Vehicle systems for use in cosmetic compositions

• US 5,104,646 A
• Filed: 07/16/1990
• Issued: 04/14/1992
• Est. Priority Date: 08/07/1989
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Norton, Michael J., Bolich, Raymond E. Jr., Russell, Glen D.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Rucker, Susan S.
• Application Number:
  US07/551,119
• Time in Patent Office: 638 Days
• Field of Search: 424/70, 424/71, 424/78, 424/DIG. 1, 514/781, 8/405
• US Class Current: 424/70.13
• CPC Class Codes: A61K 8/73 Polysaccharides
• CPC Class Codes: A61K 8/731 Cellulose; Quaternized cellulose derivatives
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61K 8/895 containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
• CPC Class Codes: A61Q 5/06 Preparations for styling the hair, e.g. by temporary shaping or colouring

Abstract

Disclosed is a unique vehicle system which provides a desirable rheology to products formulated therewith, enhanced dispersion of actives therein, and improved deposition of actives therefrom. This vehicle system comprises a primary thickening agent which is a nonionic long chain alkylated water-soluble polymer, and a secondary thickening agent which is a water-soluble surfactant, dispersed in a compatible solvent. Optionally, a rheological aid, which is a chelating agent may be included in the vehicle system. Also, optionally, a distributing aid, which is a water-soluble polymer of either high molecular weight or strong ionic character may be included in the vehicle system. These vehicle systems are useful in cosmetic compositions which are used to deliver an active component to the hair or skin. The vehicle systems are particularly useful in hair care compositions, especially rinse-off hair conditioning compositions, because they effectively deliver the hair conditioning component to the hair without depositing a substantial amount of the vehicle material onto the hair.

Claims

1. A cosmetic composition comprising:

(a) from about 80% to about 100% of a vehicle system which comprises;

(A) from about 0.1% to about 10.0% by weight of the cosmetic composition of a hydrophobically modified nonionic water-soluble polymer which comprises a water-soluble polymer backbone and hydrophobic groups selected from the group consisting of C₈ -C₂₂ alkyl, aryl alkyl, alkyl aryl groups and mixtures thereof;

wherein the ratio of the hydrophilic portion to the hydrophobic portion of the polymer is from about 10;

1 to about 1000;

1; and

(B) from about 0.02% to about 0.3% by weight of the cosmetic composition of a water-soluble surfactant having a molecular weight less than about 20,000; and

(C) from about 65% to about 99% by weight of the cosmetic composition of a compatible solvent; and

(b) from 0% to about 20%, by weight, of an active cosmetic component;

wherein said cosmetic compositions comprise no more than about 1.0% total of water-soluble surfactant materials.

2. The composition of claim 1 wherein said hydrophobically modified nonionic water-soluble polymer comprises a nonionic cellulose ether having a sufficient degree of nonionic substitution, selected from the group consisting of methyl, hydroxyethyl, and hydroxypropyl, to cause it to be water-soluble and being further substituted with a long chain alkyl radical having 10 to 22 carbon atoms in an amount between about 0.2 weight percent and the amount which renders said cellulose ether less than 1% by weight soluble in water.

3. The composition of claim 2 wherein the vehicle system provides a rheology to the cosmetic composition that is characterized by a shear stress of from 0 to about 50 pascal over a shear rate range of from about 0.04 sec^-1 to about 25 sec^-1.

4. The composition of claim 3 wherein the nonionic cellulose ether comprises from about 0.2% to about 5.0% of the cosmetic composition.

5. The composition of claim 4 wherein the nonionic cellulose ether comprises the long-chain alkyl radical attached via an ether linkage.

6. The composition of claim 5 wherein the cellulose ether comprises a water-soluble hydroxypropyl cellulose substituted with a long-chain alkyl radical having 10 to 22 carbon atoms in an amount between about 0.2 weight percent and the amount which renders the hydroxypropyl cellulose less than 1% by weight soluble in water.

