Laminate for a safety glazing

• US 5,091,258 A
• Filed: 08/20/1990
• Issued: 02/25/1992
• Est. Priority Date: 08/20/1990
• Status: Expired due to Term

• Current Assignee: Solutia Incorporated (Eastman Chemical Company)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Moran, James R.
• Primary Examiner(s): Cashion, Jr., Merrell C.
• Assistant Examiner(s): NAKARANI, DHIRAJLAL S
• Application Number:
  US07/569,332
• Time in Patent Office: 554 Days
• Field of Search: 428/141, 428/437, 428/458, 428/480, 428/524
• US Class Current: 428/437
• CPC Class Codes: B32B 17/10005 laminated safety glass or glazing
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10577 Surface roughness
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/10981 Pre-treatment of the layers
• CPC Class Codes: B32B 2307/412 Transparent
• CPC Class Codes: B32B 2307/518 bi-axially
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
• CPC Class Codes: Y10T 428/3163 Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31942 Of aldehyde or ketone condensation product

Abstract

A laminate which is substantially free of distortion when used in a safety glazing comprising a transparent, thermoplastic substrate layer, optionally surface treated or coated to improve adhesion, bearing one or more functional performance layers, such as an infra-red radiation reflecting stack, and at least one layer of plasticized polyvinyl butyral bonded on one side to a functional performance layer or the substrate layer having a roughened deairing surface on its other side characterized by a roughness value, Rz, of at least 10 micrometers, such plasticized polyvinyl butyral layer, before bonding to the substrate layer or functional performance layer, possessing low surface waviness on each side characterized by a wave index value, WI, of less than 15,000 square micrometers.

Claims

1. A laminate which is substantially free of reflected distortion when used in a safety glazing comprising:

a transparent, thermoplastic substrate layer, optionally surface treated or coated, bearing one or more functional performance layers; and

at least one layer of plasticized polyvinyl butyral bonded on one side to a functional performance layer or the substrate layer and having a roughened deairing surface on its other side characterized by a roughness value, Rz, of at least 10 micrometers;

said at least one plasticized polyvinyl butyral layer, before bonding to the substrate layer or functional performance layer, possessing low surface waviness on each side characterized by a wave index value, WI, of less than 15,000 square micrometers.

2. The laminate of claim 1 wherein the substrate layer is polyester film having a thickness of about 0.013 to 0.20 mm.

3. The laminate of claim 2 wherein the polyester is biaxially stretched polyethylene terephthalate.

4. The laminate of claim 3 wherein the biaxially stretched polyethylene terephthalate film bearing the one or more functional performance layers is encapsulated within and bonded to two layers of plasticized polyvinyl butyral, each of said layers of plasticized polyvinyl butyral having said roughened surface at least on one side and said low surface waviness on each side.

5. The laminate of claim 4 wherein the functional performance layers comprise an infra red radiation reflective stack.

6. The laminate of claim 5 wherein the infra red radiation reflective stack comprises one or more metal layers and one or more integral cooperating dielectric layers.

7. The laminate of any of claims 1, 2, 3, 4, 5 or 6 wherein WI is less than 12,000 square micrometers.

16. The laminate of any of claims 1, 8 or 12 wherein WI=H_avg ×

P_avg, wherein H_avg and P_avg, each measured in micrometers, are based on the surface profile of the sheet obtained using a Mahr C5D Perthometer with a waviness profile setting of W.

17. The laminate of claim 16 wherein the profile using said setting of W is obtained after electronically filtering out short wave-length segments measured in determining R_Z.

8. A laminate which is substantially free of reflected distortion when used in a safety glazing for controlling solar radiation comprising:

a flexible, transparent, thermoplastic substrate layer, optionally treated or coated to improve adhesion, having a carrier surface and an opposite back surface;

a multi-layer stack on the carrier surface for reflecting infra-red radiation and transmitting visible light comprising one or more metal layers and one or more cooperating dielectric layers, any of said metal or dielectric layers having been optionally surface modified or coated to improve one or more properties;

a first, flexible layer of plasticized polyvinyl butyral having a bonding surface adhered to the back surface of the substrate layer;

a second, flexible layer of plasticized polyvinyl butyral having a bonding surface adhered to the outermost layer of the multi-layer stack;

each of said first and second polyvinyl butyral layers having opposite, unbonded, roughened deairing surfaces characterized by a roughness value, R_Z, of at least 10 micrometers; and

each of said first and second polyvinyl butyral layers before bonding to the substrate layer and the stack possessing low surface waviness on each side characterized by a wave index value, WI, of less than 15,000 square micrometers.

9. The laminate of claim 8 wherein the substrate layer is a polyester film having a thickness of about 0.013 to 0.20 mm.

10. The laminate of claim 9 wherein the polyester is biaxially stretched polyethylene terephthalate.

11. The laminate of any of claims 8, 9 or 10 wherein WI is less than 12,000 square micrometers.

12. A laminate substantially free of reflected distortion when used in a safety glazing comprising two layers of plasticized polyvinyl butyral and an intermediate layer of metallized plastic film interposed therebetween, each plasticized polyvinyl butyral layer having i) an exposed deairing surface characterized by a roughness value, R_Z, of at least 10 micrometers and ii) before inclusion in the laminate, another deairing surface opposite the exposed surface also characterized by a roughness value, R_Z, of at least 10 micrometers and surface waviness on each side characterized by a wave index value, WI, less than 15,000 square micrometers.

13. The laminate of claim 12 wherein WI of each side of each plasticized polyvinyl butyral layer is less than 12.

14. The laminate of either of claims 12 or 13 wherein the plastic film is biaxially stretched polyethylene terephthalate.

15. The laminate of claim 14 wherein the plastic film is about 0.025 to 0.10 mm thick.