Method for processing heavy crude oils

• US 5,089,114 A
• Filed: 11/22/1989
• Issued: 02/18/1992
• Est. Priority Date: 11/22/1988
• Status: Expired due to Fees

• Current Assignee: Instituto Mexicano Del Petrã³Leo (Gobierno Federal De Los Estados Unidos Mexicanos)
• Original Assignee: Instituto Mexicano Del Petrã³Leo (Gobierno Federal De Los Estados Unidos Mexicanos)
• Inventors: Perez, Rene H., Lorenzo, Roberto L., Mendizabal, Oscar H. B., Tovar, Abel M., Sanchez, Carlos G. A., Olmos, Leonardo M., Barba, Roldofo C.
• Primary Examiner(s): Chaudhuri, Olik
• Assistant Examiner(s): FOURSON III, GEORGE R
• Application Number:
  US07/439,670
• Time in Patent Office: 818 Days
• Field of Search: 208/86, 208/309, 208/44, 208/50, 208/87, 208/95
• US Class Current: 208/50
• CPC Class Codes: C10B 57/06 containing additives
• CPC Class Codes: C10G 21/003 Solvent de-asphalting
• CPC Class Codes: C10G 55/00 Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process

Abstract

A method for processing heavy crude oils comprising a) atmospheric distillation of a heavy crude oil having a high content of metals, asphaltenes and sulfur; b) solvent extraction of the atmospheric distillation residue to obtain an extract with characteristics equivalent to those which an atmospheric residue derived from light crude oil and a raffinate fraction, solid at ambient conditions, in which are concentrated the asphaltenes, metals and sulfur present in the original crude oil; c) vacuum distillation of the deasphalted extract, obtaining a light fraction or gas oils with characteristics adequate to be subjected to a secondary conversion process, plus a bottoms fraction or vacuum residue; d) treatment of the vacuum gas oils in a conversion stage and e) subjecting the bottoms of raffinate from the extraction stage to a metallurgical process, in admixture with cokeable coal and coke fines to production of metallurgical coke.

Claims

1. A method for processing heavy crude oils, which comprises

distilling a 100% heavy crude oil feedstock containing at least 7 weight percent n-pentane insolubles under atmospheric pressure to obtain an atmospheric distillation residue,

contacting said atmospheric distillation residue with a selective solvent comprising C₄ to C₇ aliphatic hydrocarbon or mixtures thereof in an extraction column to extract asphaltenes, carbon, sulfur and metals from said atmospheric distillation residue, said extraction column having a top temperature of 50°

-250°

C., and a bottom temperature of 40°

-230°

C. while being operated under a pressure 3-40 kg/cm² with a solvent-hydrocarbon volume ratio of 2;

1 to 10;

1,

withdrawing an extract fraction and a raffinate fraction rich in asphaltenes from said extraction column, said extract fraction having an API gravity of 10-18, an SSF viscosity at 50°

C. of 100 to 3,500, 1.0-75 weight percent insolubles in n-pentane and 0.20-5.0 weight percent insolubles in n-heptane, a Ramsbottom carbon of 4.0-12.0 weight percent, 2.0 to 5.0 weight percent sulfur and 75 to 250 ppm metals comprising nickel and vanadium,

subjecting said extract fraction to vacuum distillation in a vacuum distillation column at a temperature of 300°

C. to 540°

C. to recover a gas oil stream and a residue stream,

catalytically cracking said gas oil stream and feeding said residue to a viscosity breaking unit and viscosity breaking the residue stream, and

admixing said asphaltene-rich raffinate fraction with coking coal and coke fines and subjecting the resulting mixture to coking under conditions to produce metallurgical coke.

2. The process of claim 1, whereby the raffinate fraction is ground to finely divided particles having an average particle diameter of less than 3.2 mm and is used in admixture with said cokeable coal to produce said metallurgical coke.

3. The process of claim 2, wherein said raffinate fraction constitutes at least 4 weight percent of said admixture.

4. The process of claim 3, wherein said raffinate fraction constitutes from about 2 to about 10 weight percent of said admixture.

5. The process of claim 3, wherein said raffinate fraction is admixed with cokeable coal having a particle size less than 3.2 mm, and coke fines having a particle size of less than 20 mm.

6. The process of claim 1, wherein said raffinate fraction has a density of 0.9-1.4 g/cm³, a Ramsbottom carbon of 30-50 weight percent, 60-90 weight percent n-pentane insolubles, 50-80 weight percent n-heptane insolubles, 5-8 weight percent sulfur and a melting point of 120°

-200°

C.

7. The process of claim 1, wherein said raffinate fraction contains 750-3,000 ppm metals comprising nickel and vanadium.

8. The process of claim 1, wherein said atmospheric distillation residue is a bituminous material having an initial boiling temperature of from 300°

to 400°

C.

9. The process of claim 1, wherein said selective solvent is normal pentane, normal hexane, or normal heptane.

10. The process of claim 1, wherein said coking is conducted at a temperature of from about 1100°

to about 1400°

C. under atmospheric pressure for a period of from about 15 to about 18 hours.