7. The composition of claim 6 wherein the nonionic cellulose ether comprises a water-soluble hydroxyethyl cellulose substituted with a long-chain alkyl radical having 10 to 22 carbon atoms in an amount between about 0.2 weight percent and the amount which renders the hydroxyethyl cellulose less than 1% by weight soluble in water.

8. The composition of claim 7 wherein the hydroxyethyl cellulose prior to substitution with the long chain alkyl group has a molecular weight of about 50,000 to 700,000.

9. The composition of claim 8 wherein the water-soluble hydroxyethyl cellulose is substituted with a long chain alkyl radical having about 16 carbon atoms in a n amount between about 0.40% to about 0.95%, by weight;

the hydroxyethyl molar substitution is from about 2.3 to about 3.7; and

the average molecular weight of the unsubstituted cellulose is from about 300,000 to about 700,000.

10. The composition of claim 3 which comprises from about 0.05% to about 0.3% of the water-soluble surfactant.

11. The composition of claim 10 wherein the water-soluble surfactant is selected from the group consisting of cetyl betaine, ammonium lauryl sulfate, ammonium laureth sulfate, cetyl trimethyl ammonium chloride, and mixtures thereof.

12. The composition of claim 3 which additionally comprises from about 0.3% to about 5.0% of a water-soluble polymeric material having a molecular weight greater than about 20,000.

13. The composition of claim 12 wherein the water-soluble polymeric material is selected from the group consisting of hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, polyethylene glycol, polyacrylamide, polyacrylic acid, polyvinyl alcohol, polyvinyl pyrrolidone, dextran, carboxymethyl cellulose, acacia plant exudate, ghatti plant exudate, tragacanth plant exudate, sodium alginate, propylene glycol alginate, sodium carrageenan, natural polysaccharides, and mixtures thereof.

14. The composition of claim 13 wherein the water-soluble polymeric material comprises a natural polysaccharide.

15. The composition of claim 14 wherein the natural polysaccharide is selected from the group consisting of guar gum, locust bean gum, xanthan gum, and mixtures thereof.

16. The composition of claim 3 which additionally comprises from about 0.05% to about 1.0% by weight of the composition of a chelating agent.

17. The composition of claim 16 wherein the chelating agent is selected from the group consisting of ethylene diaminetetracetic acid and salts thereof, nitriloacetic acid and salts thereof, hydroxyethylene diamine triacetic acid and salts thereof, diethylene triaminepenta-acetic acid and salts thereof, diethanolglycine and salts thereof, ethanol diglycine and salts thereof, citric acid and salts thereof, and phosphoric acid and salts thereof.

18. The composition of claim 12 which additionally comprises from about 0.05% to about 3% by weight of the composition of a chelating agent.

19. The composition of claim 18 wherein the chelating agent is selected from the group consisting of ethylene diaminetetracetic acid and salts thereof, nitriloacetic acid and salts thereof, hydroxyethylene diamine triacetic acid and salts thereof, diethylene triaminepenta-acetic acid and salts thereof, diethanolglycine and salts thereof, ethanol diglycine and salts thereof, citric acid and salts thereof, and phosphoric acid and salts thereof.

20. The composition of claim 12 wherein from bout 0.02% to about 2.5% of the water-soluble polymer is selected from the group consisting of water-soluble polymeric materials having a molecular weight greater than about 1,000,000, and water-soluble polymeric materials having strong ionic character.

21. The composition of claim 16 wherein from about 0.02% to about 2.5% of the water-soluble polymer is selected from the group consisting of water-soluble polymeric materials having a molecular weight greater than about 1,000,000, and water-soluble polymeric materials having strong ionic character.

22. The composition of claim 18 wherein from about 0.02% to about 2.5% of the water-soluble polymer is selected from the group consisting of water-soluble polymeric materials having a molecular weight greater than 1,000,000, and water-soluble polymeric materials having strong ionic character.

23. The cosmetic composition of claim 3 which is a hair care composition wherein said active component comprises an active hair care component.

