Liquid crystal devices

• US 5,088,807 A
• Filed: 05/23/1989
• Issued: 02/18/1992
• Est. Priority Date: 05/23/1988
• Status: Expired due to Fees

• Current Assignee: Imperial Chemical Industries PLC (Nouryon BV)
• Original Assignee: Imperial Chemical Industries PLC (Nouryon BV)
• Inventors: Noakes, Timothy J., Hitomi, Chiyoji, Waters, Colin M., Pavey, Ian
• Primary Examiner(s): Hille, Rolf
• Assistant Examiner(s): Ho, Tan
• Application Number:
  US07/359,471
• Time in Patent Office: 1,001 Days
• Field of Search: 350/347, 350/331 R, 350/334, 350/46.17, 350/96.34, 428/1
• US Class Current: 349/91
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal
• CPC Class Codes: G02F 1/1334 based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
• CPC Class Codes: G02F 1/13345 Network or three-dimensional gels
• CPC Class Codes: G02F 1/1339 Gaskets; Spacers; Sealing of cells
• CPC Class Codes: G02F 1/13392 spacers dispersed on the cell substrate, e.g. spherical particles, microfibres

Abstract

A liquid crystal device comprises a layer of fibers or filaments (15) permeated with liquid crystal material, the layer (15) being located between electrodes (13, 14) by means of which an electric field can be applied across the layer to vary the transmissivity of the liquid crystal/fiber composite. The diameters of the fibers/filaments are selected so that the light transmissivity of the composite has reduced sensitivity with respect to mismatch of the refractive indices of the liquid crystal and the fibers/filaments.

Claims

1. A liquid crystal device comprising:

means for containing liquid crystal material,

means for applying one of an electric and magnetic field across the liquid crystal material, and

a permeable body of optically non-absorbing material permeated by the liquid crystal material such that light transmission through a composite, comprising said body and the liquid crystal material, is reduced in an off state of said field-applying means,

wherein said permeable body comprises at least one of fibers and filaments deposited to form a layer.

2. A device as claimed in claim 1 in which said fibers or filaments have diameters such that, in the field-off state, domain formation is promoted in the liquid crystal material on a scale such that at least 25% of light attenuation in the off-state is attributable to light scattering as a result of domain formation.

3. A device as claimed in claim 1 in which the ordinary refractive indices of the liquid crystal material and said fibers/filaments differ and the light transmissivity of said composite is at least 90% in the field-on liquid crystal-aligned state.

4. A device as claimed in claim 3 in which said refractive indices differ by at least 0.005.

5. A device as claimed in claim 3 in which said refractive indices differ by up to 0.01.

6. A device as claimed in claim 3 in which said refractive indices differ by up to 0.012.

7. A device as claimed in claim 1 in which at least a major proportion of said fibers/filaments have sub-micronic diameters.

8. A device as claimed in claim 1 in which 50% of said fibers/filaments have diameters no greater than 500 nm.

9. A device as claimed in claim 1 in which at least 70% of said fibers/filaments have diameters no greater than 500 nm.

10. A device as claimed in claim 1 in which the fibers/filaments have an average diameter less than 1 micron.

11. A device as claimed in claim 1 in which the fibers/filaments have an average diameter less than 750 nm.

12. A device as claimed in claim 1 in which the fibers/filaments have an average diameter less than 500 nm.

13. A device as claimed in claim 1 in which said permeable body comprises a mat of said fibers or filaments.

14. A device as claimed in claim 13, wherein said mat is a spun mat, that is, one produced by spinning.

15. A device as claimed in claim 1 in which, in the field-off state, the transmissivity of said composite is less than 30%.

16. A device as claimed in claim 1 in which, in the field-off state, the transmissivity of said composite is reduced predominantly by light scattering by domains formed in the liquid crystal material as a consequence of the presence of submicronic fibers or filaments therein.

17. A liquid crystal device comprising:

means for containing liquid crystal material,

means for applying one of an electric and magnetic field across the liquid crystal material,

and a permeable body of optically non-absorbing material permeated by the liquid crystal such that light transmission through a composite comprising said body and the liquid crystal material is reduced in an off-state of said field-applying means,

wherein said permeable body comprises at least one of fibers and filaments having diameters such that, in a field-on liquid crystal-aligned state of the device, light transmissivity of said composite is substantially insensitive to differences of up to 0.01 in ordinary refractive indices of the liquid crystal material and said fibers/filaments.

18. A device as claimed in claim 17 in which said fiber/filament diameters are such that, in the field-on, aligned state the light transmissivity of said composite varies by no more than 10% in response to ordinary refractive index differences ranging up to 0.01.

19. A device as claimed in claim 17 in which said fiber/filament diameters are such that, in the field-on, aligned state the light transmissivity of said composite varies by no more than 5% in response to ordinary refractive index differences ranging up to 0.01.

20. A device as claimed in claim 17 in which said insensitivity is exhibited for ordinary refractive index differences ranging up to 0.02.