Nitrogen gas generator

• US 5,104,466 A
• Filed: 04/16/1991
• Issued: 04/14/1992
• Est. Priority Date: 04/16/1991
• Status: Expired due to Fees

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Original Assignee: Morton International Incorporated (Autoliv Incorporated)
• Inventors: Rink, Linda M., Allard, John E.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US07/685,777
• Time in Patent Office: 364 Days
• Field of Search: 149/21, 149/35, 149/61, 149/110, 149/112, 280/741
• US Class Current: 149/21
• CPC Class Codes: B60R 21/2644 using only solid reacting substances, e.g. pellets, powder
• CPC Class Codes: C06B 23/001 Fillers, gelling and thickening agents (e.g. fibres) , absorbents for nitroglycerine binders, plasticisers for propellants C06B45/10; crosslinking or curing agents C06B45/10
• CPC Class Codes: C06B 35/00 Compositions containing a metal azide
• CPC Class Codes: C06D 5/06 by reaction of two or more solids
• CPC Class Codes: F42B 3/04 for producing gas under pressure generators of inflation fluid especially adapted for vehicle air bags B60R21/26
• CPC Class Codes: Y10S 149/11 Particle size of a component
• CPC Class Codes: Y10S 149/112 Inorganic nitrogen-oxygen salt

Abstract

Particles of glass or silica type material are added to pellets of gas generating material as the gas generating material is being loaded into the combustion chamber of a gas generator or inflator. When the inflator is fired, the liquids and gases produced by the resulting rapid combustion process are cooled and condensed by the particles of glass or silica type material to a solid inside the combustion chamber near the exit ports or outlet holes thereof. This dramatically reduces the amount of combustible particle residue or particulates that leave the inflator.

Claims

1. A mixture for generating nitrogen gas consisting essentially of the following ingredients:

a. an alkali metal azide;

b. an oxidizing compound in proportion sufficient to react substantially completely with said azide with the liberation of nitrogen therefrom, with said azide and oxidizing compound being fabricated in the form of pellets each of which individually has a geometric configuration such that when aggregated in a mass there is contained between the pellets a free volume made up of the spaces therebetween; and

c. discrete particles of silica containing material which are substantially smaller than said pellets, said particles being disposed amongst said pellets and substantially filling the free volume therebetween.

2. A mixture as defined by claim 1 wherein said particles of silica containing material comprises particles of glass.

3. A mixture as defined by claim 2 wherein said particles of glass comprises glass beads.

4. A mixture as defined by claim 1 wherein the geometric configuration of the pellets is round and shallow and the particles of silica type material comprise particles of glass.

5. A mixture as defined by claim 4 wherein the pellets each have a diameter of about 0.25 inches (0.635 cm.) and a thickness of about 0.10 inches (0.254 cm.), and wherein

said particles of glass comprise one (1) millimeter glass beads.

6. An inflator for inflating an inflatable cushion of a vehicle occupant restraint system in response to a vehicle collision signal comprising:

housing means defining at least one discharge port for directing a gaseous flow from said housing means,

gas generating means disposed within said housing means and including a mixture comprised of the following ingredients;

a. an alkali metal azide,

b. an oxidizing compound in proportion sufficient to react substantially completely with said azide with the liberation of nitrogen therefrom, with said azide and said oxidizing compound being fabricated in the form of pellets each of which individually has a geometric configuration such that when aggregated in a mass there is contained between the pellets a free volume made up of the spaces therebetween, and

c. discrete particles of silica containing material which are substantially smaller than said pellets, said particles being disposed amongst said pellets and substantially filling the free volume therebetween, and

means operable to thermally initiate said gas generating means in response to the collision signal.

7. An inflator as defined by claim 6 wherein said particles of silica containing material comprises particles of glass.

8. An inflator as defined by claim 7 wherein said particles of glass comprise glass beads.

9. An inflator as defined by claim 6 wherein the geometric configuration of the pellets is round and shallow and the particles of silica type material comprise particles of glass.

10. An inflator as defined by claim 9 wherein the pellets each have a diameter of about 0.25 inches (0.635 cm.) and a thickness of about 0.10 inches (0.254 cm.) and said particles of glass comprise one (1) millimeter glass beads.