Semi-continuous method and apparatus for forming a heated and pressurized mixture of fluids in a predetermined proportion

• US 5,098,194 A
• Filed: 06/27/1990
• Issued: 03/24/1992
• Est. Priority Date: 06/27/1990
• Status: Expired due to Fees

• Current Assignee: Union Carbide Chemicals And Plastics Company, Inc.
• Original Assignee: Union Carbide Chemicals & Plastics Technology Corporation (Dow, Inc.)
• Inventors: Condron, James A., Hoy, Kenneth L., Kuo, Alex C.
• Primary Examiner(s): JENKINS, ROBERT
• Application Number:
  US07/544,777
• Time in Patent Office: 636 Days
• Field of Search: 366/348, 366/349, 366/136, 366/137, 366/139, 366/144, 366/145, 366/146, 366/147, 366/148, 366/149, 366/151, 366/159, 366/160, 366/161, 366/162, 366/336, 366/337, 366/338 , 366/339, 366/340, 366/152, 427/422, 427/421
• US Class Current: 366/144
• CPC Class Codes: B01F 23/29 Mixing systems, i.e. flow charts or diagrams
• CPC Class Codes: B05B 12/1418 for supplying several liquids or other fluent materials in selected proportions to a single spray outlet controlling ratio of two or more flows of fluid G05D11/02
• CPC Class Codes: B05B 7/32 the fed liquid or other fluent material being under pressure
• CPC Class Codes: B05D 1/025 using gas close to its critical state
• CPC Class Codes: B29B 7/002 Methods chemical aspects C08J3/00

Abstract

The present invention is directed to apparatus and methods for effectively supplying, feeding, measuring, proportioning, mixing, pressurizing, and heating on a semi-continuous basis, a plurality of fluids. Preferably, the fluids comprise at least one substantially non-compressible fluid, such as coating formulation, and at least one substantially compressible fluid, such as carbon dioxide, to form a substantially accurately proportionated coating admixture in the supercritical state of the compressible fluid for spraying the combined mixture through a spraying means onto a substrate to produce a coating. The process employs vessels having a known displacement volume to feed and proportion the fluids. The pressurization, mixing and heating is accomplished in an oscillation loop wherein the mixture is pressurized and heated while in such oscillation loop. A spray gun connected to the oscillation loop is used to spray the mixture.

Claims

1. An apparatus for mixing, heating and pressurizing two or more fluids comprising:

(a) at least two or more vessels each having walls and an upper and lower end;

(b) means communicating between said vessels for conveying the fluids from one or more of the vessels to one or more of the other of said vessels;

(c) means for continuously oscillating the fluids through the communicating means from at least one of said vessels to at least one of the other of said vessels comprising a reciprocating displacement means contained in each of the vessels for displacing the fluids contained in said vessels, where said oscillation of the fluids provides for their mixing;

(d) means for pressurizing the fluids as they are being oscillated between the vessels; and

(e) means for heating the fluids as they are being oscillated through the vessels.

2. The apparatus of claim 1, wherein the displacement means comprises a piston with suitable sealing means having a front face and a back face;

the front face facing the lower end of the vessel and being in contact with the fluids such that the fluids are contained within the walls of the vessel, the front face of the piston, and the lower end of the vessel which communicates with communicating means (b);

the back face being mounted on a piston rod;

said piston being capable of reciprocally traversing the length of the vessel such that when the front face of the piston is in substantial proximity to the lower end of the vessel, substantially all of the fluids have been displaced from the vessel to communicating means (b).

3. The apparatus of claim 2, wherein the piston rod is engaged with a pressure force means.

4. The apparatus of claim 3, wherein the pressure force means comprises pressurized hydraulic fluid, compressed air, or an electromechanical means.

5. The apparatus of claim 1, wherein the two or more vessels each comprise an accumulator.

6. The apparatus of claim 1, wherein the means for pressurizing the fluids as they are are being oscillated between the vessels is by the displacement means acting on the fluids as they are being displaced.

7. The apparatus of claim 6, wherein the displacement means includes means for measuring the pressure on the fluids and generating a signal in response to such pressure measurement.

8. The apparatus of claim 7, wherein the means for measuring the pressure on the fluids and generating a signal in response to such pressure measurement is a pressure switch.

9. The apparatus of claim 7, wherein the displacement means also includes a switching means responsive to the generated signal which causes the displacement means in one or more of the vessels to stop the displacement of the fluids while causing the displacement means in one or more of the other vessels to begin displacement of the fluids in a synchronized manner.

10. The apparatus of claim 9, wherein the switching means is a solenoid valve.

11. The apparatus of claim 1, wherein the means for heating the fluids as they are being oscillated between the vessels is located in or on one or more of the vessels.

12. The apparatus of claim 11, wherein the heating means is an electrically heated element.

13. The apparatus of claim 1, wherein the means for heating the fluids as they are being oscillated between the vessels is located in communicating means (b).

14. The apparatus of claim 13, wherein the heating means is a heat exchanger.

15. The apparatus of claim 11, wherein communicating means (b) contains a static mixer type stationary mixing device.

16. A method of mixing, heating and pressurizing two or more fluids comprising:

(a) supplying the fluids to at least one of at least two or more vessels;

(b) oscillating the fluids from at least one of said vessels to at least one of the other of said vessels by synchronized displacement of the fluids in one or more of the vessels and introduction of the fluids in one or more of the other vessels, where said oscillation of the fluids by said synchronized displacement provides for their mixing;

(c) pressurizing the fluids as they are being oscillated between the vessels; and

(d) heating the fluids as they are being oscillated between the vessels.

17. The method of claim 16, wherein the fluids are pressurized by their being displaced from at least one of the vessels and introduced into at least one of the other vessels.

18. The method of claim 16, wherein the fluids are heated in the vessels.

19. The method of claim 18, wherein the fluids are heated in the vessels by electrically heated elements.

20. The method of claim 16, wherein the fluids are heated by heat exchangers as they are oscillated from the at least one or more vessels to the at least one or more other vessels.

21. The method of claim 16, wherein the at least two or more vessels each comprise accumulators.

22. The method of claim 16, wherein at least one of the fluids is a compressible fluid and at least one of the other fluids is a non-compressible fluid.