24. The composition of claim 23 wherein the composition comprises no more than bout 1% of fatty alcohol materials.

25. The composition of claim 24 wherein the active hair care component is selected from the group consisting of conditioning agents, antidandruff aids, hair growth promoters, perfumes, dyes, pigments, hair holding polymers, and mixtures thereof.

26. The composition of claim 25 wherein the active hair care component is selected from the group consisting of a volatile silicone fluid having a viscosity at 25°

C. of less than about 10 centipoise, a non-volatile silicone fluid having a viscosity at 25°

C. of less than about 100,000 cP;

a silicone gum having a viscosity at 25°

C. greater than about 1,000,000 cP, and mixtures thereof.

27. The composition of claim 26 wherein the silicone gum is selected from the group consisting of polydimethylsiloxane gums and polyphenyl methyl siloxane gums.

28. The composition of claim 25 wherein the active hair care component comprises from about 0.01% to bout 10% of a rigid silicone polymer having a complex viscosity at 25°

C. of at least 2×

10⁵ poise.

29. The composition of claim 28 which additionally comprises a volatile carrier for the rigid silicone polymer.

30. A hair care composition according to claim 29 wherein the rigid silicone polymer is selected from the group consisting of organic substituted siloxane gums, silicone elastomers, filler reinforced polydimethyl siloxane gums, resin reinforced siloxanes and crosslinked siloxane polymers.

31. A hair care composition according to claim 30 wherein the volatile carrier is a cyclic silicone containing from about 3 to about 7 silicon atoms.

32. A hair care composition according to claim 31 wherein the rigid silicone polymer is a silicone elastomer and the sole volatile carrier is water.

33. A hair care composition according to claim 31 wherein the rigid silicone polymer is a filler reinforced polydimethyl siloxane gum.

34. A hair care composition according to claim 31 wherein the rigid silicone polymer is an organic substituted siloxane gum.

35. A hair care composition according to claim 31 wherein the rigid silicone polymer is a resin reinforced siloxane.

36. The composition of claim 25 wherein the active hair care component comprises from about 0.1% to bout 10.0% of a copolymer which has a vinyl polymeric backbone having grafted to it monovalent siloxane polymeric moieties, said copolymer comprising C monomers and components selected from the group consisting of A monomers, B monomers, and mixtures thereof, wherein:

A is at least one free radically polymerizable vinyl monomer, the amount by weight of A monomer, when used, being up to about 98% by weight of the total weight of all monomers in said copolymer;

B is at least one reinforcing monomer copolymerizable with Z, the amount by weight of B monomer, when used, being up to about 98% of the total weight of all monomers in said copolymer, said B monomer being selected from the group consisting of polar monomers and macromers; and

C is a polymeric monomer having a molecular weight of from about 1,000 to about 50,000 and the general formula

space="preserve" listing-type="equation">X(Y).sub.n Si(R).sub.3-m (Z).sub.m

wherein

X is a vinyl group copolymerizable with the A and B monomers

Y is a divalent linking group

R is a hydrogen, lower alkyl, aryl or alkoxy

Z is a monovalent siloxane polymeric moiety having a number average molecular weight of at least about 500, is essentially unreactive under copolymerization conditions, and is pendant from said vinyl polymeric backbone after polymerization

n is 0 or 1

m is an integer from 1 to 3

wherein C comprises from bout 0.01% to bout 50% of the copolymer.

37. The composition of claim 36 wherein the copolymer comprises from about 5% to about 98% A monomer, from about 0.1% to about 50% monomer, and from 0% to about 98% B monomer.

38. The composition of claim 25 wherein the active hair care component comprises a lipophilic free radically polymerizable vinyl monomer or a hydrophilic monomer which is copolymerizable with A, or a mixture thereof, and a silicone-containing macromer having a weight average molecular weight of from bout 1,000 to bout 50,000 based on polydimethylsiloxane selected from the group consisting of ##STR15## wherein m is 1, 2 or 3;

p is 0 or 1;

R" is alkyl or hydrogen;

q is an integer from 2 to 6;

s is an integer from 0 to 2;

X is ##STR16## R¹ is hydrogen or --COO;

R² is hydrogen, methyl or --C₂ COO;

Z is ##STR17## R⁴ is alkyl, alkoxy, alkylamino, aryl, or hydroxyl; and

r is an integer from about 5 to bout 700.

