Diamond metal composite cutter and method for making same

• US 5,096,465 A
• Filed: 12/13/1989
• Issued: 03/17/1992
• Est. Priority Date: 12/13/1989
• Status: Expired due to Fees

• Current Assignee: Norton Company (Compagnie De Saint-Gobain)
• Original Assignee: Norton Company (Compagnie De Saint-Gobain)
• Inventors: Sung, Chien-Min, Chen, Sy-Hwa
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): THOMPSON, WILLIE
• Application Number:
  US07/450,047
• Time in Patent Office: 825 Days
• Field of Search: 51/293, 51/295, 51/298, 51/308, 51/309
• US Class Current: 51/295
• CPC Class Codes: B23B 27/148 Composition of the cutting inserts
• CPC Class Codes: B23P 15/28 cutting tools sawing tools B23D63/00, B23D65/00; files or rasps B23D73/00
• CPC Class Codes: B24D 18/0009 using moulds or presses
• CPC Class Codes: C09K 3/1445 the coating consisting exclusively of metals
• CPC Class Codes: C22C 2026/005 with additional metal compounds being borides
• CPC Class Codes: C22C 26/00 Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
• CPC Class Codes: E21B 10/5676 having a cutting face with different segments, e.g. mosaic-type inserts

Abstract

A superhard material-metal composite product comprises a plurality of metal coated superhard particles (diamond or cubic boron nitride), and a binder alloy forming a cementing matrix which binds the coated superhard particles into a coherent mass. The binder alloy has a melting point below about 1300° C. and is capable of wetting the metal coating on the superhard particles. The superhard material-metal composite product is formed by assembling the coated particles and the binder alloy in a graphite mold, and then hot pressing at temperatures and pressures well below the temperatures and pressures of the diamond forming region. The superhard component comprises about 40% to 75% by volume of the composite product. The superhard material-metal composite product is of intermediate quality and is particularly useful in earth boring bits for drilling soft rock formations having abrasive rock stringers therein.

Claims

1. A superhard material-metal composite product, comprising

a plurality of metal coated superhard particles, and

a binder alloy having a melting point below about 1300°

C., said binder alloy forming a matrix binding said coated superhard particles into a coherent mass,

said superhard particles comprising above about 40% to about 75% by volume of said coherent mass,

said metal being wetted by said binder alloy when said binder alloy is caused to flow.

2. The composite product of claim 1 wherein said superhard particles are diamond particles.

3. The composite product of claim 2 wherein said superhard particles are single crystal diamond particles.

4. The composite product of claim 2 wherein said superhard particles are polycrystalline diamond particles.

5. The composite product of claim 1 wherein said superhard particles are cubic boron nitride or wurzitic boron nitride particles.

6. The composite product of claim 1 wherein said superhard particles comprise about 50 to 75% by volume of said coherent mass.

7. The composite product of claim 1 wherein said superhard particles comprise about 60 to 75% by volume of said coherent mass.

8. The composite product claim 1 wherein said superhard particles are about 50 to 2,000 microns in diameter.

9. The composite product of claim 1 wherein said superhard particles are about 300 to 1,000 microns in diameter.

10. The composite product of claim 1 wherein said superhard particles are about 400 to 600 microns in diameter.

11. The composite product of claim 1 wherein said superhard particles comprise a first set of superhard particles and a second set of abrasive particles, said first set of superhard particles being substantially larger than said second set of abrasive particles.

12. The composite product of claim 11 wherein said abrasive particles are diamond or cubic boron nitride particles.

13. The composite product of claim 11 wherein said abrasive particles are tungsten carbide, silicon carbide, or aluminum oxide particles.

14. The composite product of claim 11 wherein said second set of abrasive particles is about 1/6 to 1/9 the size of said first set of superhard particles.

15. The composite product of claim 11 wherein said superhard particles of said first set are about 50 to 2,000 microns in diameter and said abrasive particles of said second set are about 25 to 75 microns in diameter.

16. The composite product of claim 11 wherein said superhard particles of said first set are about 400 to 600 microns in diameter and said abrasive particles of said second set are about 50 to 65 microns in diameter.

17. The composite product of claim 11 further comprising a third set of abrasive particles, said third set of abrasive particles being about 1/6 to 1/9 the size of said second set of abrasive particles.

18. The composite product of claim 11 wherein said second set of abrasive particles comprises about 10 to 30% by volume of said first set of superhard particles.

