Polyester film with nodule surface

• US 5,096,784 A
• Filed: 12/20/1989
• Issued: 03/17/1992
• Est. Priority Date: 12/20/1989
• Status: Expired due to Term

• Current Assignee: Hoechst Diafoil Company
• Original Assignee: Hoechst Celanese Corporation (Sanofi )
• Inventors: Culbertson, Edwin C., Heberger, John M.
• Primary Examiner(s): Cashion, Jr., Merrell C.
• Assistant Examiner(s): Le, Hoa T.
• Application Number:
  US07/453,728
• Time in Patent Office: 818 Days
• Field of Search: 428/480, 428/483, 428/332, 428/409, 428/482, 524/365
• US Class Current: 428/482
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 2433/00 Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C09D 133/12 Homopolymers or copolymers of methyl methacrylate
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
• CPC Class Codes: Y10T 428/24372 Particulate matter
• CPC Class Codes: Y10T 428/24405 Polymer or resin [e.g., natural or synthetic rubber, etc.]
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/31 Surface property or characteristic of web, sheet or block
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31794 Of cross-linked polyester
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

A polyester film having a nodule surface is disclosed. The acrylic coating is preferably a crosslinked composition having a relatively high methyl methacrylate content and specific surfactants. The acrylic coating composition is applied as an aqueous dispersion to polyester film, preferably after corona treatment of the polyester film. The nodule surface reduces the coefficient of friction of the polyester film. The coating composition comprises from 60 to 90 mole percent methyl methacrylate; from 10 to 35 mole percent of at least one modifier selected from the group of ethyl acrylate, propyl acrylate, butyl acrylate, and mixtures of these; and from 3 to 10 mole percent of a crosslinkable monomer or a self-crosslinking monomer selected from the group of N-methylol methacrylamide, N-methylol acrylamide, acrylamide, methacrylamide, and mixtures of these; with from 2 to 15 weight percent of the nonionic surfactant and at least 0.1 percent by weight of the anionic surfactant.

Claims

1. An oriented polyester film having a nodule surface for producing a low coefficient of friction surface comprising:

an oriented polyester film having an acrylic coating composition on at least one surface, said acrylic coating being a dried residue of an aqueous emulsion comprising;

(a) from 80 to 97.9 percent by weight, based upon the total weight of said composition, of a methyl methacrylate terpolymer comprising;

(1) from 60 to 90 mole percent of methyl methacrylate;

(2) from 10 to 35 mole percent of at least one modifier selected from the group consisting of ethyl acrylate, propyl acrylate, butyl acrylate, and a mixture of these;

(3) from 1 to 10 mole percent of at least one comonomer selected from the group consisting of N-methylol acrylamide, N-methylol methacrylamide, acrylamide, methacrylamide, and a mixture of these;

(b) from 2 to 15 percent by weight, based upon the total weight of said coating composition, of a nonionic surfactant;

(c) at least from about 0.1 percent by weight, based upon the total weight of said coating composition, of an anionic surfactant;

wherein said acrylic coating forms a nodule surface characterized by nodule islands rising from the surface of said film with a minimum surface area coverage of about 5 percent.

2. The coated film of claim 1, wherein said nonionic surfactant is an alkylphenol ethoxylate.

3. The coated film of claim 2, wherein said alkylphenol ethoxylate is octylphenol ethoxylate with a nominal degree of polymerization of 40.

4. The coated film of claim 1, wherein said nonionic surfactant is selected from the group consisting of sodium lauryl sulfate and sodium dodecylbenzene sulfonate.

5. The coated film of claim 1, wherein said nonionic surfactant is from about 2 to about 10 percent by weight, based on the total weight of said coating composition.

6. The coated film of claim 5, wherein said anionic surfactant is in a range from about 0.1 to about 0.5 percent by weight, based upon the total weight of said coating composition.

7. The coated film of claim 1, wherein said coating further comprises colloidal silica.

8. The coated film of claim 1, wherein said comonomer is self-crosslinking, and wherein said modifier is ethyl acrylate, and wherein said non-ionic surfactant is octylphenol ethoxylate, and wherein said anionic surfactant is sodium lauryl sulfate.