Modular fuel cell assembly

• US 5,094,928 A
• Filed: 04/20/1990
• Issued: 03/10/1992
• Est. Priority Date: 04/20/1990
• Status: Expired due to Term

• Current Assignee: Telcordia Technologies Incorporated (Telefonaktiebolaget LM Ericsson)
• Original Assignee: Bell Communications Research, Inc. (Telefonaktiebolaget LM Ericsson)
• Inventors: Dyer, Christopher K.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US07/512,117
• Time in Patent Office: 690 Days
• Field of Search: 429/30, 429/32, 429/33, 429/40, 429/42, 429/44, 429/12, 429/94, 429/191, 429/210, 29/623.5, 427/115
• US Class Current: 429/432
• CPC Class Codes: H01M 8/0297 Arrangements for joining electrodes, reservoir layers, heat exchange units or bipolar separators to each other H01M8/0271 takes precedence
• CPC Class Codes: H01M 8/10 Fuel cells with solid electrolytes
• CPC Class Codes: H01M 8/1007 with both reactants being gaseous or vaporised H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1023 having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
• CPC Class Codes: H01M 8/1039 halogenated, e.g. sulfonated polyvinylidene fluorides
• CPC Class Codes: H01M 8/1081 starting from solutions, dispersions or slurries exclusively of polymers
• CPC Class Codes: H01M 8/2404 Processes or apparatus for grouping fuel cells
• CPC Class Codes: H01M 8/241 with solid or matrix-supported electrolytes
• CPC Class Codes: H01M 8/2432 Grouping of unit cells of planar configuration
• CPC Class Codes: H01M 8/2457 with both reactants being gaseous or vaporised
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

Two or more individual fuel cells are connected together to form a modular assembly whose output voltage is two or more times that of a single cell. Corrugated current collectors interconnect adjacent cells and allow a required fuel/oxidizer mixture to have access to virtually the entire surface area of one side of each of the interconnected cells. Such a modular assembly is advantageously made by a continuous fabrication process. Each assembly is packaged in either a flat or a spiral form.

Claims

1. A modular fuel cell assembly comprising

n fuel cells, where n is a positive integer having a value of at least 2, each of said cells including a first electrode arrangement and a second electrode arrangement separated by and in contact with a solid-electrolyte body, wherein said first electrode arrangement is permeable to a fuel and an oxidizer, wherein said second electrode arrangement is impermeable to the fuel and the oxidizer, and wherein the solid-electrolyte body consists essentially of an electronically insulating material that is also ionically conducting to at least a first ionic species and which material is permeable to the fuel, to the oxidizer and to the products of electrochemical reactions of this fuel and oxidizer,

and current collecting means that is permeable to the fuel and the oxidizer electrically connecting the first electrode arrangement of a cell to the second electrode arrangement of the next adjacent cell in the series connection of cells.

2. An assembly as in claim 1 wherein said current collecting means comprises a conductive corrugated member.

3. An assembly as in claim 2 wherein said first electrode arrangement of each cell comprises a permeable layer of a catalytic material in contact with said solid-electrolyte body.

4. An assembly as in claim 3 wherein said second electrode arrangement of each cell comprises a conductive carrier member having a layer of a catalytic material deposited on said carrier member and in contact with said solid-electrolyte body.

5. An assembly as in claim 4 wherein said first electrode arrangement of each cell further comprises a permeable conductive layer interposed between said permeable catalytic layer and said conductive corrugated member.

6. An assembly as in claim 5 wherein said permeable conductive layer comprises a material selected from the group consisting of a permeable conductive polymer and a carbon-fiber-mesh material.

7. An assembly as in claim 1 wherein the fuel comprises at least one member of the group consisting of hydrogen, methane and methanol, and wherein the oxidizer comprises oxygen.

8. An assembly as in claim 7 wherein said current collecting means comprises a corrugated member selected from the group consisting of a metal and a conductive polymer.

9. An assembly as in claim 8 wherein said first electrode arrangement of each cell comprises a permeable layer of a catalytic material in contact with said solid-electrolyte body, said permeable layer being selected from the group consisting of platinum, palladium, gold, nickel, alloys of platinum, palladium, gold and nickel, and electronically conducting mixed oxides.

10. An assembly as in claim 9 wherein said second electrode arrangement of each cell comprises a conductive carrier member comprising a material selected from the group consisting of a metal and a conductive polymer, and wherein a catalyic material is deposited on said carrier member in contact with said solid-electrolyte body, said last-mentioned catalytic material being selected from the group consisting of platinum, palladium, gold, nickel, alloys of platinum, palladium, gold and nickel, and electronically conducting mixed oxides.

11. An assembly as in claim 10 wherein said solid-electrolyte body comprises a material selected from the group consisting of a hydrated oxide of aluminum and a carbon-based polymer.

12. An assembly as in claim 1 further including

means, including two parallel spaced-apart conductive planer members, for containing said series-connected cells as a flat-pack assembly, one planar member being in electrical contact with the current collecting means that is connected to the first electrode arrangement of an end cell of the series-connected cells, and the other planar member being in electrical contact with the second electrode arrangement of the other end cell of said series-connected cells, said containing means including openings through which the fuel and the oxidizer can enter and the product of the fuel cell reactions can leave.

13. An assembly as in claim 1 wherein said series-connected cells are rolled to form a spiral package, and further including a conductive member within said spiral package and in contact with one of said current collecting means and said second electrode means to constitute one output terminal of said spiral package, the outer surface of said spiral package constituting the other output terminal thereof.

14. An assembly as defined in claim 1 made by a method comprising the steps of

forming at least two individual physically separate elongated fuel cells in a continuous fabrication process,

forming at least two individual elongated current collecting means in a continuous fabrication process,

interleaving said elongated fuel cells and current collecting means to form an elongated assembly in which at least two elongated fuel cells are connected in series to provide an output voltage that is at least two times that of an individual cell,

and cutting said elongated assembly into sections to form multiple individual fuel cell assemblies each of which comprises series-connected cells.