Method for producing a solid electrolyte cell

• US 5,089,027 A
• Filed: 11/26/1990
• Issued: 02/18/1992
• Est. Priority Date: 11/26/1990
• Status: Expired due to Term

• Current Assignee: NGK Spark PLUG Company Limited (Niterra Co., Ltd.)
• Original Assignee: Gould, Inc. (Transdigm Group Incorporated)
• Inventors: Rossoll, Mary P., Revilock, Alan J.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US07/617,993
• Time in Patent Office: 449 Days
• Field of Search: 29/623.2, 29/623.4, 29/623.5, 29/623.1, 429/162, 429/192
• US Class Current: 29/623.2
• CPC Class Codes: H01M 10/0436 Small-sized flat cells or batteries for portable equipment
• CPC Class Codes: H01M 6/164 by the solvent
• CPC Class Codes: H01M 6/181 with polymeric electrolytes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/4911 including sealing
• CPC Class Codes: Y10T 29/49114 including adhesively bonding
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

A method for producing a solid electrolyte cell employing a poly(ethylene oxide) plus EC/PC-containing cathode; a poly(ethylene oxide) plus EC/PC-containing solid electrolyte separator and an anode strip, such as lithium, sandwiched between current collector sheets, such as cooper sheets, that are sealed at their peripheral area by an adhesive coated frame.

Claims

1. A method for producing a cell comprising the steps:

(a) depositing an active cathode material containing at least ethylene carbonate and propylene carbonate onto a first conductive current collector sheet and within an adhesive coated frame positioned at the peripheral area of the current collector sheet;

(b) depositing on the cathode material propylene carbonate or ethylene carbonate and propylene carbonate and allowing said deposit to be absorbed into the cathode material

(c) preparing a separator strip as follows;

(a'"'"') dissolving ethylene carbonate in propylene carbonate to form a solution;

(b'"'"') dissolving poly(ethylene oxide) in a solvent;

(c'"'"') adding a metal salt and a solvent along with the solution of step (a'"'"') to the dissolved poly(ethylene oxide) solution of step (b'"'"') to form a mix and mixing the mixture to form a homogeneous mixture and drying said mixture to less than about 30 ppm water and then forming a separator strip from said mixture;

(d) placing the separator strip onto the cathode material, said separator strip being smaller than the area of the cathode collector sheet and larger than the exposed area of the cathode material thereby leaving a portion of the adhesive coated frame area exposed;

(e) placing an anode strip onto the separator and within the frame thereby leaving an exposed portion of the area of ht adhesive coated frame;

(f) placing a second conductive current collector substantially the size of the first conductive current collector onto the anode and exposed area of the adhesive coated frame; and

(g) heating at least the frame of the cell assembly at a pressure and temperature for a period of time sufficient to secure the first current collector to the adhesive coated frame on one side and the opposite side of the adhesive coated frame to the second current collector thereby producing a sealed cell.

2. The method of claim 1 wherein in step (a) the active cathode material is deposited onto the first current collector sheet and then the adhesive coated frame is positioned around said active cathode material and onto the peripheral area of the first current collector sheet.

3. The method of claim 1 wherein said first current collector and said second current collector is selected from the group consisting of copper, nickel and stainless steel.

4. The method of claim 3 wherein said first current collector and said second current collector are copper.

5. The method of claim 1 wherein said cathode material contains an active cathode material selected from the group consisting of manganese dioxide, iron sulfides, copper sulfides, silver chromates, lead oxides, bismuth oxides, copper oxides, nickel oxides, carbon monofluoride, vanadium oxide, silver vanadium chromate and cadmium.

6. The method of claim 5 wherein the active cathode material is manganese dioxide.

7. The method of claim 1 wherein the homogenous mixture is deposited onto a releasable sheet and dried to less than about 30 ppm water.

8. The method of claim 7 wherein the solvent in step (b'"'"') is isopropyl alcohol.

9. The method of claim 7 wherein the solvent is step (c'"'"') is acetonitfile.

10. The method of claim 7 wherein the separator film contains less than about 20 ppm water.

11. The method of claim 6 wherein the cathode material contains less than 30 ppm water

12. The method of claim 1 wherein in step (f) the cell assembly is heated at a temperature . between 170°

C. to 175°

C. at a pressure of between 75 psig to 80 psig to seal the first current collector and the second current collector to the adhesive frame thereby producing a sealed cell.

13. The method of claim 1 wherein the cell assembly is encased in a plastic film.

14. The method of claim 1 wherein the cathode material comprises manganese dioxide and carbon and the anode strip is lithium.

15. The method of claim 1 wherein the cathode material comprises vanadium oxide;

and the anode strip is lithium.