Oriented multilayer heat sealable packaging film

• US 5,093,194 A
• Filed: 11/01/1989
• Issued: 03/03/1992
• Est. Priority Date: 11/01/1989
• Status: Expired due to Term

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Cretekos, George, Nahmias, A. Michael, Touhsaent, Robert E.
• Primary Examiner(s): BUFFALOW, EDITH
• Application Number:
  US07/430,201
• Time in Patent Office: 853 Days
• Field of Search: 428/349, 428/353, 428/414, 428/518, 428/476.3, 428/484, 428/520, 156/244.11
• US Class Current: 428/349
• CPC Class Codes: B32B 2307/31 Heat sealable
• CPC Class Codes: B32B 2307/518 bi-axially
• CPC Class Codes: B32B 2307/7242 Non-permeable
• CPC Class Codes: B32B 2310/0445 using gas or flames B32B2310/0427 takes precedence
• CPC Class Codes: B32B 2310/14 Corona, ionisation, electrical discharge, plasma treatment
• CPC Class Codes: B32B 2323/10 Polypropylene
• CPC Class Codes: B32B 2327/06 PVC, i.e. polyvinylchloride
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/16 specially treated, e.g. irradiated
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 37/153 at least one layer is extruded and immediately laminated while in semi-molten state
• CPC Class Codes: B32B 38/0008 Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation heat treatment B32B38/0036
• CPC Class Codes: C08J 2323/02 not modified by chemical after treatment
• CPC Class Codes: C08J 2423/00 Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/048 Forming gas barrier coatings
• CPC Class Codes: C08J 7/052 Forming heat-sealable coatings
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/2843 : including a primer layer
• CPC Class Codes: Y10T 428/31515 : As intermediate layer
• CPC Class Codes: Y10T 428/3175 : Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31801 : Of wax or waxy material
• CPC Class Codes: Y10T 428/3192 : Next to vinyl or vinylidene chloride polymer
• CPC Class Codes: Y10T 428/31928 : Ester, halide or nitrile of addition polymer

Abstract

An oriented heat sealable multilayer structure. The structure comprises a substrate having a first surface and a second surface, the substrate comprising a polyolefin film; a polymeric heat sealable layer on the first surface of the substrate, the layer comprising a polymeric material selected from the group consisting of a terpolymer of ethylene, propylene and butene-1, a random copolymer of ethylene and propylene, and blends thereof; a primer coating on the second surface of the substrate; and a water vapor and gas barrier layer on the primer coating, the water vapor and gas barrier layer selected from the group consisting of a vinylidene chloride copolymer containing at least about 50% of vinylidene chloride and an interpolymer comprising a minor amount of acrylic acid, methacrylic acid or mixtures thereof and a major amount of neutral monomer esters comprising methyl acrylate, ethyl acrylate, methyl methacrylate or mixtures thereof. A method for producing the heat sealable multilayer film structure is also provided.

Claims

1. An oriented heat sealable multilayer structure, comprising:

(a) a substrate comprising a polyolefin film having a first surface and a second surface;

(b) a polymeric heat sealable layer on said first surface of said substrate, said heat sealable layer comprising a polymeric material selected from the group consisting of a terpolymer of ethylene containing from about 1 to 8% by weight of ethylene and from about 1 to 8% by weight of butene-1, propylene and butene-1, said terpolymer of ethylene, propylene and butene-1, a random copolymer or ethylene and propylene, and blends thereof;

(c) a primer coating on said second surface of said substrate; and

(d) a water vapor and gas barrier layer on said primer coating, said water vapor and gas barrier layer selected from the group consisting of a polyvinylidene chloride containing at least about 50% by weight of vinylidene chloride monomer and an interpolymer comprising a minor amount of acrylic acid, methacrylic acid or mixtures thereof and a major amount of neutral monomer esters comprising methyl acrylate, ethyl acrylate, methyl methacrylate or mixtures thereof.

2. The multilayer structure of claim 1, wherein said polyolefin substrate comprises homopolymer polypropylene.

3. The multilayer structure of claim 2, wherein said primer comprises a member selected from the group consisting of a reaction product of an acidified aminoethylated vinyl polymer and an epoxy resin, the condensation product of a monoaldehyde with an interpolymer of an acrylamide or methacrylamide and at least one unsaturated monomer, and a condensation product of aminoaldehyde with acrylamide or methacrylamide interpolymerized with at least one other unsaturated monomer in the presence of a C₁ -C₆ alkanol.

4. The multilayer structure of claim 3, wherein said second surface of said substrate is surface treated using a surface treatment technique selected from the group consisting of flame treatment and corona discharge treatment.

5. The multilayer structure of claim 4, wherein said water vapor and gas barrier layer comprises a polyvinylidene chloride containing at least about 90% by weight of vinylidene chloride monomer.

6. The multilayer structure of claim 5, wherein said water vapor and gas barrier layer further comprises a carnuba wax at a level of from about 0.5 to about 15% by weight.

