Thermoplastic polymer composition

• US 5,104,938 A
• Filed: 03/02/1989
• Issued: 04/14/1992
• Est. Priority Date: 03/07/1988
• Status: Expired due to Term

• Current Assignee: JSR Corporation
• Original Assignee: Japan Synthetic Rubber Co., Ltd.
• Inventors: Miyachi, Takumi, Toyama, Yasuo
• Primary Examiner(s): Bleutge, John C.
• Assistant Examiner(s): Hamilton, III., Thomas
• Application Number:
  US07/317,841
• Time in Patent Office: 1,139 Days
• Field of Search: 525/92
• US Class Current: 525/92.00C
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 53/025 modified

Abstract

A thermoplastic polymer composition consisting essentially of:

(a) at least one member selected from the group consisting of a block copolymer consisting of a polymer block comprising at least 60% by weight of an alkenyl aromatic compound and a polymer block comprising at least 60% by weight of a conjugated diene compound and a hydrogenated product of said copolymer;

(b) a thermoplastic polyurethane elastomer and

(c) at least one member selected from the group consisting of the following (c-1) and (c-2) components:

(c-1): a copolymer of an alkenyl aromatic compound with at least one compound selected from the group consisting of an unsaturated carboxylic acid and its derivative,

(c-2): a modified (co)polymer obtained by reacting an isocyanate with a (co)polymer of at least one compound selected from the group consisting of an alkenyl aromatic compound and a conjugated diene compound; or a hydrogenated product of the modified (co)polymer or a mixture of the isocyanate-modified (co)polymer with the hydrogenated product,

wherein the (a)/(b) weight ratio is 2/98-98/2 and the proportion of the (c) component is 1-100 parts by weight per 100 parts by weight of a total of the (a) and (b) components. The above composition is excellent in compatibility between the (a) component and the (b) component, and hence, has excellent heat resistance, mechanical strengths and wear resistance.

Claims

1. A thermoplastic polymer composition consisting essentially of:

(a) at least one member selected from the group consisting of a block copolymer consisting of a polymer block comprising at least 60% by weight of an alkenyl aromatic compound and a polymer block comprising at least 60% by weight of a conjugated diene compound and a hydrogenated product of said copolymer;

(b) a thermoplastic polyurethane elastomer and

(c) at least one member selected from the group consisting of the following (c-1) and (c-2) components;

(c-1);

a copolymer of an alkenyl aromatic compound with at least one compound selected from the group consisting of an unsaturated carboxylic acid and its derivative,

(c-2);

a modified (co)polymer obtained by reacting an isocyanate with a (co)polymer of at least one compound selected from the group consisting of an alkenyl aromatic compound and a conjugated diene compound;

or a hydrogenated product of the modified (co)polymer or a mixture of the isocyanate-modified (co)polymer with the hydrogenated product,

wherein the (a)/(b) weight ratio is 2/98-98/2 and the proportion of the (c) component is 1-100 parts by weight per 100 parts by weight of a total of the (a) and (b) components.

2. The thermoplastic polymer composition according to claim 1, wherein the (a) component block copolymer is a linear, branched or radial block copolymer comprising 5-95% by weight of an alkenyl aromatic compound.

3. The thermoplastic polymer composition according to claim 2, wherein the (a) component block copolymer comprises 10-90% by weight of an alkenyl aromatic compound.

4. The thermoplastic polymer composition according to claim 1, wherein the (a) component block copolymer is a block copolymer represented by one of the following formulas:

space="preserve" listing-type="equation">(A--B).sub.n, (A--B).sub.n A and (A--B).sub.n X

wherein A represents a polymer block comprising at least 60% by weight of an alkenyl aromatic compound, B represents a polymer block comprising at least 60% by weight of a conjugated diene compound, X represents a coupling agent residue and n is an integer of 1 or more.

5. The thermoplastic polymer composition according to claim 1, wherein the (a) component block copolymer consists of a block of a homopolymer of an alkenyl aromatic compound or a block of a copolymer of an alkenyl aromatic compound with a conjugated diene compound in which the proportion of the alkenyl aromatic compound is at least 80% by weight, and a block of a homopolymer of a conjugated diene compound or a block of a copolymer of a conjugated diene compound and an alkenyl aromatic compound in which the proportion of the conjugated diene compound is at least 80% by weight.

6. The thermoplastic polymer composition according to claim 5, wherein the alkenyl aromatic compound of the (a) component block copolymer is at least one member selected from the group consisting of styrene, α

-methylstyrene, p-methylstyrene, vinylxylene, monochlorostyrene, fluorostyrene, dichlorostyrene, monobromostyrene, dibromostyrene, fluorostyrene, p-t-butylstyrene, ethylstyrene and vinylnaphthalene.

