Mirror and method of manufacturing same

• US 5,096,785 A
• Filed: 01/18/1990
• Issued: 03/17/1992
• Est. Priority Date: 01/26/1989
• Status: Expired due to Fees

• Current Assignee: Glaverbel
• Original Assignee: Glaverbel
• Inventors: Somerhausen, Bernard, Servais, Albert
• Primary Examiner(s): Dean, Richard O.
• Assistant Examiner(s): Wyszomierski, George
• Application Number:
  US07/466,918
• Time in Patent Office: 789 Days
• Field of Search: 428/621, 428/626, 428/673, 428/674, 428/76, 428/912.2, 350/641, 427/409, 427/410
• US Class Current: 428/626
• CPC Class Codes: G02B 1/105 Protective coatings
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: G02B 5/0808 having a single reflecting layer G02B5/0883, G02B5/0891 take precedence
• CPC Class Codes: G02B 5/0858 the reflecting layers comprising a single metallic layer with one or more dielectric layers
• CPC Class Codes: Y10T 428/12569 Synthetic resin
• CPC Class Codes: Y10T 428/12896 Ag-base component
• CPC Class Codes: Y10T 428/12903 Cu-base component

Abstract

A mirror comprises a transparent glass sheet having a reflective metal coating deposited on the glass and a protective coating applied to the reflective coating. The protective coating comprises a paint having a residual internal stress S_R equal to or less than 1 MPa, measured by the Cantilever method (as defined) at a temperature above its glass transition temperature. One suitable paint used in coating the mirror has the following composition:

50% pigments:

10% titanium dioxide

45% barium sulphate

25% talc

15% lead pigment

5% coloring pigment and carbon black

15% binder

100% epoxy resin ester with 45% castor oil

35% solvents

5% butanol and isobutanol

95% xylene.

The glass transition temperature of the paint is approximately 10° C., the residual internal stress at 20° C. is approximately 0.05 MPa and the Persoz hardness is approximately 120.

Claims

1. A mirror, comprising:

a glass sheet which is transparent;

a reflective metal coating deposited on at least one surface of the glass sheet; and

a protective coating applied to the reflective metal coating and comprising a paint which has a glass transition temperature of less than 35°

C. and which has a residual internal stress S_R equal to or less than 1 MPa when measured by a Cantilever method as defined herein 20°

C. or at at a temperature which is 5°

C. above its glass transition temperature whichever is higher, at which temperature a curve of internal stress as a function of temperature becomes substantially parallel to the temperature axis whereby said mirror shows a means marginal corrosion of no more than about 1.0 mm when subjected to a saline mist test as described herein.

2. The mirror as claimed in claim 1, wherein the paint has a glass transition temperature of less than 20°

C.

3. The mirror as claimed in claim 1, wherein the paint has a pigmentary volume concentration which is close to but slightly less than a critical pigmentary volume concentration.

4. The mirror as claimed in claim 1, wherein the paint has a pigmentary volume concentration which ranges between 50% and 90% of a critical pigmentary volume concentration.

5. The mirror as claimed in claim 1, wherein the paint has a Persoz harndess of less than 180.

6. The mirror as claimed in claim 1, wherein the paint has a Persoz hardness of less than 150.

7. The mirror as claimed in claim 1, wherein the paint includes a binder selected from the group consisting of polyester, acrylic, epoxy, cellulosic and phenolic resins.

8. The mirror as claimed in claim 1, wherein the paint includes a binder containing less than 30% by weight of fatty acid.

9. The mirror as claimed in claim 1, wherein the paint includes a binder containing a non-siccative fatty acid.

10. The mirror as claimed in claim 1, wherein the paint includes a binder containing less than 10% by weight of melamine formaldehyde.

11. The mirror as claimed in claim 1, wherein the paint presents substantially no reactivity towards oxygen.

12. The mirror as claimed in claim 1, wherein the reflective metal coating is formed of a material selected from the group consisting of silver, copper and a composite layer of copper deposited on silver.

13. The mirror as claimed in claim 1, wherein the reflective metal coating is selected from the group consisting of a layer of copper and a layer of a reflective metal other than copper and a layer of copper deposited on the reflective metal other than copper, and wherein an azole composition is applied to the copper.

14. The mirror as claimed in claim 13, wherein he azole composition is selected from 5-amino tetrazole, 3-amino-1,2,4-triazole, 7-aminoindazole and indazole.

15. The mirror as claimed in claim 13, wherein the azole composition is incorporated in the paint.

16. The mirror as claimed in claim 13, wherein the azole composition is applied as a separate coating layer.

17. The mirror as claimed in claim 1, wherein the paint comprises a first paint and a second paint, and wherein a layer of the second paint is superimposed on a layer of the first paint, said layer of the second paint being harder than said layer of the first paint.

18. A method of manufacturing a mirror comprising:

depositing a reflective metal coating on a glass sheet; and

applying a protective coating to the reflective metal coating which is comprised of a paint having a glass transition temperatur eof less than 35°

C., and having a residual internal stress S_R equal to or less than 1 MPa when measured by a Cantilever method as defined ehrein at 20°

C. or at a temperature which is 5°

C. above its glass transition temperature whichever is higher, at which temperature a curve of internal stress as a function of temperature becomes substantially parallel to the temperature axis whereby a mirror thus produced shows a mean marginal corrosion of no more than about 1.0 mm when subjected to a saline mist test as described herein.

19. The method as claimed in claim 18, wherein the reflective metal coating is selected from the group consisting of a layer of copper and a layer of a reflective metal other than copper and a layer of copper deposited on the other metal, and wherein the method further comprises depositng an azole composition on the copper prior to applying the paint.

20. The method as claimed in claim 18, wherein the paint is applied by means of a curtain coating apparatus including the steps of conveying the glass sheet at a controlled uniform speed and in a horizontal plane through the curtain coating apparatus with the reflective metal coating uppermost, and depositing a uniform layer of paint on the reflective metal coating by causing a continuous film of paint to fall on the reflective metal coating under the influence of gravity.

21. The method as claim 18, wherein the method further comprises baking the paint in a furnace and wherein the paint applied achieves its final strength after leaving the furance within the time needed to cool the mirror to room temperature.