19. The composite product of claim 11 wherein said second set of abrasive particles comprises about 10% by volume of said first set of superhard particles.

20. The composite product of claim 1 further comprising a backing member, said matrix binding said coated superhard particles to said backing member.

21. The composite product of claim 20 wherein said backing member is made from cemented tungsten carbide, silicon carbide, boron carbide, titanium nitride, steel, or a ceramic material.

22. The composite product of claim 20 wherein said backing member is made from cemented tungsten carbide.

23. The composite product of claim 1 wherein said superhard particles are coated with a metal layer that is about 0.5 to 30 microns thick.

24. The composite product of claim 23 wherein said metal layer is 2 to 10 microns thick.

25. The composite product of claim 23 wherein said metal layer includes a carbide forming metal, a boride forming metal, or a nitride forming metal.

26. The composite product of claim 23 wherein said metal layer includes an oxidation resistant metal.

27. The composite product of claim 23 wherein said metal layer includes nickel boride.

28. The composite product of claim 23 wherein said metal layer includes a metal selected from the group consisting of tungsten, chromium, vanadium, molybdenum, tantalum, copper, tin, nickel, cobalt, iron, palladium, platinum and alloys thereof.

29. The composite product of claim 23 wherein said superhard particles have a coating of multiple layers.

30. The composite product of claim 1 wherein said binder alloy has a melting point in the range of about 650 to 1300°

C.

31. The composite product of claim 1 wherein said binder alloy has a melting point in the range of about 900 to 1100°

C.

32. The composite product of claim 1 wherein said binder alloy is a nickel based alloy.

33. The composite product of claim 1 wherein said binder alloy is a cobalt, iron, aluminum, tin, or copper based alloy.

34. The composite product of claim 1 wherein said product is a cutting element for a drill bit.

35. The composite product of claim 1 wherein said product is a cutting element for a dressing tool.

36. The composite product of claim 1 wherein said product is a cutting element for a machining tool.

37. The composite product of claim 1 wherein said product is a cutting element for a woodworking tool.

38. The composite product of claim 1 wherein said product is a cutting element for a wire drawing die.

39. The composite product of claim 1 wherein said product is a cutting element for a cutting tool.

40. The composite product of claim 1 wherein said product is a bearing element.

41. A superhard product, comprising

a superhard component comprising a first set of superhard particles and a second set of abrasive particles, said first set of particles being larger than said second set of particles, said particles of said second set substantially surrounding and being substantially located in the interstices between said particles of said first set,

said particles of said first and second sets each being coated with a metal coating,

said superhard component further including a binder alloy having a melting point less than about 1300°

C. and forming a cementing matrix binding said coated particles to each other, said superhard component having a superhard particle content in the range of above about 40% to about 75% by volume.

42. The superhard product of claim 41 wherein said first set of superhard particles and said second set of abrasive particles each comprises diamond particles.

43. The superhard product of claim 42 wherein said superhard component has a diamond content in the range of about 50 to 75% by volume.

44. The superhard product of claim 42 wherein said superhard component has a diamond content in the range of about 60 to 75% by volume.

45. The superhard product of claim 42 wherein said diamond particles are single crystal diamond particles.

46. The superhard product of claim 42 wherein said second set of particles comprises about 10 to 30% by volume of said first set of particles.

47. The superhard product of claim 42 wherein said diamond particles of said first set are in the range of about 50 to 2,000 microns in diameter, and said diamond particles of said second set are in the range of about 25 to 75 microns in diameter.

48. The superhard product of claim 42 wherein said first metal coating is about 0.5 to 30 microns thick.

49. The superhard product of claim 42 wherein said metal coating on said first set of diamond particles includes multiple layers.

50. The superhard product of claim 42 wherein said metal coating on said first set of diamond particles includes a layer of nickel boride, tungsten, tantalum, molybdenum, vanadium, chromium, copper, tin, cobalt, iron, palladium, platinum, or alloys thereof.

51. The superhard product of claim 42 wherein said binder alloy is a nickel, cobalt, iron, aluminum, tin, or copper based alloy.

52. The superhard product of claim 42 further comprising a backing member, said binder alloy forming a cementing matrix binding said coated diamond particles to said backing member.

53. The superhard product of claim 52 wherein said backing member is made from cemented tungsten carbide, silicon carbide, boron carbide, titanium nitride, steel, or a ceramic material.