7. The multilayer structure of claim 6, wherein said water vapor and gas barrier layer further comprises a carnuba wax at a level of from about 0.5 to about 5% by weight.

8. The multilayer structure of claim 6, further comprising an adhesion promoting layer on said water vapor and gas barrier layer comprising from about 25% to about 90% by weight of a member selected from the group consisting of a polyvinylidene chloride containing at least about 50% by weight of vinylidene chloride monomer and an interpolymer comprising a minor amount of acrylic acid, methacrylic acid or mixtures thereof and a major amount of neutral monomer esters comprising methyl acrylate, ethyl acrylate, methyl methacrylate or mixtures thereof, and from about 10% to about 75% by weight of wax.

9. The multilayer structure of claim 1, further comprising an adhesion promoting layer on said water vapor and gas barrier layer comprising from about 25% to about 90% by weight of a member selected from the group consisting of a polyvinylidene chloride containing at least about 50% by weight of vinylidene chloride monomer and an interpolymer comprising a minor amount of acrylic acid, methacrylic acid or mixtures thereof and a major amount of neutral monomer esters comprising methyl acrylate, ethyl acrylate, methyl methacrylate or mixtures thereof, and from about 10% to about 75% by weight of wax.

10. A method for producing an oriented heat sealable multilayer structure, comprising:

(a) coextruding a substrate comprising a polyolefin film with a polymeric heat sealable layer the polymeric heat sealable layer comprising a material selected from the group consisting of a terpolymer of ethylene, propylene and butene-1, said terpolymer of ethylene, propylene and butene-1 containing from about 1 to 8% by weight of ethylene and from about 1 to 8% by weight of butene-1 a random copolymer of ethylene and propylene, and blends thereof;

(b) biaxially orienting the coextrudate;

(c) applying a primer coating on the surface of the polyolefin substrate; and

(d) applying a water vapor and gas barrier layer on the primer coating, the water vapor and gas barrier layer selected from the group consisting of a polyvinylidene chloride containing at least about 50% by weight of vinylidene chloride monomer and an interpolymer comprising a minor amount of acrylic acid, methacrylic acid or mixtures thereof and a major amount of neutral monomer esters comprising methyl acrylate, ethyl acrylate, methyl methacrylate or mixtures thereof.

11. The method of claim 10, wherein in step (a) the polyolefin substrate comprises homopolymer polypropylene.

12. The method of claim 11, wherein in step (c) the primer comprises a member selected from the group consisting of a reaction product of an acidified aminoethylated vinyl polymer and an epoxy resin, a condensation product of a monoaldehyde with an interpolymer of an acrylamide or methacrylamide and at least one unsaturated monomer, and a condensation product of aminoaldehyde with acrylamide or methacrylamide interpolymerized with at least one other unsaturated monomer in the presence of a C₁ -C₆ alkanol.

13. The method of claim 12, further comprising the step of surface treating the polyolefin substrate surface of the coextrudate prior to step (c) using a surface treatment technique selected from the group consisting of flame treatment and corona discharge treatment.

14. The method of claim 13, wherein in step (d) the water vapor and gas barrier layer comprises a polyvinylidene chloride containing at least about 90% by weight of vinylidene chloride monomer.

15. The method of claim 14, wherein in step (d) the water vapor and gas barrier layer further comprises a carnuba wax at a level of from about 0.5 to about 15% by weight.

16. The method of claim 15, wherein in step (d) the water vapor and gas barrier layer further comprises a carnuba wax at a level of from about 0.5 to about 5% by weight.

17. The method of claim 15, wherein in step (a) the terpolymer of ethylene, propylene and butene-1 contains from about 1 to 8% by weight of ethylene and from about 1 to 8% by weight of butene-1.

18. The method of claim 17, further comprising the step of applying an adhesion promoting layer on the water vapor and gas barrier layer, the adhesion promoting layer comprising from about 25% to about 90% by weight of a member selected from the group consisting of a polyvinylidene chloride containing at least about 50% by weight of vinylidene chloride monomer and an interpolymer comprising a minor amount of acrylic acid, methacrylic acid or mixtures thereof and a major amount of neutral monomer esters comprising methyl acrylate, ethyl acrylate, methyl methacrylate or mixtures thereof, and from about 10% to about 75% by weight of wax.

19. The method of claim 10, further comprising the step of applying an adhesion promoting layer on the water vapor and gas barrier layer, the adhesion promoting layer comprising from about 25% to about 90% by weight of a member selected from the group consisting of a polyvinylidene chloride containing at least about 50% by weight of vinylidene chloride monomer and an interpolymer comprising a minor amount of acrylic acid, methacrylic acid or mixtures thereof and a major amount of neutral monomer esters comprising methyl acrylate, ethyl acrylate, methyl methacrylate or mixtures thereof, and from about 10% to about 75% by weight of wax.