Catalyst composition for oxidation of ethylene to ethylene oxide

• US 5,102,848 A
• Filed: 09/28/1990
• Issued: 04/07/1992
• Est. Priority Date: 09/28/1990
• Status: Expired due to Term

• Current Assignee: Dow Technology Investments LLC (Dow, Inc.)
• Original Assignee: Union Carbide Chemicals & Plastics Technology Corporation (Dow, Inc.)
• Inventors: Soo, Hwaili, Bhasin, Madan M., Chou, Pen-Yuan
• Primary Examiner(s): Shine, W. J.
• Assistant Examiner(s): McGinty, Douglas J.
• Application Number:
  US07/589,213
• Time in Patent Office: 557 Days
• Field of Search: 502/347, 502/348, 502/217, 502/218
• US Class Current: 502/218
• CPC Class Codes: B01J 23/682 with vanadium, niobium, tantalum or polonium
• CPC Class Codes: B01J 23/683 with chromium, molybdenum or tungsten
• CPC Class Codes: B01J 27/055 with alkali metals, copper, gold or silver
• CPC Class Codes: B01J 27/12 Fluorides
• CPC Class Codes: C07D 301/10 with catalysts containing silver or gold

Abstract

Catalysts for the epoxidation of ethylene in the vapor phase comprise silver impregnated support having thereon at least one cation promoter and oxyanion promoter comprising (i) sulfate anion, (ii) fluoride anion and (iii) oxyanion of an element of Group 3b to 6b, inclusive, of the Periodic Table, wherein the amount of fluoride anion is sufficient to reduce ethylene oxide burning.

Claims

1. A catalyst for the epoxidation of ethylene to the ethylene oxide comprising a catalytically effective amount of silver impregnated on an inert, refractory solid support which support has an essential absence of fluoride anion, said catalyst further containing an efficiency enhancing amount, relative to the amount of silver metal, of promoter comprising cation selected from at least one member of the group of lithium, sodium, potassium, rubidium, cesium, and barium and anion comprising (i) sulfate, (ii) fluoride and (iii) at least one member of the group of oxyanions of elements having atomic numbers of 21 to 74, inclusive, selected from Groups 3b to 6b, inclusive, of the Periodic Table of Elements, wherein the sulfate and fluoride anions may be in the form of fluorosulfate and the fluoride anion is also in an amount sufficient to reduce ethylene oxide burning as compared to an otherwise identical catalyst but not containing the fluoride anion and its associated cation.

2. The catalyst of claim 1 in which the at least one oxyanion of elements having atomic numbers of 21 to 74, inclusive, is selected from Group 5b and 6b of the Periodic Table of the Elements.

3. The catalyst of claim 2 in which the at least one oxyanion of elements having atomic numbers of 21 to 74, inclusive, is oxyanion of molybdenum.

4. The catalyst of claim 1 in which the cation promoter comprises cesium cation.

5. The catalyst of claim 4 in which the at least one oxyanion of elements having atomic numbers of 21 to 74, inclusive, is selected from Group 5b and 6b of the Periodic Table of the Elements.

6. The catalyst of claim 5 in which the at least one oxyanion of elements having atomic numbers of 21 to 74, inclusive, is oxyanion of molybdenum.

7. The catalyst of claim 1 in which the atomic ratio of Group 3b to 6b element of the oxyanion to sulfur is between about 1:

10 to 10;

1.

8. The catalyst of claim 7 in which the atomic ratio of sulfur to fluorine is between about 1:

10 to 10;

1

9. The catalyst of claim 8 in which the at least one oxyanion of elements having atomic numbers of 21 to 74, inclusive, is selected from Group 5b and 6b of the Periodic Table of the Elements.

10. The catalyst of claim 9 in which the at least one oxyanion of elements having atomic numbers of 21 to 74, inclusive, is oxyanion of molybdenum.

11. The catalyst of claim 2 in which the total anion promoter is provided from about 0.001 to 0.5 weight percent based on the total weight of the catalyst.

12. The catalyst of claim 11 in which the cation promoter is provided in an amount of 10 to 2000 ppmw.

13. The catalyst of claim 12 in which fluoride anion is present in an amount of at least 20 ppmw.

14. The catalyst of claim 13 in which the atomic ratio of sulfur to fluorine is between about 1:

10 to 10;

1

15. The catalyst of claim 14 in which the support is alpha-alumina.

16. The catalyst of claim 2 in which the support is alpha-alumina.

17. The catalyst of claim 1 in which the at least one oxyanion of elements having atomic numbers of 21 to 74, inclusive, is oxyanion of tungsten.