54. The superhard product of claim 53 wherein said backing member is an insert member made from cemented tungsten carbide for an earth boring bit.

55. A superhard cutter for an earth boring bit, comprising

a base member,

a superhard component bonded to said base member,

said superhard component comprising a first set of superhard particles having a size in the range of about 50 to 2,000 microns in diameter, and a second set of abrasive particles having a size in the range of about 25 to 75 microns in diameter, said second set of particles substantially surrounding and being substantially located in the interstices between said particles of said first set,

said particles of said first set being coated with a metallic coating that is about 2 to 10 microns thick, and said particles of said second set being coated with a metallic coating that is about 1 to 10 microns thick,

said superhard component further including a binder alloy forming a matrix binding said coated particles to each other and to said base member, said binder alloy having a melting point in the range of about 650 to 1300°

C. and being capable of wetting said coated particles,

said superhard component having a superhard particle content in the range of above about 40% to about 75% by volume.

56. The cutter of claim 55 wherein said base member is a bit body.

57. The cutter of claim 55 wherein said base member is an insert member attachable to a bit body.

58. The cutter of claim 55 wherein said superhard particles of said first set are diamond or cubic boron nitride particles.

59. The cutter of claim 55 wherein said abrasive particles of said second set are diamond, cubic boron nitride, tungsten carbide, silicon carbide, or aluminum oxide particles.

60. The cutter of claim 55 wherein said particles of said first and second sets are single crystal diamond particles.

61. The cutter of claim 55 wherein said second set of particles comprises about 10 to 30% by volume of said first set of particles.

62. The cutter of claim 55 wherein said particles of said first set are in the range of about 400 to 600 microns in diameter, and said particles of said second set are in the range of about 50 to 65 microns in diameter.

63. The cutter of claim 62 wherein said metallic coatings each includes a layer of nickel boride.

64. The cutter of claim 63 wherein said metallic coating on said first set of superhard particles further includes a layer of tungsten, chromium, tantalum, molybdenum, vanadium, copper, tin, nickel, cobalt, iron, palladium, platinum, or alloys thereof.

65. The cutter of claim 64 wherein said binder alloy comprises a nickel, cobalt, iron, aluminum, tin, or copper based alloy.

66. The cutter of claim 65 wherein said base member is made from steel, cemented tungsten carbide, silicon carbide, boron carbide, titanium nitride, or a ceramic material.

67. The cutter of claim 66 wherein said superhard component includes a plurality of layers of said superhard particles of said first set.

68. A method for forming a superhard material-metal composite product at temperatures and pressures below the diamond forming range of temperatures and pressures, comprising

packing a charge of superhard particles into a container, said superhard particles being coated with a metal coating,

introducing a binder alloy into said container, said binder alloy having a melting point of less than 1300°

C. and being capable of wetting said coated superhard particles when caused to flow,

heating said superhard particles and said binder alloy to a temperature between about 650 to 1300°

C. while applying a pressure in the range of about 1,000 to 20,000 psi, thereby causing said binder alloy to flow and to wet said coated superhard particles, and

removing said pressure and allowing said superhard particles and said binder alloy to cool.

69. The method of claim 68 wherein said superhard particles comprise diamond particles.

70. The method of claim 68 wherein said superhard particles and binder alloy are heated to a temperature in the range of about 900 to 1100°

C.

71. The method of claim 68 wherein said superhard particles and binder alloy are subjected to a pressure of about 3,000 to 6,000 psi.

72. The method of claim 68 wherein said superhard particles and binder alloy are subjected to a pressure of about 5,000 psi.

73. The method of claim 68 wherein said heat and pressure are applied for a period of about one to six minutes.

74. The method of claim 68 wherein said binder alloy is introduced into said container prior to introducing said superhard particles into said container.

75. The method of claim 68 further comprising packing a second charge of abrasive particles into said container prior to said heating step, said particles of said second charge being smaller than said particles of said first charge, said particles of said second charge substantially surrounding and being substantially located in the interstices between said particles of said first charge.

76. The method of claim 75 wherein said abrasive particles are diamond, cubic boron nitride, tungsten carbide, silicon carbide, or aluminum oxide particles.

77. The method of claim 75 further comprising packing a third charge of abrasive particles into said container prior to said heating step, said particles of said third charge being smaller than said particles of said second charge.

78. The method of claim 68 further comprising placing a backing member on top of said mixture of superhard particles and binder alloy prior to said heating step.