39. A hair care composition according to claim 38 wherein monomer A is selected from the group consisting of acrylic acid esters of C₁ -C₁₈ alcohols, methacrylic acid esters of C₁ -C₁₈ alcohols, styrene, vinyl acetate, vinyl chloride, vinylidene chloride, acrylonitrile, alpha-methylstyrene, t-butylstyrene, butadiene, cyclohexadiene, ethylene, propylene, vinyl toluene, polystyrene macromer, and mixtures thereof.

40. A hair care composition according to claim 39 wherein monomer B is selected from the group consisting of acrylic acid, methacrylic acid, N,N-dimethylacrylamide, dimethylaminoethyl methacrylate, quaternized dimethylaminoethyl methacrylate, methacrylonitrile, methacryloamide, maleic anhydride, half esters of maleic anhydride, itaconic acid, acrylamide, acrylate alcohols, hydroxyethyl methacrylate, diallyldimethyl ammonium chloride, vinyl pyrrolidone, vinyl ethers maleimides, acylactones, 2-ethyl-2-oxazoline, vinyl pyridine, vinyl imidazole, styrene sulfonate, and mixtures thereof.

41. A hair care composition according of claim 37 wherein monomer A is selected from the group consisting of N-butylmethacrylate, isobutylmethacrylate, 2-ethylhexyl methacrylate, t-butylacrylate, t-butylmethacrylate, methylmethacrylate, and mixtures thereof.

42. A hair care composition according to claim 41 wherein monomer B is selected from the group consisting of acrylic acid, N,N-dimethylacrylamide, dimethylaminoethyl methacrylate, quaternized dimethylaminoethyl methacrylate, vinyl pyrrolidone, and mixtures thereof.

43. A hair care composition according to claim 42 wherein monomer C has the formula ##STR18##

44. A hair care composition according to claim 43 wherein p =0 and q=3.

45. A hair care composition according to claim 44 wherein m is 1, r is about 250, R⁴ is alkyl, R₁ is hydrogen and R² is methyl.

46. A hair care composition according to claim 40 wherein the silicone-containing copolymer is selected from the group consisting of

acrylic acid/n-butylmethacrylate/polydimethylsiloxane macromer-20,000 mw (10/70/20);

N,N-dimethylacrylamide/isobutyl methacrylate/PDMS macromer-20,000 ms (20/60/20);

dimethylaminoethyl methacrylate/isobutyl methacrylate/2-ethylhexyl methacrylate/PDMS-20,000 mw (25/40/15/20);

dimethylaminoethyl methacrylate/isobutyl methacrylate/PDMS-20,000 mw (10/70/20);

quaternized dimethylaminoethyl methacrylate/isobutyl methacrylate/PDMS-20,000 mw (40/40/20);

acrylic acid/methyl methacrylate/PDMA-20,000 mw (40/40/20);

acrylic acid/isopropyl methacrylate/PDMS-20,000 mw (25/65/10);

N,N-dimethylacrylamide/methoxyethyl methacrylate/PDMS-20,000 mw (60/2515);

dimethylacrylamide/PDMS macromer-20,000 mw (80/20);

t-butylacrylate/t-butylmethacrylate/PDMS macromer-10,000 mw (56/24/20);

t-butylacrylate/PDMS macromer-10,000 mw (80/20);

t-butylacrylate/N,N-dimethylacrylamide/PDMS macromer-10,000 mw (70/10/20);

t-butylacrylate/acrylic acid/PDMS macromer-10,000 mw (75/5/20); and

mixtures thereof.

