Cleaning compositions with bleach-stable colorant

• US 5,089,162 A
• Filed: 05/08/1989
• Issued: 02/18/1992
• Est. Priority Date: 05/08/1989
• Status: Expired due to Fees

• Current Assignee: Lever Brothers Company, Division Of Conopco, Inc.
• Original Assignee: Lever Brothers Company, Division Of Conopco, Inc.
• Inventors: Mantell, Carlene M., Rapisarda, Anthony A.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Beadles-Hay, A.
• Application Number:
  US07/348,549
• Time in Patent Office: 1,016 Days
• Field of Search: 252/187.24, 252/187.25, 252/187.26, 252/187.33, 252/187.34, 252/102, 252/98, 252/174.11, 252/524, 252/542, 252/174.25, 252/94, 252/95, 252/99
• US Class Current: 510/101
• CPC Class Codes: C11D 3/40 Dyes ; Pigments

Abstract

Cleaning compositions contain a bleach-stable water dispersible or water-soluble yellow colorant and either a chlorine bleach or an oxygen bleach. The compositions may take the form of automatic dishwashing detergents, in granular or liquid form, and preferably also have a lemon-like scent to compliment the yellow color.

Claims

1. A cleaning composition comprising:

a) chlorine bleach is an amount providing 0.01-5% available chlorine to the composition; and

b) 0.0005-0.2% of a relatively water-soluble or water-dispersible colorant which is color stable to chlorine bleach, which colorant is selected from the group consisting of Pigment Yellow 14, Pigment Yellow 74, Pigment Yellow 108, Pigment Yellow 109, Direct Yellow 28, Direct Yellow 29, Direct Dye Colour Index Number 19550 and zinc chromate.

2. A liquid autodish detergent according to claim 1 further comprising:

a) 1-40% silicate;

b) 0-3% surfactant;

c) 5-90% builder;

d) 0-8% of a thickener; and

e) 0.01-5% of a stabilizer;

f) 0.02-2% of a defoamer; and

g) balance water.

3. The autodish detergent according to claim 2 further comprising 0.002-2% of a perfume composition having perfume selected from the group consisting of dipentene, lemon aldehyde, litsea cubeba oil, lemonile or mixtures thereof.

4. The composition according to claim 3 wherein the colorant is selected from the group consisting of Pigment Yellow 108, Direct Yellow 28, Direct Yellow 29, Direct Dye Colour Index Number 19550, and zinc chromate.

5. The composition according to claim 4 where the perfume composition further comprises one or more of allyl trimethyl hexanone, citronellol, dimyrcetol (dihydromyrcenol/2,6-dimethyl-7-octen-2-ol), dipentene 122, galoxolide 50, geranyl nitrile, hexyl cinnamic aldehyde, isobornyl acetate, lemon terpenes, lime alcohol, lime terpenes, methyl heptenone, methyl nonyl ketone, orivone (4-tertiary pentacyclo hexanone), terpinyl acetate extra, tetrahydro muguol, and 6-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene.

6. The composition according to claim 5 wherein the perfume composition further comprises one or more of alcohol C-8, citrotone B, lime alcohol, 3-nonanone, Acetal S Acetate C-9, Alcohol C-9, allyl cyclohexyl propionate, amyl benzoate, cyclo galbanate, decyl methyl ether, Folione, geranyl ethyl ether, greenyl acetate, iso propyl quinolene, linalyl propionate, methyl chavicol, methyl diphenyl ether, methyl octine carbonate, opopanax oil, paracresyl methyl ether, Peru balsam resin, phenyl ethyl butyrate and tetra hydro myrcenol.

7. The composition according to claim 5 wherein the colorant is selected from the group consisting of Pigment Yellow 108, Direct Yellow 28, Direct Yellow 29, Direct Dye Colour Index Number 19550 and zinc chromate.

8. The composition according to claim 7 wherein the colorant is Direct Yellow 28.

9. The composition according to claim 3 wherein the perfume composition further comprises one or more of alcohol C-8, citrotone B, lime alcohol, 3-nonanone, Acetal S acetate C-9, Alcohol C-9, allyl cyclohexyl propionate, amyl benzoate, cyclo galbanate, decyl methyl ether, Folione, geranyl ethyl ether, greenyl acetate, iso propyl quinolene, linalyl propionate, methyl chavicol, methyl diphenyl ether, methyl octine carbonate, opopanax oil, paracresyl methyl ether, Peru balsam resin, phenyl ethyl butyrate and tetra hydro myrcenol.

10. A gel autodish composition according to claim 1 further comprising:

a) 1-40% silicate;

b) 0-3% surfactant;

c) 5-90% builder;

d) 0-5% thickener of chlorine stable polymeric thickener;

e) 0-5stabilizer;

f) 0.02-2% defoamer; and

g) balance water.

11. The composition according to claim 10 further comprising 0.001-2% of a perfume composition having perfume selected from the group consisting of dipentene, lemon aldehyde, litsea cubeba oil, lemonile or mixtures thereof.

12. A granular autodish detergent composition according to claim 1 further comprising:

a) 1-40% silicate;

b) 0.1 to 10% nonionic surfactant;

c) 5-90% builder; and

d) 0-60% filler material.

13. Composition of claim 1 is a container which is a bottle, box or sachet at least part of which is substantially transparent or translucent.

14. A cleaning composition comprising:

a) 0.5-20% of an oxygen bleach;

b) 0.0005-0.2% of a colorant selected from the group consisting of Pigment Yellow 14, Pigment Yellow 74, Pigment Yellow 108, Pigment Yellow 109, Direct Yellow 28, Direct Yellow 29, Direct Dye Colour Index Number 19550 and zinc chromate; and

c) 0.5-2% enzyme,

the composition being substantially free from chlorine bleach agent.