Thermal transfer ribbon

• US 5,089,350 A
• Filed: 11/03/1989
• Issued: 02/18/1992
• Est. Priority Date: 04/28/1988
• Status: Expired due to Term

• Current Assignee: NCR Corporation
• Original Assignee: NCR Corporation
• Inventors: Puckett, Richard D., Obringer, Thomas J., Talvalkar, Shashi G.
• Primary Examiner(s): Schwartz, Pamela R.
• Application Number:
  US07/431,692
• Time in Patent Office: 837 Days
• Field of Search: 428/216, 428/207, 428/336, 428/484, 428/488.1, 428/690, 428/913, 428/914, 428/195, 428/522
• US Class Current: 428/32.84
• CPC Class Codes: B41M 5/385 characterised by the transferable dyes or pigments infrared absorbing dyes B41M5/465
• CPC Class Codes: B41M 5/392 Additives, other than colour forming substances, dyes or pigments, e.g. sensitisers, transfer promoting agents
• CPC Class Codes: B41M 5/395 Macromolecular additives, e.g. binders
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 428/914 Transfer or decalcomania
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

A thermal transfer ribbon includes a substrate and a layer thereon comprising a mixture of an emulsion essentially consisting of hydrocarbon, paraffin and carnauba waxes and an acetate copolymer, and a fluorescent color coating essentially containing a fluorescent pigment, a color toner and a filler.

Claims

1. A thermal transfer ribbon for use in nonimpact printing comprising a substrate and a thermal transfer layer which is formed from a mixture comprising the combination of a wax emulsion containing as essential ingredients about 20 to 45% oxidized, isocyanated hydrocarbon wax, about 35 to 65% paraffin wax mixture of solid crystalline hydrocarbons of the methane series derived from the paraffin distillate portion of crude petroleum, about 5 to 30% carnauba wax and about 3 to 15% ethylene vinyl acetate copolymer resin in a solvent solution and a fluorescent color coating containing as essential ingredients about 5 to 15% orange fluorescent pigment, about 1 to 10% white fluorescent pigment, and about 15 to 30% color toning pigment, the fluorescent pigments in the thermal transfer ribbon having a fluorescence greater than 10 postage meter units, the thermal transfer layer providing a transferred image of a color having a measure of lightness (L) in the range of 40 to 50, a measure (a) on the red-green axis and a measure (b) on the blue-yellow axis, and a total color difference value (Δ

) of the transferred image not to exceed 10 when using the formula (Δ

)=√

(Δ

L)² +(Δ

a)² +(Δ

b)² as measured on the Hunter Color Meter.

2. The ribbon of claim 1 wherein the first-mentioned fluorescent pigment is reddish-orange.

3. The ribbon of claim 1 wherein the color toning pigment is red.

4. A thermal transfer ribbon for use in nonimpact printing comprising a substrate and a thermal transfer coating which is formed from a mixture comprising the combination of a wax emulsion containing as essential ingredients about 20 to 45% oxidized, isocyanated hydrocarbon wax, about 35 to 65% paraffin wax mixture of solid crystalline hydrocarbons of the methane series derived from the paraffin distillate portion of crude petroleum, about 5 to 30% carnauba wax and about 3 to 15% ethylene vinyl acetate copolymer resin in a solvent solution and a fluorescent color coating containing as essential ingredients about 5 to 20% fluorescent pigment, about 1 to 10% of one toning pigment, and about 5 to 20% of another toning pigment, the fluorescent pigment in the thermal transfer ribbon having a fluorescence greater than 10 postage meter units, the thermal transfer coating providing a transferred image of a color having a measure of lightness (L) in the range of 40 to 50, a measure (a) on the red-green axis and a measure (b) on the blue-yellow axis, and a total color difference value (Δ

) of the transferred image not to exceed 10 when using the formula (Δ

)=√

(Δ

L)² +(Δ

a)² +(Δ

b)² as measured on the Hunter Color Meter.

5. The ribbon of claim 4 wherein the fluorescent pigment is reddish-orange.

6. The ribbon of claim 4 wherein the first-mentioned toning pigment is scarlet.

7. A thermal transfer ribbon for use in nonimpact printing comprising a substrate and a thermal transfer coating which is formed from a mixture comprising the combination of a wax emulsion containing as essential ingredients about 20 to 45% oxidized, isocyanated hydrocarbon wax, about 35 to 65% paraffin wax mixture of solid crystalline hydrocarbons of the methane series derived from the paraffin distillate portion of crude petroleum, about 5 to 20% carnauba wax, about 3 to 15% ethylene vinyl acetate copolymer resin, and about 1 to 25% hard, color stable styrene copolymer resin in a solvent solution and a fluorescent color coating containing as essential ingredients about 5 to 20% of one fluorescent pigment, about 3 to 10% of another fluorescent pigment, about 5 to 20% of one toning pigment, and about 1 to 10% of another toning pigment, the fluorescent pigments in the thermal transfer ribbon having a fluorescence greater than 10 postal meter units and a peak wavelength in the range of 600 to 650 nanometers, the thermal transfer coating providing a transferred image of a color having a measure of lightness (L) in the range of 40 to 50, a measure (a) on the red-green axis and a measure (b) on the blue-yellow axis, and a total color difference value (Δ

) of the transferred image not to exceed 10 when using the formula (Δ

)=√

(Δ

L)² +(Δ

a)² +(Δ

b)² as measured on the Hunter Color Meter.

8. The ribbon of claim 7 wherein said one fluorescent pigment is fire orange.

9. The ribbon of claim 7 wherein said one color toning pigment is red.

10. The ribbon of claim 7 wherein said another toning pigment is scarlet.

11. The ribbon of claim 7 wherein said another fluorescent pigment is red-orange.

13. The thermal transfer ribbon of claim 11 wherein said fluorescent color coating occupies approximately one-half of the surface of the substrate and a thermal transfer coating of another color occupies approximately the remaining one-half of the surface of the substrate along the length thereof.

12. A thermal transfer ribbon for use in nonimpact printing comprising a substrate and a thermal transfer coating which is formed from a mixture comprising the combination of a wax emulsion containing as essential ingredients about 20 to 45% oxidized, isocyanated hydrocarbon wax, about 35 to 65% paraffin wax mixture of solid crystalline hydrocarbons of the methane series derived from the paraffin distillate portion of crude petroleum, about 5 to 20% carnauba wax and about 3 to 15% ethylene vinyl acetate copolymer resin in a solvent solution and a fluorescent color coating containing as essential ingredients about 5 to 20% of red-orange fluorescent pigment, about 1 to 4% of a yellow fluorescent pigment, about 3 to 10% calcium carbonate filler, and about 5 to 10% of a red toning pigment, the fluorescent pigments in the thermal transfer ribbon having a fluorescence greater than 10 postal meter units and a peak wavelength in the range of 600 to 650 nanometers, the thermal transfer coating providing a transferred image of a color having a measure of lightness (L) in the range of 40 to 50, a measure (a) on the red-green axis and a measure (b) on the blue-yellow axis, and a total color difference value (Δ

) of the transferred image not to exceed 10 when using the formula (Δ

)=√

(Δ

L)² +(Δ

a)² +(Δ

b)² as measured on the Hunter Color Meter.

14. The thermal transfer ribbon of claim 12 wherein said fluorescent color coating occupies a portion of the surface of said substrate and a thermal transfer coating of another color occupies the surface of an adjacent portion in repeated manner along the length of the substrate.

15. The thermal transfer ribbon of claim 12 wherein said thermal transfer coating equates to a coating weight of between 9 and 16 milligrams per four square inches on said substrate.