Method for the destruction of toxic waste products and a plasma chemical reactor

• US 5,108,718 A
• Filed: 07/14/1989
• Issued: 04/28/1992
• Est. Priority Date: 08/11/1988
• Status: Expired due to Fees

• Current Assignee: Veb Chemieanlagenbaukombinat Leipzig/Grimma
• Original Assignee: Veb Chemieanlagenbaukombinat Leipzig/Grimma
• Inventors: Dummersdorf, Hans-Ulrich, Jahn, Wolfgang, Noack, Werner, Hebecker, Dietrich, Dummersdorf, Heinz, Kunze, Robert, Merten, Hartmut, Wohllebe, Gert
• Primary Examiner(s): Stoll, Robert L.
• Assistant Examiner(s): Bhat, N.
• Application Number:
  US07/380,169
• Time in Patent Office: 1,019 Days
• Field of Search: 422/186.23, 110/250, 110/346, 110/238, 110/247, 204/169
• US Class Current: 422/186.23
• CPC Class Codes: B01J 19/088 giving rise to electric discharges for heating purposes H05B7/00; for the production of ozone C01B13/11, H01T19/00
• CPC Class Codes: B01J 2219/0894 Processes carried out in the presence of a plasma
• CPC Class Codes: F23G 2204/201 Plasma
• CPC Class Codes: F23G 2209/142 Halogen gases, e.g. silane
• CPC Class Codes: F23G 5/085 High-temperature heating means, e.g. plasma, for partly melting the waste
• CPC Class Codes: F23G 7/00 Incinerators or other apparatus for consuming industrial waste, e.g. chemicals incinerator closets A47K11/02; oxidation of sludge C02F11/06; burners in general, burner details F23D; incinerating radioactive waste G21F9/00
• CPC Class Codes: Y02C 20/30 of perfluorocarbons [PFC], hydrofluorocarbons [HFC] or sulfur hexafluoride [SF6]

Abstract

Toxic wastes are destroyed by contact thereof with a steam plasma jet and immediately thereafter with an oxidizing medium followed by washing of the resultant gaseous product with an alkaline medium. An apparatus for carrying out this method is in the form of a tubular assembly adapted to be received on a plasmatron in axial alignment therewith.

Claims

1. Method for the destruction of toxic wastes, comprising contacting toxic wastes containing at least one member selected from the group consisting of fluorinated and chlorinated hydrocarbons (1) with a stream plasma jet for a period of at least 10^-3 second and (2) immediately thereafter with an oxidizing medium at a temperature no higher than 1500°

C. and for a period of at least 10^-2 second thereby to produce a gaseous product and (3) contacting the gaseous product with an alkaline wash medium.

2. Method according to claim 1, in which the wastes are gaseous, liquid or pasty and contacted in those forms with the steam plasma jet.

3. Method according to claim 1, in which the wastes are solid and further comprising, prior to contacting the wastes with the steam plasma jet, grinding the wastes to a particle size of under 300 μ

m and entraining the particles in gas, the contacting with the steam plasma jet being effected by conducting the entrained particles into the jet.

4. Method according to claim 1, in which the oxidizing medium is a gas mixture containing free oxygen.

5. Method according to claim 4, in which the oxidizing medium is air.

6. Method according to claim 1, in which the step of contacting the gaseous product with an alkaline wash medium comprises prewashing the gaseous product in a pre-absorber with alkaline solution and then rewashing the prewashed product with alkaline solution in a packed column where cooling to ambient temperature takes place.

7. Plasma-chemical reactor for the destruction of toxic wastes, said reactor being adapted to be connected to a plasmatron in axial alignment therewith, comprising a tubular assembly having at one end a flange adapted to be mounted on a plasmatron, an axial channel formed through the flange for receiving a plasma jet from the plasmatron, radial channels formed in the flange in communication with the axial channel for conducting toxic wastes into the axial channel, an expansion ring received on a face of the flange opposite a face of the flange adapted to be received on the plasmatron, the ring having an axial bore in the form of an inverted frustocone in axial alignment with the axial flange channel and with its smaller mouth resting on the flange, a tubular member of high temperature resistant ceramic of poor thermal conductivity having a first end resting on the flange with the expansion ring loosely and coaxially received in the tubular member, a cylindrical outer jacket having a first end received on the flange with the tubular member coaxially received in the jacket, the jacket being shorter than the tubular member, an annular space being formed between the tubular member and the jacket, radial spacer pins extending from the jacket into the annular space, but not gripping the tubular member, for centering the tubular member without imposing strain thereupon, the other end of the jacket having a flange formed thereon, received on the jacket flange in axial alignment therewith a double-walled tubular member having a first end with a flange formed thereon which is received on the jacket flange and having an inner wall of the same internal diameter as the jacket, the tubular member extending a relatively small distance into the double-walled tubular member, and respective conduit means communicating with said annular space and with an annular space between the walls of the double-walled tubular member.

8. Plasma-chemical reactor according to claim 7, in which an annular groove is formed in the expansion ring and comprising an additional tubular member of high temperature resistant ceramic of poor thermal conductivity, the additional tubular member being coaxially received in the expansion ring with the lower end thereof resting on the annular groove and being of smaller diameter and no more than half the length of the other tubular member of high temperature resistant ceramic of poor thermal conductivity.