Sequence for separating propylene from cracked gases

• US 5,090,977 A
• Filed: 11/13/1990
• Issued: 02/25/1992
• Est. Priority Date: 11/13/1990
• Status: Expired due to Term

• Current Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Halle, Roy T., Strack, Robert D., Vebeliunas, Rimas V., Bamford, David A.
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US07/613,435
• Time in Patent Office: 469 Days
• Field of Search: 62/23, 62/24, 62/28, 62/11, 208/351
• US Class Current: 62/623
• CPC Class Codes: C10G 70/02 by hydrogenation
• CPC Class Codes: C10G 70/041 by distillation
• CPC Class Codes: F25J 2210/12 Refinery or petrochemical off-gas
• CPC Class Codes: F25J 2215/62 Ethane or ethylene
• CPC Class Codes: F25J 2215/64 Propane or propylene
• CPC Class Codes: F25J 3/0219 Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: F25J 3/0242 separation of CnHm with 3 carbon atoms or more
• CPC Class Codes: F25J 3/0252 separation of hydrogen production of hydrogen containing gas in general C01B3/00, e.g. separation of hydrogen or hydrogen containing gases form gaseous mixtures at low temperatures C01B3/506

Abstract

A process sequence for treating cracked gases of heavy feedstocks which preferentially produces propylene to the exclusion of propane, butanes and butenes. The process eliminates the need for a depropanizer with the attendant savings in capital and operating costs. In lieu of a conventional C3 splitter, the process features a depropylenizer, i.e. a distillation tower designed to separate propylene from propane, butanes and butenes. A hydrogenation unit to eliminate contaminants can be placed upstream of the depropylenizer or the depropylenizer can be split into two sections with the hydrogenation unit located between the two sections.

Claims

1. A process for separating propylene from a mixture of cracked hydrocarbons produced by a cracking unit, comprising the steps of:

(a) separating the mixture in a deethanizer into a deethanizer tops stream and deethanizer bottoms stream;

(b) separating the deethanizer bottoms stream in a debutanizer into a debutanizer tops stream and a debutanizer bottoms stream;

(c) separating the debutanizer tops stream in a depropylenizer into a depropylenizer tops stream comprising propylene and a depropylenizer bottoms stream.

2. A process as in claim 1, further comprising:

separating the deethanizer tops stream into an ethane stream and an ethylene stream.

3. A process as in claim 1, further comprising:

recycling the depropylenizer bottoms stream to the cracking unit.

4. A process as in claim 1, wherein the depropylenizer is made up of a top section and a bottom section with liquid flow means for conducting liquid from the bottom of the top section to the top of the bottom section and vapor flow means for conducting vapor from the top of the bottom section to the bottom of the top section.

5. A process as in claim 4, further comprising:

separating the deethanizer tops stream into an ethane stream and an ethylene stream.

6. A process as in claim 4, further comprising:

recycling the depropylenizer bottoms stream to the cracking unit.

7. A process as in claim 4, wherein the said liquid flow means includes a hydrogenation unit.

8. A process for separating propylene from a mixture of cracked hydrocarbons produced by a cracking unit, comprising the steps of:

(a) separating the mixture in a deethanizer into a deethanizer tops stream and deethanizer bottoms stream;

(b) separating the deethanizer bottoms stream in a debutanizer into a debutanizer tops stream and a debutanizer bottoms stream;

(c) treating the debutanizer tops stream in a hydrogenation unit to produce a hydrogenation unit outlet stream;

(d) separating the hydrogenation unit outlet stream in a depropylenizer into a depropylenizer tops stream comprising propylene and a depropylenizer bottoms stream.

9. A process as in claim 8, further comprising:

separating the deethanizer tops stream into an ethane stream and an ethylene stream.

10. A process as in claim 8 wherein the depropylenizer is provided with a pasteurization section capable of removing unreacted hydrogen and light components.

11. A process as in claim 8, further comprising:

recycling the depropylenizer bottoms stream to the cracking unit.

12. A process for separating propylene from a mixture of cracked hydrocarbons produced by a cracking unit, comprising the steps of:

(a) separating the mixture in a demethanizer system into a demethanizer tops stream and demethanizer bottoms stream;

(b) separating the demethanizer bottoms stream in a deethanizer into a deethanizer tops stream and deethanizer bottoms stream;

(c) separating the deethanizer bottoms stream in a debutanizer into a debutanizer tops stream and a debutanizer bottoms stream;

(d) separating the debutanizer tops stream in a depropylenizer into a depropylenizer tops stream comprising propylene and a depropylenizer bottoms stream.

13. A process as in claim 12, further comprising:

separating the deethanizer tops stream into an ethane stream and an ethylene stream.

14. A process as in claim 12, further comprising:

recycling the depropylenizer bottoms stream to the cracking unit.

15. A process as in claim 12, wherein the depropylenizer is made up of a top section and a bottom section with liquid flow means for conducting liquid from the bottom of the top section to the top of the bottom section and vapor flow means for conducting vapor from the top of the bottom section to the bottom of the top section.

16. A process as in claim 15, further comprising:

separating the deethanizer tops stream into an ethane stream and an ethylene stream.

17. A process as in claim 15, further comprising:

recycling the depropylenizer bottoms stream to the cracking unit.

18. A process as in claim 15, wherein said liquid flow means includes a hydrogenation unit.

19. A process for separating propylene from a mixture of cracked hydrocarbons produced by a cracking unit, comprising the steps of:

(a) separating the mixture in a demethanizer system into a demethanizer tops stream and demethanizer bottoms stream;

(b) separating the demethanizer bottoms stream in a deethanizer into a deethanizer tops stream and deethanizer bottoms stream;

(c) separating the deethanizer bottoms stream in a debutanizer into a debutanizer tops stream and a debutanizer bottoms stream;

(d) treating the debutanizer tops stream in a hydrogenation unit to produce a hydrogenation unit outlet stream;

(e) separating the hydrogenation unit outlet stream in a depropylenizer into a depropylenizer tops stream comprising propylene and a depropylenizer bottoms stream.

20. A process as in claim 19, further comprising:

separating the deethanizer tops stream into an ethane stream and an ethylene stream.

21. A process as in claim 19, further comprising:

recycling the depropylenizer bottoms stream to the cracking unit.