Inks with dendrimer colorants

• US 5,098,475 A
• Filed: 01/28/1991
• Issued: 03/24/1992
• Est. Priority Date: 01/28/1991
• Status: Expired due to Term

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Davidson, Anthony R., Breton, Marcel P., Winnik, Francoise M.
• Primary Examiner(s): LEVY, NEIL S
• Assistant Examiner(s): Einsmann, Margaret V.
• Application Number:
  US07/646,904
• Time in Patent Office: 421 Days
• Field of Search: 106/22, 525/259, 528/405, 528/332, 528/418
• US Class Current: 524/386
• CPC Class Codes: C09B 69/10 Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds addition products of alkylene oxide to dyes, C09B69/00; dyeing with polymeric dyes D06P1/0056
• CPC Class Codes: C09D 11/328 characterised by dyes
• CPC Class Codes: Y10S 424/16 Dendrimers and dendritic polymers

Abstract

An ink composition comprising a solution with a dendrimer colored with a dye or dyes covalently attached thereto. As optional additives there may be included in the ink humectants and biocides. The aforementioned inks can be prepared by mixing the appropriate components such as a dendrimer, water and a reactive dye. Also disclosed is a process for the utilization of the aforementioned compositions and ink jet printing processes.

Claims

1. An aqueous ink composition comprising a solution of a dendrimer colored with a dye or dyes covalently attached thereto.

2. An ink in accordance with claim 1 wherein the solution contains water, and three different dye colors.

3. An ink in accordance with claim 1 wherein the solution contains water, a humectant, and a biocide.

4. An ink in accordance with claim 1 wherein the dendrimer is a first, second or third generation dendrimer.

5. An ink in accordance with claim 1 wherein the dendrimer is microparticle of the first generation with an average diameter of about 10.8 Angstroms, and with 6 terminal amino groups.

6. An ink in accordance with claim 1 wherein the dendrimer is a microparticle of the third generation with an average diameter of about 22 Angstroms and with 24 terminal amino groups.

7. An ink in accordance with claim 1 wherein the dye or dyes are selected from Reactive dyes.

8. An ink in accordance with claim 1 wherein the dye is selected from the group consisting of anthraquinones, monoazo dyes, disazo dyes, phthalocyanines, aza[18]annulenes, formazan copper complexes, and triphenodioxazines, to which are covalently attached reactive groups.

9. An ink in accordance with claim 1 wherein the dye comprises a reactive group selected from the group consisting of dichlorotriazines, monochlorotriazines, dichloroquinoxalines, aminoepoxides, mono-(m-carboxypyridinium)-triazines, 2,4,5-trihalogenopyrimidines, 2,4-dichloropyrimidines, 2,3-dichloroquinoxalines, monofluorotriazines, 4,5-dichloro-6-methyl-2-methylsulfonylpyrimidines, 1,4-dichlorophthalazines, chlorobenzo-thiazoles, sulfatoethylsulfones, β

-chloroethylsulfones, 4,5-dichloro-6-pyridazones, α

-bromoacryloylamidos, and α

,β

-dibromopropionylamidos.

10. An ink in accordance with claim 1 wherein the dye is present in an amount of about 0.5 to about 10 percent by weight, the dendrimer is present in an amount of about 1 to about 15 percent by weight, and the solution contains water in an amount of from about 75 to about 98.5 percent by weight.

11. An ink in accordance with claim 1 wherein the dye is present in an amount of about 2 to about 7 percent by weight, the dendrimer is present in an amount of from about 2 to about 13 percent by weight, and the solution contains water in an amount of from about 96 to about 80 percent by weight.

12. An ink in accordance with claim 3 wherein the humectant is present in the amount of from about 2 to about 50 percent by weight.

13. An ink in accordance with claim 12 wherein the humectant is a glycol.

14. An ink in accordance with claim 12 wherein the humectant is a glycol selected from the group consisting of ethylene glycol, propylene glycol, diethylene glycol, and mixtures thereof.

15. An ink in accordance with claim 12 wherein the biocide is present in the amount of from about 0.02 to about 0.1 percent by weight.

18. An ink in accordance with claim 2 wherein distilled water or deionized water is selected.

16. An ink composition comprised of a solution of water, and a dendrimer colored with a dye attached thereto.

17. An ink in accordance with claim 16 wherein the solution contains a biocide, and a humectant.