Electrolyte compositions and methods

• US 5,108,856 A
• Filed: 04/12/1990
• Issued: 04/28/1992
• Est. Priority Date: 03/13/1989
• Status: Expired due to Fees

• Current Assignee: Enzon Labs Inc.
• Original Assignee: Westinghouse Electric Corporation (Paramount Global (f/k/a ViacomCBS Inc.))
• Inventors: Shuster, Nicholas
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): MARQUIS, STEVEN
• Application Number:
  US07/512,010
• Time in Patent Office: 747 Days
• Field of Search: 429/206, 429/195, 429/198
• US Class Current: 429/347
• CPC Class Codes: H01M 4/628 Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
• CPC Class Codes: H01M 6/04 Cells with aqueous electrolyte
• CPC Class Codes: H01M 6/26 Cells without oxidising active material, e.g. Volta cells

Abstract

A surfactant is present in an aqeuous alkaline electrolyte of a consumable metal anode electrochemical cell in a concentration sufficient to substantially reduce both the surface tension of the electrolyte and the rate of the parasitic corrosion reaction occurring between the electrolyte and the anode. The surfactant is useful in minimizing the harmful side effects, such as increased heat generation, anode consumption without producing useful energy and increased hydrogen gas production rates, such as are associated with the parasitic corrosion reaction experienced in such electrochemical cells.

Claims

1. An electrochemical cell, comprising:

a consumable metal anode which comprises a reactive metal selected from the group consisting of alkali metals and aluminum;

a cathode spaced from said anode; and

,

an electrolyte in contact with said anode and said cathode and defining an interface with said anode during operation of the cell, said electrolyte including a surfactant containing at least 8 carbon atoms and having a structure characterized by a hydrophilic polar group and a hydrophobic tail in a concentration sufficient to substantially reduce both the surface tension of said electrolyte and the rate of the parasitic corrosion reaction occurring between said electrolyte and said anode metal at said interface.

2. The electrochemical cell of claim 1 wherein said electrolyte comprises an aqueous alkaline electrolyte.

3. The electrochemical cell of claim 2 wherein said surfactant comprises an anionic surfactant.

4. The electrochemical cell of claim 3 wherein the concentration of said surfactant in said electrolyte is at least about 50 ppm.

5. The electrochemical cell of claim 4 wherein the concentration of said surfactant in said electrolyte is about 100-200 ppm.

6. The electrochemical cell of claim 1 wherein said surfactant is selected from the group consisting of anionic surfactants, nonionic surfactants and cationic surfactants.

7. The electrochemical cell of claim 1 wherein the molecules of said surfactant comprise carboxylate groups.

8. The electrochemical cell of claim 1 wherein the molecules of said surfactant comprise sulfonate groups.

9. The electrochemical cell of claim 1 wherein said surfactant comprises a fluorochemical surfactant.

10. The electrochemical of claim 9 wherein said fluorochemical surfactant comprises a potassium fluorinated alkyl carboxylate.

11. The electrochemical cell of claim 1 wherein said reactive metal comprises an alkali metal.

12. The electrochemical cell of claim 11 wherein said alkali metal comprises lithium.

13. The electrochemical cell of claim 1 wherein said anode comprises aluminum.

14. The electrochemical cell of claim 1 wherein said anode is adhered to a conductive metal substrate.

15. An electrochemical cell, comprising:

a reactive metal anode which comprises a metal selected from the group consisting of alkali metals and aluminum;

a cathode spaced from said anode; and

an aqueous alkaline electrolyte in contact with said anode and said cathode and defining an interface with said anode during operation of said cell, said electrolyte including an anionic surfactant containing at least 8 carbon atoms and having a structure characterized by a hydrophilic polar group and a hydrophobic tail in a concentration sufficient to substantially reduce both the surface tension of said electrolyte and the rate of the parasitic corrosion reaction occurring between said electrolyte and said anode metal at said interface.

