Composition monitor and monitoring process using impedance measurements

• US 5,103,181 A
• Filed: 10/05/1988
• Issued: 04/07/1992
• Est. Priority Date: 10/05/1988
• Status: Expired due to Term

• Current Assignee: Den Norske Opera & Ballett As (Government of Norway)
• Original Assignee: Den Norske Oljeselskap A. S.
• Inventors: Gaisford, Scott G., Watjen, John P., Bjornsen, Bjorn G.
• Primary Examiner(s): Weider, Kenneth
• Assistant Examiner(s): Harvey, Jack B.
• Application Number:
  US07/254,415
• Time in Patent Office: 1,280 Days
• Field of Search: 324/58 R, 324/58 B, 324/58.5 R, 324/58 A, 324/58.5 A, 324/633, 324/634, 324/635, 324/637, 324/639-643, 324/645-648, 73/61 R, 73/61.1 R, 333/248
• US Class Current: 324/637
• CPC Class Codes: G01N 22/00 Investigating or analysing materials by the use of microwaves or radio waves, i.e. electromagnetic waves with a wavelength of one millimetre or more G01N3/00 - G01N17/00, G01N24/00 take precedence
• CPC Class Codes: G01N 33/2823 Raw oil, drilling fluid or polyphasic mixtures

Abstract

Radio frequency bridge techniques are used to parameterize the complex dielectric properties of solids, liquids, gasses and mixtures thereof. This parameterization is performed in an electrically isolated, physically open structure which allows continuous or batch monitoring of the materials and their mixtures. A method and apparatus are provided for measuring the composition of mutlicomponent process streams flowing in pipes or ducts. The method uses the pipe in which the mixture flows as a waveguide in which propagating radio frequency electromagnetic energy is induced through dielectric loaded apertures. The dielectric measurement is performed in an electrically isolated, flow through test section which induces constructive or destructive interference patterns at characteristics frequencies. The characteristic frequency determines the dielectric constant of the mixture. The dielectric properties are used in turn to determine mixture composition. A density measurement is also provided for three comiponent strams such as oil, water, and gas. Temperature and pressure measurements are made to correct for temperature and pressure induced variations in calibrated component impedance and density values.

Claims

1. A multiple component composition monitor, which comprises:

a transducer having an electrically conductive wall forming an enclosure with physically open ends for insertion of the composition, said transducer including a test section having a first end and a second end;

at least one electromagnetic wave transmission coupler; and

an electromagnetic wave receiving coupler facing said enclosure;

said at least one transmission coupler being positioned at a first location on said test section to create electromagnetic waves in said enclosure and said receiving coupler being positioned at a second location on said test section to receive electromagnetic waves from said enclosure;

said transducer further including an impedance section at each of said first and second ends of said test section, each said impedance section having an impedance different from an impedance of said test section;

a circuit in which said transducer comprises at least one electrical path in said circuit; and

means for producing a minimum or maximum output from said circuit by inducing an electromagnetic interference pattern, said minimum or maximum output serving to characterize relative proportions of the components in the composition.

2. The multiple component composition monitor of claim 1 in which each said impedance section for terminating said test section comprises at least one physical discontinuity in said electrically conductive wall.

3. The multiple component composition monitor of claim 2 in which each said physical discontinuity in said electrically conductive wall comprises at least one portion of said electrically conductive wall having a greater cross section than remainder of said electrically conductive wall.

4. The multiple component composition monitor of claim 3 in which each said physical discontinuity lies substantially in a plane transverse to a longitudinal dimension of the enclosure.

5. The multiple component composition monitor of claim 1 in which said transmitting and receiving couplers are positioned in said electrically conductive wall.

6. The multiple component composition monitor of claim 1, in which:

said at least one electromagnetic wave transmission coupler comprises a plurality of electromagnetic wave transmitting apertures, and said at least one electromagnetic wave receiving coupler comprises a plurality of electromagnetic wave receiving apertures, said transmitting and receiving apertures being positioned around said electrically conductive wall.

7. The multiple component composition monitor of claim 1 in which said at least one transmission coupler comprises at least a first transmitting coupler and a second transmitting coupler, wherein said receiving coupler is positioned at a different distance from said first transmitting coupler than from said second transmitting coupler.

