Photoimagable solder mask coating

• US 5,089,376 A
• Filed: 06/13/1989
• Issued: 02/18/1992
• Est. Priority Date: 12/08/1986
• Status: Expired due to Fees

• Current Assignee: AWI Licensing Company (Armstrong World Industries Incorporated)
• Original Assignee: Armstrong World Industries Incorporated
• Inventors: Setthachayanon, Songvit
• Primary Examiner(s): Hamilton, Cynthia
• Application Number:
  US07/365,328
• Time in Patent Office: 980 Days
• Field of Search: 522/95, 522/96, 522/92, 522/97, 430/910, 430/284
• US Class Current: 430/284.1
• CPC Class Codes: C08F 299/06 from polyurethanes
• CPC Class Codes: C08G 18/0823 containing carboxylate salt groups or groups forming them
• CPC Class Codes: C08G 18/348 Hydroxycarboxylic acids
• CPC Class Codes: C08G 18/672 Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
• CPC Class Codes: C08G 18/6725 containing ester groups other than acrylate or alkylacrylate ester groups
• CPC Class Codes: G03F 7/035 the binders being polyurethanes
• CPC Class Codes: Y10S 430/111 Polymer of unsaturated acid or ester

Abstract

A UV sensitive coating composition is described which uses a polymer prepared from a condensation reaction of a diisocyanate, a hydroxy alkyl (di or tri) (meth)acrylate and a carboxylic acid polyol. Optionally, a polyol and/or a dicarboxylic acid polyol can also be included as reactants. The coating polymer, thus prepared, is combined with binders and crosslinkers to form a solder mask.

Claims

1. A solder mask coating composition comprising:

1) a resin binder,

     2) a crosslinker,

     3) a UV sensitive polymer which has a carboxyl moiety and

     4) an acid functional acrylate ester of a bisphenol A epoxy resin in an amount of from about 7 to about 28% by weight of the total solids wt., further providing that the UV sensitive polymer was made by condensing a reaction mixture of component (A), a diisocyanate having from 6 to 18 carbon atoms;

component (B) a carboxylic acid polyol having the formula;

(OH)_x --R6--COOH, wherein x can be an integer from 2 to 5, and wherein R6 is a linear or branched, saturated, unsaturated, or aromatic hydrocarbon moiety having from 2 to 29 carbon atoms; and

component (C) a hydroxy alkyl(meth)acrylate wherein its alkyl group has from 2 to 28 carbon atoms;

provided that component (A) is present in an amount of from about 30 to about 80% by weight of the total amount of the reaction mixture;

component (B) is present in an amount of from about 5 to about 45% by weight of the total amount of the reaction mixture and has a minimum of about 0.3 milliequivalents of acid per gram of the total amount of the reaction mixture; and

component (C) is present in an amount of from about 5 to about 50% by weight of the total amount of the reaction mixture with a minimum amount of 0.5 milliequivalents of acrylate per gram of the total amount of the reaction mixture;

wherein the UV sensitive polymer is characterized by its hydrophilic nature;

further providing that a solder mask coat prepared from the coating composition is soluble or swellable in aqueous solutions having a pH in excess of 7.5 until exposure to UV light.

2. The solder mask coating composition of claim 1 which also contains a thixotropic agent.

3. The solder mask coating composition of claim 1 having fumed silica as a thixotropic agent in an amount of from about 0.5 to about 15% by weight of the total solids weight.

4. The solder mask coating composition of claim 1 wherein the resin binder is a hydrophilic resin binder, providing however, that the solder mask coating composition is stable and homogeneous because the carboxyl moiety makes the polymer and the resin binder compatible.

5. The solder mask coating composition of claim 1 wherein the resin binder is a styrene/maleic anhydride copolymer resin.

6. The solder mask coating composition of claim 5 wherein the styrene/maleic anhydride copolymer resin binder has a glass transition temperature of about 155°

C. or greater.

7. The solder mask coating composition of claim 1 wherein component (B) provided the reaction mixture with acid milliequivalents in the range of from about 0.8 to about 2.6 milliequivalents of acid per gram of the total reaction mixture.