7. The thermoplastic polymer composition according to claim 5, wherein the conjugated diene compound of the (a) component block copolymer is at least one member selected from the group consisting of 1,3-butadiene, 2-methyl-1,3-butadiene, 2,3-dimethyl-1,3-butadiene, 2-neopentyl-1,3-butadiene, 2-chloro-1,3-butadiene, 2-cyano-1,3-butadiene, straight chain conjugated pentadiene, substituted conjugated pentadienes, straight chain conjugated hexadiene and substituted conjugated hexadienes.

8. The thermoplastic polymer composition according to claim 1, wherein the (a) component block copolymer has a weight average molecular weight of 10,000-500,000.

9. The thermoplastic polymer composition according to claim 1, wherein the hydrogenated product of the block copolymer as the (a) component is a styrene-ethylene-propylene block copolymer or a styrene-ethylene-butylene block copolymer.

10. The thermoplastic polymer composition according to claim 1, wherein the (b) component thermoplastic polyurethane elastomer is one prepared by subjecting a long chain polyol, a short chain glycol and a diisocyanate to addition polymerization.

11. The thermoplastic polymer composition according to claim 10, wherein the long chain polyol is poly-(1,4-butylene adipate), poly(1,6-hexane adipate), polycarpolatone, polyethylene glycol, polypropylene glycol or polyoxytetramethylene glycol.

12. The thermoplastic polymer composition according to claim 10, wherein the short chain glycol is ethylene glycol, 1,4-butanediol or 1,4-hexanediol.

13. The thermoplastic polymer composition according to claim 10, wherein the diisocyanate is tolylene diisocyanate, 4,4'"'"'-di-phenylmethane diisocyanate, hexamethylene diisocyanate or isophorone diisocyanate.

14. The thermoplastic polymer composition according to claim 1, wherein the (c) component is the (c-1) component copolymer.

15. The thermoplastic polymer composition according to claim 14, wherein the (c-1) component copolymer is a copolymer of an alkenyl aromatic compound selected from the group consisting of styrene, α

-methylstyrene, p-methylstyrene, vinylxylene, monochlorostyrene, dichlorostyrene, monobromostyrene, dibromostyrene, fluorostyrene, p-t-butylstyrene, ethylstyrene and vinylnaphthalene, with an unsaturated carboxylic acid selected from the group consisting of maleic acid, fumaric acid, itaconic acid, acrylic acid, crotonic acid and cis-4-cyclohexene-1,2-dicarboxylic acid or anhydride or imide of the acid.

16. The thermoplastic polymer composition according to claim 15, wherein the (c-1) component is a copolymer of styrene with maleic anhydride.

17. The thermoplastic polymer composition according to claim 1, wherein the (c) component is the (c-2) component modified (co)polymer, its hydrogenated product or a mixture of the two.

18. The thermoplastic polymer composition according to claim 17, wherein the modified (co)polymer is an isocyanate-modified homo- or co-polymer obtained by homopolymerizing a conjugated diene compound or an alkenyl aromatic compound or random- or block-copolymerizing a conjugated diene and an alkenyl aromatic compound with a lithium type initiator and then reacting the homopolymer or copolymer obtained with an isocyanate at the terminals.

19. The thermoplastic polymer composition according to claim 18, wherein the conjugated diene compound is a member selected from the group consisting of 1,3-butadiene, 2-methyl-1,3-butadiene, 2,3-dimethyl-1,3-butadiene, 2-neopentyl-1,3-butadiene, 2-chloro-1,3-butadiene and 2-cyanopentyl-1,3-butadiene, the alkenyl aromatic compound is selected from the group consisting of styrene, u-methylstyrene, p-methylstyrene, vinylxylene, monochlorostyrene, dichlorostyrene, monobromostyrene, dibromostyrene, fluorostyrene, p-t-butylstyrene, ethylstyrene and vinylnaphthalene, and the isocyanate is selected from the group consisting of aromatic diisocyanates, aromatic triisocyanates and aliphatic isocyanates.

20. The thermoplastic polymer composition according to claim 19, wherein the conjugated diene compound is 1,3-butadiene or 2-methyl-1,3-butadiene, the alkenyl aromatic compound is styrene and the isocyanate is an aromatic diisocyanate selected form the group consisting of 2,4-tolylene diisocyanate, diphenylmethane diisocyanate and naphthalene diisocyanate.

21. The thermoplastic polymer composition according to claim 1, wherein the (a) component/the (b) component weight ratio is 5/95-95/5 and the proportion of the (c) component is 2-80 parts by weight per 100 parts by weight of a total of the (a) component and the (b) component.

22. The thermoplastic polymer composition according to claim 1, which further contains at least one additive selected from the group consisting of fillers, reinforcing agents, plasticizers, antioxidants, ultraviolet absorbers, antistatic agents, flame retardants, lubricants, foaming agents, coloring agents, pigments, nucleating agents, crosslinking agents, crosslinking coagents, rubbery polymers and thermoplastic resins.