8. The multiple component composition monitor of claim 1, further including means external to said test section for splitting an input signal to said test section into first and second signal portions, wherein said circuit comprises a bridge circuit serving to balance the first and second signal portions, said means for splitting the input signal being connected to pass at least one said first signal portion through said test section, and said means for producing a minimum or maximum output from said circuit being connected to receive said second signal portion for tuning said circuit to produce the maximum or minimum.

9. The multiple component composition monitor of claim 8 in which said test section including a substantially lossless waveguide material and said impedance section includes a lossy waveguide material at each of said first and second ends of said test section.

10. The multiple component composition monitor of claim 8 in which said means for producing a minimum output from said bridge circuit includes means for obtaining a transmission phase difference of 180 degrees between said first and second signal portions.

11. The multiple component composition monitor of claim 8 in which said means for producing a minimum output from said bridge circuit includes means for adjusting a transmission property of the second signal portion to produce a null output.

12. The multiple component composition monitor of claim 11, in which said means for adjusting a transmission property of the second signal portion includes means for adjusting attenuation of said second signal portion.

13. The multiple component composition monitor of claim 11, in which said means for adjusting a transmission property of the second signal portion includes means for adjusting phase of the second signal portion.

14. The multiple component composition monitor of claim 11, in which said means for adjusting a transmission property of the second signal portion includes means for adjusting phase and attenuation of the second signal portion.

15. The multiple component composition monitor of claim 8, wherein said circuit is configured for passing said first and second signal portions through said test section, and for passing said second signal portion but not said first signal portion through said means for producing a minimum or maximum output.

16. The multiple component composition monitor of claim 15, wherein said means for producing a minimum or maximum output includes a frequency generator connected for providing said input signal to said signal splitting means, and means for adjusting frequency of said second signal portion.

17. The multiple component composition monitor of claim 16, wherein said means for producing a minimum or maximum output further comprises a variable resistor connected for adjusting attenuation of said second signal portion.

18. The multiple component composition monitor of claim 8, wherein said impedance section comprises a lossy load section connected to each of said first and second ends of said test section.

19. The multiple component composition monitor of claim 8, wherein said means for producing a minimum or maximum output includes a variable frequency generator connected for providing said input signal to said signal splitting means, and a variable resistor connected for adjusting attenuation of said second signal portion.

20. The multiple component composition monitor of claim 8, wherein said means for producing a minimum or maximum output includes a variable resistor and a phase adjustor connected for adjusting attenuation and phase, respectively, of said second signal portion.

21. The multiple component composition monitor of claim 1 additionally comprising a means connected to said at least one transmitting coupler for varying frequency of the electromagnetic waves.

22. The multiple component composition monitor of claim 1 in which said enclosure includes a passage adapted for flowing the composition therethrough.

23. The multiple component composition monitor of claim 1, said monitor constituting a first monitor mounted at a first location on a pipe for flowing said composition therethrough, wherein a second multiple component composition monitor in accordance with claim 1 is mounted at a second location on said pipe at a distance from said first location, and wherein said first and second monitors in combination constitute means for determining a flow rate of the composition through said pipe, further including means connected to said first and second monitors for cross-correlating output signals from said multiple component composition monitor and said second composition monitor for determining a length of time taken for a portion of the composition to travel from said first location to said second location.

24. The multiple component composition monitor of claim 1, wherein a material injection port is mounted on said pipe at a known distance upstream from said multiple component composition monitor, wherein said composition monitor and material injection port in combination constitute means for determining a flow rate of the composition through said pipe, said flow rate determining means further including means for measuring an amount of time taken for material injected at said material injection port to travel to said multiple component composition monitor.

25. The multiple component composition monitor of claim 1 in which said circuit comprises a bridge circuit having a first electrical path and a second electrical path, said second electrical path including adjustable circuit elements external of said transducer.

26. The multiple component composition monitor of claim 25, in which the adjustable circuit elements comprise a variable attenuator.

27. The multiple component composition monitor of claim 25, in which the adjustable circuit element comprises a variable phase shifter.

28. The multiple component composition monitor of claim 1, in which said circuit constitutes a bridge circuit and said transducer comprises two electrical paths in said bridge circuit.

29. The multiple component composition monitor of claim 1, further including a density monitor connected to said transducer at a location spaced from said test section for measuring density of the composition.

30. The multiple component composition monitor of claim 29, further including means coupled to said density monitor for comparing said measured density with a calculated density for the composition.

