per square nanometer.

35. An adsorbent according to claim 29 wherein said adsorbent has a heat of adsorption of carbon dioxide between about 7 and about 17 Kcal/mol.

36. An adsorbent according to claim 29 wherein the carbon dioxide adsorption process yields a carbamate surface moiety when the carbon dioxide is dry and a bicarbonate surface species when the carbon dioxide is humid.

37. An adsorbent according to claim 29 wherein said adsorbent adsorbs between about 7.5 and about 11.7 cc of dry CO₂ per gram.

38. An adsorbent according to claim 29 wherein said adsorbent is regenerable at a temperature between about 70°

C. and about 150°

C. without losing substantially any adsorptive capacity.

39. A method for producing a reversible adsorbent for use in the removal of carbon dioxide comprising the steps of:

mixing a material containing silica with a filler material so as to obtain a material containing between about 10 wt. % and about 30 wt. % of said filler material;

adding water to said material in an amount sufficient to provide said material with a water content in the range of from about 35 wt. % to about 50 wt. %;

extruding said material to form an extrudate;

placing said extrudate in a reactor;

adding a mixture of a silane surface modifying reagent in a concentration between about 5 vol. % and about 75 vol. % and a solvent in a concentration between about 25 vol. % and 95 vol. % to said reactor;

agitating said extrudate and said mixture at a temperature between about 50°

C. to about 150°

C. for between about 4.5 hours to about 30 hours to form said reversible adsorbent for removing carbon dioxide;

washing said adsorbent in a solvent; and

drying said absorbent.