16. The electrochemical cell of claim 15 wherein the molecules of said anionic surfactant comprise carboxylate groups.

17. The electrochemical cell of claim 15 wherein the molecules of said anionic surfactant comprise sulfonate groups.

18. The electrochemical cell of claim 15 wherein said anionic surfactant comprises a fluorochemical surfactant.

19. The electrochemical cell of claim 18 wherein said fluorochemical surfactant comprises a potassium fluorinated alkyl carboxylate.

20. The electrochemical cell of claim 15 wherein said reactive metal comprises an alkali metal.

21. The electrochemical cell of claim 20 wherein said alkali metal comprises lithium.

22. The electrochemical cell of claim 15 wherein said anode comprises aluminum.

23. The electrochemical cell of claim 15 wherein said anode is adhered to a conductive metal substrate.

24. A method of reducing parasitic consumption of a consumable metal anode which comprises a reactive metal selected from the group consisting of alkali metals and aluminum in an electrochemical cell having an aqueous electrolyte, comprising adding a surfactant containing at least 8 carbon atoms and having a structure characterized by a hydrophilic polar group and a hydrophobic tail to the aqueous electrolyte in a concentration sufficient to substantially reduce the surface tension of said electrolyte.

25. The method of claim 24 wherein said surfactant is selected from the group consisting of anionic surfactants, nonionic surfactants and cationic surfactants.

26. The method of claim 25 wherein said surfactant comprises an anionic surfactant.

27. The method of claim 26 wherein the concentration of said surfactant in said electrolyte is at least about 50 ppm.

28. The method of claim 27 wherein the concentration of said surfactant in said electrolyte is about 100-200 ppm.

29. The method of claim 24 wherein the molecules of said surfactant comprise carboxylate groups.

30. The method of claim 24 wherein the molecules of said surfactant comprise sulfonate groups.

31. The method of claim 24 wherein said surfactant comprises a fluorochemical surfactant.

32. The method of claim 31 wherein said fluorochemical surfactant comprises a potassium fluorinated alkyl carboxylate.

33. The method of claim 24 wherein said reactive metal comprises an alkali metal.

34. The method of claim 33 wherein said alkali metal comprises lithium.

35. The method of claim 24 wherein said anode comprises aluminum.

36. The method of claim 24 wherein said anode is adhered to a conductive metal substrate.

37. A method of providing electrical energy from an electrochemical cells, comprising the steps of:

supplying an aqueous alkaline electrolyte to an electrochemical reaction zone defined between a cathode and a spaced consumable metal anode of said cell wherein said anode comprises a reactive metal selected from the group consisting of alkali metals and aluminum, said electrolyte including a surfactant containing at least 8 carbon atoms and having a structure characterized by a hydrophilic polar group and a hydrophobic tail in a concentration sufficient to substantially reduce both the surface tension of said electrolyte and the rate of the parasitic corrosion reaction occurring between said electrolyte and said anode metal.

38. The method of claim 37 wherein said surfactant is selected from the group consisting of anionic surfactants, nonionic surfactants and cationic surfactants.

39. The method of claim 38 wherein said surfactant comprises an anionic surfactant.

40. The method of claim 39 wherein the concentration of said surfactant in said electrolyte is at least about 50 ppm.

41. The method of claim 40 wherein the concentration of said surfactant in said electrolyte is about 100-200 ppm.

42. The method of claim 37 wherein the molecules of said surfactant comprise carboxylate groups.

43. The method of claim 37 wherein the molecules of said surfactant comprise sulfonate groups.

44. The method of claim 37 wherein said surfactant comprises a fluorochemical surfactant.

45. The method of claim 44 wherein said fluorochemical surfactant comprises a potassium fluorinated alkyl carboxylate.

46. The method of claim 37 wherein said reactive metal comprises an alkali metal.

47. The method of claim 46 wherein said alkali metal comprises lithium.

48. The method of claim 37 wherein said anode comprises aluminum.

49. The method of claim 37 wherein said anode is adhered to a conductive metal substrate.