47. The process of claim 30 additionally comprising the step of measuring density of the multiple component mixture.

54. The process of claim 53, wherein steps 1 through 6 are carried out at a first location at a first time, and comprise a first composition measurement, and wherein the flow rate determining step includes the steps of:

generating a second composition measurement by measuring the composition of the multiple component mixture in accordance with claim 30 at a second time at a second location spaced from the first location; and

cross-correlating the first and second composition measurements.

56. The multiple component composition monitor of claim 22, including means coupled to said passage for determining a flow rate of the composition therethrough.

31. A multiple component composition monitor, comprising:

a transducer having an electrically conductive wall forming an enclosure with physically open ends for insertion of the composition, said transducer including a test section having a first end and a second end;

at least one electromagnetic wave transmission coupler; and

an electromagnetic wave receiving coupler facing said enclosure;

said at least one transmission coupler being positioned to create electromagnetic waves in said enclosure and said receiving coupler being positioned to receive electromagnetic waves from said enclosure;

said at least one transmission coupler and said receiving coupler being located in said test section;

said transducer further including an impedance section at each of said first and second ends of said test section, each said impedance section having an impedance different from an impedance of said test section;

a circuit in which said transducer comprises at least one electrical path in said circuit; and

means for producing a minimum or maximum output from said circuit by inducing an electromagnetic interference pattern, said minimum or maximum output serving to characterize relative proportions of the components in the composition;

in which said impedance section comprises a sleeve of insulating material positioned on an inside source of said electrically conductive wall, said sleeve of insulating material having a first portion of a first insulating material adjacent said transmitting and receiving couplers, said sleeve of insulating material having second portions of a second insulating material, with one said second portion joined to said first portion on each side of said transmitting and receiving couplers, the second insulating material having a substantially different dielectric constant than the first insulating material.

32. A multiple component composition monitor, comprising:

a transducer having an electrically conductive wall forming an enclosure with physically open ends for insertion of the composition, said transducer including a test section having a first end and a second end;

at least one electromagnetic wave transmission coupler; and

an electromagnetic wave receiving coupler facing said enclosure;

said at least one transmission coupler being positioned to create electromagnetic waves in said enclosure and said receiving coupler being positioned to receive electromagnetic waves from said enclosure;

said at least one transmission coupler and said receiving coupler being located in said test section;

said transducer further including an impedance section at each of said first and second ends of said test section, each said impedance section having an impedance different from an impedance of said test section;

a circuit in which said transducer comprises at least noe electrical path in said circuit; and

means for producing a minimum or maximum output from said circuit by inducing an electromagnetic interference pattern, said minimum or maximum output serving to characterize relative proportions of the components in the composition;

in which said impedance section comprises portions of said electrically conductive wall positioned on either side of said test section, wherein said test section has a cutoff frequency different from a cutoff frequency of said impedance section.

33. The multiple component composition monitor of claim 32 additionally comprising an insulating sleeve extending through the first portion and the second portions of said electrically conductive wall.

34. The multiple component composition of claim 32, wherein said test section has a perimeter that is noncoextensive with a perimeter of said impedance section.

35. The multiple component composition of claim 34, wherein said test section has a different size than said impedance section.

36. The multiple component composition of claim 34, wherein said test section has a different shape than said impedance section.

37. The multiple component composition of claim 34, wherein said test section has a different geometrical arrangement than said impedance section.

38. The multiple component composition of claim 34, wherein said test section has a different diameter than said impedance section.

39. The multiple component composition of claim 38, wherein said test section has a larger diameter than said impedance section.

40. The multiple component composition of claim 38, wherein said test section has a smaller diameter than said impedance section.

41. A multiple component composition monitor, comprising:

a transducer having an electrically conductive wall forming an enclosure with physically open ends for insertion of the composition, said transducer including a test section having a first end and a second end;

at least one electromagnetic wave transmission coupler; and

an electromagnetic wave receiving coupler facing said enclosure;

said at least one transmission coupler being positioned to create electromagnetic waves in said enclosure and said receiving coupler being positioned to receive electromagnetic waves from said enclosure;

said at least one transmission coupler and said receiving coupler being located in said test section;

said transducer further including an impedance section at each of said first and second ends of said test section, each said impedance section having an impedance different from an impedance of said test section;

a circuit in which said transducer comprises at least noe electrical path in said circuit; and

means for producing a minimum or maximum output from said circuit by inducing an electromagnetic interference pattern, said minimum or maximum output serving to characterize relative proportions of the components in the composition;

in which said impedance section comprises a waveguide reactive load section connected to each of said first and second ends of said test section, said waveguide reactive load sections being generally parallel to a longitudinal dimension of said test section and segmented by a plurality of metal surfaces.