47. A hair care composition comprising:

(a) from about 80% to about 99.9%, by weight of the hair care composition, of a vehicle system which comprises;

(A) from about 0.2% to bout 5.0%, by weight of the hair care composition, of a nonionic cellulose ether having a hydroxyethyl molar substitution of from about 2.3% to about 3.7%, and being further substituted with a C₁₆ alkyl group at from about 0.40% is about 0.95%, by weight, wherein the unsubstituted hydroxyethyl cellulose has an average molecular weight of from about 300,000 to bout 700,000;

(B) from about 0.05% to about 0.3%, by weight of the hair care composition, of a water-soluble surfactant, having a molecular weight less than about 20,000, which is selected from the group consisting of cetyl betaine, ammonium lauryl sulfate, ammonium laureth sulfate, cetyl trimethyl ammonium chloride, and mixtures thereof;

(C) from about 0.05% to about 0.3%, of a chelating agent which is selected from the group consisting of ethylene diamine tetra acetic acid and salts thereof, citric acid and salts thereof, and phosphoric acid and salts thereof;

(D) from about 0.05% to about 1.0% of a distributing aid which is selected from the group consisting of xanthan gum and dextran having a molecular weight greater than about 1,000,000; and

(E) from about 65% to about 99% by weight of the hair care composition of a compatible solvent; and

(b) from about 0.1% to about 20%, by weight of the hair care composition, of an active hair care component;

wherein said hair care composition comprises no more than about 0.5% total of water-soluble surfactants;

no more than about 1% of fatty alcohol materials; and

wherein said hair care composition has a rheology that is characterized by a shear stress of from 0 to about 50 pascal over a shear rate range of from about 0.04 sec^-1 to about 25 sec^-1.

48. The composition of claim 47 wherein the active hair care component comprises a silicone-containing copolymer selected from the group consisting of

acrylic acid/n-butylmethacrylate/polydimethylsiloxane macromer-20,000 mw (10/70/20);

N,N-dimethylacrylamide/isobutyl methacrylate/PDMS macromer-20,000 mw (20/60/20));

dimethylaminoethyl methacrylate/isobutyl methacrylate/2l-ethylhexyl methacrylate/PDMS-20,000 mw (25/40/15/20);

dimethylaminoethyl methacrylate/isobutyl methacrylate/PDMS-20,000 mw (10/70/20);

quaternized dimethylaminoethyl methacrylate/isobutyl methacrylate/PDMS-20,000 mw (40/40/20);

acrylic acid/methyl methacrylate/PDMS-20,000 mw (40/40/20);

acrylic acid/isopropyl methacrylate/PDMS-20,000 mw (25/65/10);

N,N-dimethylacrylamide/methoxyethyl methacrylate/PDMS-20,000 mw (60/25/15);

dimethylacrylamide/PDMS macromer-20,000 mw (80/20);

t-butylacrylate/t-butylmethacrylate/PDMS macromer-10,000 mw (56/24/20);

t-butylacrylate/PDMS macromer-10,000 mw (80/20);

t-butylacrylate/N,N-dimethylacrylamide/PDMS macromer-10,000 mw (70/10/20);

t-butylacrylate/acrylic acid/PDMS macromer-10,000 mw (75/5/20); and

mixtures thereof.

49. The composition of claim 47 wherein the active hair care component comprises a silicone conditioning agent which is selected from the group consisting of a conditioning agent comprising, by weight of the hair care composition:

(a) from about 0.1% to about 2.5% of a polydimethylsiloxane gum;

(b) from about 0.02% to about 0.7% of fumed silica; and

(c) from about 0.4% to about 18% of a volatile carrier;

a conditioning agent comprising;

(a) a volatile silicone fluid having a viscosity at 25°

C. of less than about 10 centipoise;

(b) from about 0.5% to bout 2.0% of a silicone gum having a viscosity at 25°

C. of greater than about 1,000,000 centipoise;

at ratios of volatile fluid to gum of from bout 85;

15 to about 50;

50; and

conditioning agent comprising;

(a) a non-volatile silicone fluid having a viscosity at 25°

C. of less than about 100,000 centipoise;

(b) from about 0.5% to about 2.0% of a silicone gum having a viscosity at 25°

C. of greater than 1,000,000 centipoise;

at ratios of non-volatile fluid to gum of from about 60;

40 to about 40;

60.