Structures with multiple polymeric layers comprising a vinylidene fluoride polymer layer bonded to a polar polymer layer

• US 5,096,782 A
• Filed: 04/26/1990
• Issued: 03/17/1992
• Est. Priority Date: 05/05/1989
• Status: Expired due to Fees

• Current Assignee: Solvay & CIE
• Original Assignee: Solvay & CIE
• Inventors: Dehennau, Claude, Dupont, Serge
• Primary Examiner(s): HERBERT JR, THOMAS
• Application Number:
  US07/527,331
• Time in Patent Office: 691 Days
• Field of Search: 428/421, 428/516, 428/519, 428/520, 428/518, 428/412
• US Class Current: 428/412
• CPC Class Codes: B32B 2327/12 containing fluorine
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: B63H 9/067 Sails characterised by their construction or manufacturing process
• CPC Class Codes: C08J 5/124 using adhesives based on a macromolecular component
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/31924 Including polyene monomers
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer

Abstract

Structures with multiple polymeric layers comprising a vinylidene fluoride polymer layer bonded to a polar polymer layer by the use of a polymeric adhesive comprising a vinyl acetate polymer. These structures are characterized in that the product of the weight content of vinyl acetate of the polymeric adhesive, expressed in percent, and its dynamic viscosity at 100° C. and 1 s^-1, expressed in kPa s, is greater than 1.4×10³. The structures with multiple polymeric layers can take the form of films, sheets, panels, tubes or hollow bodies which can be employed particularly in the field of protection against corrosion or ultraviolet rays.

Claims

1. A structure with multiple polymeric layers comprising a vinylidene fluoride polymer layer bonded to a polar polymer layer by the use of a polymeric adhesive comprising a vinyl acetate polymer, which are characterized in that the product of the weight content of vinyl acetate of the polymeric adhesive, expressed in per cent, and its dynamic viscosity at 100°

C. and 1 s^-1, expressed in kPa s, is greater than 1.4×

10³.

2. The structure with multiple polymeric layers according to claim 1, wherein the product of the weight content of vinyl acetate of the polymeric adhesive, expressed in per cent, and its dynamic viscosity at 100°

C. and 1 s^-1, expressed in kPa s, is greater than 1.6×

10³.

3. The structure with multiple polymeric layers according to claim 1, wherein the vinyl acetate polymer is a binary copolymer of vinyl acetate and ethylene containing from 60 to 90% by weight of vinyl acetate.

4. The structure with multiple polymeric layers according to claim 1, wherein the polymeric adhesive consists of 75 to 90% by weight of binary copolymer of vinyl acetate and ethylene containing from 60 to 90% by weight of vinyl acetate and of 25 to 10% by weight of polymethyl methacrylate.

5. The structure with multiple polymeric layers according to claim 1, wherein they result from an assembly by thermal bonding with the aid of a solution of the adhesive polymer.

6. The structure with multiple polymeric layers according to claim 1, assembled by heat-lamination, or by coextrusion.

7. The structure with multiple polymeric layers according to claim 1, assembled by coextrusion-lamination.

8. The structure with multiple polymeric layers according to claim 1, wherein the polar polymer is selected from the group consisting of polyvinyl chloride, acrylonitrile/butadiene/styrene (ABS) copolymers and aromatic polycarbonates.

9. The structure with multiple polymeric layers according to claim 8, wherein the polar polymer is flexible polyvinyl chloride whose Shore A hardness does not exceed 90.

10. The structure with multiple polymeric layers according to claim 1, wherein the polymeric adhesive contains an effective amount of polymethyl methacrylate to improve the heat stability of the polymeric adhesive.

11. The structure with multiple polymeric layers according to claim 10, wherein the polymeric adhesive contains polymethyl methacrylate in a quantity not exceeding 50% by weight.

12. The structure with multiple polymeric layers according to claim 11, wherein the polymeric adhesive contains polymethyl methacrylate in a quantity not exceeding 25% by weight.