42. A multiple component composition monitor transducer, which comprises:

an electrically conductive wall forming an enclosure for the composition;

at least a pair of electromagnetic wave transmission couplers and an electromagnetic wave receiving coupler facing said enclosure;

said at least a pair of transmission couplers being positioned to create interfering electromagnetic waves in said enclosure and said receiving coupler being positioned to receive electromagnetic waves from said enclosure; and

means for electrically isolating a test section of said transducer, wherein said transducer includes said at least a pair of transmission couplers and said receiving coupler.

43. The multiple component composition monitor of claim 42, in which said at least a pair of transmission couplers are spaced different distances from said receiving coupler.

44. The multiple component composition monitor of claim 42, in which said means for electrically isolating said test section comprises a substantially lossless waveguide material positioned in said test section and a lossy waveguide material positioned at each of two ends of said test section.

45. The multiple component composition monitor of claim 42, in which said enclosure includes a passage for flowing the composition therethrough.

46. A process for measuring the composition of a multiple component mixture, including the steps of:

(1) providing at least one electromagnetic wave transmitting coupler at a distance from a receiving coupler;

(2) transmitting elector magnetic waves into the mixture;

(3) generating an interference pattern of the electromagnetic waves in the mixture;

(4) receiving the transmitted electromagnetic waves at the receiving coupler;

(5) varying the frequency of the electromagnetic waves; and

(6) observing frequencies at which transmitted energy maxima or minima are received.

48. The process of claim 46 in which the electromagnetic waves are transmitted and received at a plurality of points around a test section enclosing the mixture.

49. The process of claim 46, additionally comprising, during the steps 2 through 6, the step of flowing the mixture past the transmission couplers and the receiving coupler.

50. The process of claim 46 additionally comprising the step of isolating the transmission and receiving couplers with a load on each side of the transmission couplers remote from the receiving coupler.

51. The process of claim 50, wherein the load is a reactive load.

52. The process of claim 50, wherein the load is a resistive load.

53. The process of claim 46 additionally comprising the step of determining flow rate of the multiple component mixture.

55. The process of claim 53, wherein steps 1 through 6 are carried out at a first location, and the flow rate determining step includes the steps of:

injecting a material into the multiple component mixture at a second location a known distance from the first location; and

determining the flow rate from travel time of the injected material from the second location to the first location.

57. A multiple component composition monitor for measuring ratios of component materials in a composition, comprising:

a transducer having an electrically conductive wall forming an enclosure for receiving the composition, said transducer including a test section having a first end, a second end, and an impedance section at each of said first and second ends, each of said impedance section having an impedance different from an impedance of said test section;

at least one electromagnetic wave transmission coupler;

positioned at said test section for creating electromagnetic waves in said enclosure;

an electromagnetic wave receiving coupler positioned at said test section for receiving said electromagnetic waves from said enclosure;

a circuit in which said transducer comprises at least one electrical path in said circuit;

means for producing a minimum or maximum output from said circuit by inducing an electromagnetic interference pattern; and

a density monitor connected to said transducer for measuring density of the composition, said minimum or maximum output and said density serving to characterize the ratios of the components materials in the composition.

58. The multiple component composition monitor of claim 57, in which said enclosure includes a passage adapted for flowing the composition therethrough.

59. The multiple component composition monitor of claim 58, including means coupled to said passage for determining a flow rate of the composition therethrough.

60. The multiple component composition monitor of claim 57, said monitor constituting a first monitor mounted at a first location on a pipe for flowing said composition therethrough, wherein a second multiple component composition monitor in accordance with claim 68 is mounted at a second location on said pipe at a distance from said first location, and wherein said first and second monitors in combination constitute means for determining a flow rate of the composition through said pipe, further including means connected to said first and second monitors for cross-correlating output signals from said multiple component composition monitor and said second composition monitor for determining a length of time taken for a portion of the composition to travel from said first location to said second location.

61. The multiple component composition monitor of claim 57, wherein a material injection port is mounted on said pipe at a known distance upstream from said multiple component composition monitor, wherein said composition monitor and material injection port in combination constitutes means for determining a flow rate of the composition through said pipe, said flow rate determining means further including means for measuring an amount of time taken for material injected by at said material injection port to travel to said multiple component composition monitor.