8. The solder mask coating composition of claim 1 wherein the reaction mixture for the UV sensitive polymer also contained component D, a polyol.

9. The solder mask coating composition of claim 8 wherein the polyol had from 2 to 16 carbon atoms, and was present in an amount of from about 2 to about 15% by weight of the total reactants.

10. The solder mask coating composition of claim 8 wherein component B had a minimum of about 1 milliequivalents of acid per gram of the total reactants, and the polyol had from 2 to 28 carbon atoms and was present in an amount of from about 2 to about 10% by weight of the total reactants.

11. The solder mask coating composition of claim 1 wherein the acid functional acrylate ester has an acid value in the range of from about one to about 30 and wherein the solder mask also includes from about 3 to about 15% by weight of a polyfunctional (meth)acrylate monomer crosslinking agent, a photopolymerization initiator in an amount less than 10% by weight, a thermopolymerization inhibitor, and a flow leveling agent.

12. The solder mask coating composition of claim 1 also having a polyfunctional (meth)acrylate monomer crosslinking agent in an amount of from about 3 to about 20% by weight of the total solids.

13. A solder mask composition specifically formulated for coating techniques in silk screen printing apparatus comprises:

1) a styrene/maleic anhydride copolymer resin binder in an amount of from about 17 to about 45% by weight of the total solids;

2) a UV sensitive polymer having a carboxyl moiety, the polymer having been made by condensing a reaction mixture of component (A), a diisocyanate having from 6 to 18 carbon atoms;

component (B) a carboxylic acid polyol having the formula;

(OH)x--R6--COOH;

wherein x can be an integer from 2 to 5, and wherein R6 is a linear or branched, saturated, unsaturated or aromatic hydrocarbon moiety having from 2 to 29 carbon atoms; and

component (C), a hydroxy alkyl(meth)acrylate wherein its alkyl group has from 2 to 28 carbon atoms;

provided that component (A) is present in an amount of from about 30 to about 80% by weight of the total amount of the reaction mixture;

component (B) is present in an amount of from about 5 to about 45% by weight of the total amount of the reaction mixture and has from about 0.8 to about 2.6 milliequivalents of acid per gram of the total reaction mixture, and component (C) is present in an amount of 0.5 milliequivalents of acrylate per gram of the total amount of the reaction mixture, wherein the UV sensitive polymer has a molecular weight in the range of from about 6,500 to about 20,000 and is present in an amount of from about 15 to about 35% by weight of the total solids;

3) An acid functional acrylate ester of a bisphenol A epoxy resin which has an acid value in the range of from about 13 to about 27 and is present at an amount in the range of from about 7 to about 28% by weight of the total solids;

4) a polyfunctional (meth)acrylate monomer crosslinking agent in an amount of from about 3 to about 15% by weight of the total solids;

5) a photopolymerization initiator in an amount less than 10% by weight of the total solids;

6) a thermopolymerization inhibitor in an amount up to about 1.1% by weight of the total solids;

7) a flow leveling agent in an amount up to about 2.6% by weight of the total solids;

8) a solvent in an amount of from about 30 to about 42% by weight; and

9) a thixotrope in an amount effective to adjust the viscosity of the formulation to a level in the range of from about 55,000 to about 65,000 CPS.

14. The solder mask coating composition of claim 13 wherein the thixotrope is present at an amount up to about 15% by weight of the total solids weight, further providing that at least about 50% by weight of the thixotrope is fumed silica.

15. The solder mask coating composition of claim 13 wherein the styrene/maleic anhydride resin binder has a glass transition temperature in the range of from about 155°

to about 200°

C.

16. The solder mask coating composition of claim 13 wherein the reaction mixture for the UV sensitive polymer also contained component D, a polyol at an amount in the range of from about 2 to about 10% by weight.