Olefin polymerization catalyst

• US 5,106,806 A
• Filed: 10/18/1990
• Issued: 04/21/1992
• Est. Priority Date: 10/18/1990
• Status: Expired due to Term

• Current Assignee: Union Carbide Chemicals & Plastics Technology Corporation (Dow, Inc.)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Job, Robert C.
• Primary Examiner(s): Garvin, Patrick P.
• Assistant Examiner(s): PEEBLES, BRENT
• Application Number:
  US07/599,610
• Time in Patent Office: 551 Days
• Field of Search: 502/111, 502/121, 502/124, 502/125, 502/126, 502/127, 502/133, 502/123
• US Class Current: 502/111
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 110/06 Propene
• CPC Class Codes: C08F 2500/18 Bulk density
• CPC Class Codes: C08F 4/651 Pretreating with non-metals or metal-free compounds
• CPC Class Codes: C08F 4/6548 magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546
• CPC Class Codes: C08F 4/6574 and magnesium or compounds thereof

Abstract

Improved lower α-olefin polymerization catalysts are produced from an organoaluminum cocatalyst, a selectivity control agent and a specified magnesium-containing, titanium-containing, halide-containing procatalyst. The procatalyst is produced from an electron donor, tetravalent titanium halide and a complex alkoxide compound formed from magnesium alkoxide, titanium alkoxide and a phenolic compound. The catalyst is utilized produce poly-α-olefin in good yield, which polymer is characterized by a relatively low xylene solubles content and a relatively high bulk density.

Claims

1. An olefin polymerization catalyst component precursor consisting of a solution of a complex alkoxide compound of the formula

View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27)

2. The component precursor of claim 1 of the formula

3. The component precursor of claim 2 wherein each OR is ethoxide.

4. The precursor of claim 3 wherein each X is o-cresylate.

5. An olefin polymerization catalyst component which consists essentially of the product of contacting the catalyst precursor of claim 1 with a tetravalent titanium halide and an electron donor.

6. The component of claim 5 wherein the tetravalent titanium halide is a titanium tetrahalide.

7. The component of claim 6 wherein the electron donor is an ester of an aromatic monocarboxylic or dicarboxylic acid.

8. The component of claim 7 wherein the titanium tetrahalide is titanium tetrachloride.

9. The component of claim 8 wherein the electron donor is an alkyl ester of an aromatic monocarboxylic acid.

10. The component of claim 9 wherein the ester is ethyl benzoate.

11. The component of claim 8 wherein the electron donor is an alkyl ester of an aromatic dicarboxylic acid.

12. The component of claim 11 wherein the ester is diisobutyl phthalate.

13. An olefin polymerization catalyst obtained by contacting the catalyst component of claim 4 with an organoaluminum cocatalyst and a selectivity control agent.

14. The catalyst of claim 13 wherein the cocatalyst is halide-free.

15. The catalyst of claim 14 wherein the cocatalyst is a trialkylaluminum.

16. The catalyst of claim 15 wherein the selectivity control agent is an ester of an aromatic monocarboxylic or dicarboxylic acid or an organosilane of the formula

17. The catalyst of claim 16 wherein the selectivity control agent is an ester.

18. The catalyst of claim 17 wherein the cocatalyst is triethylaluminum.

19. The catalyst of claim 18 wherein the ester is ethyl p-ethoxybenzoate.

20. The catalyst of claim 18 wherein the ester is diisobutyl phthalate.

21. The catalyst of claim 16 wherein the selectivity control agent is an organosilane.

22. The catalyst of claim 21 wherein R is alkyl and R, is methyl.

23. The catalyst of claim 22 wherein the cocatalyst is triethylaluminum.

24. The catalyst of claim 23 wherein the organosilane is diisobutyldimethoxysilane.

25. The catalyst of claim 24 wherein the organosilane is propyltrimethoxysilane.

26. The catalyst of claim 24 wherein the organosilane is cyclohexylmethyldimethoxysilane.

27. The process of producing the catalyst component precursor of claim 1 by contacting magnesium dialkoxide and titanium tetraalkoxide in the presence of a phenolic compound selected from phenol or activating group-substituted phenol wherein the activating group is alkyl, halo, or dialkylamino at a temperature from about 50°

C. to about 110°

C. and a pressure sufficient to maintain the reaction mixture in a non-gaseous state in inert diluent.