Films using blends of polypropylene and polyisobutylene

• US 5,110,642 A
• Filed: 04/08/1991
• Issued: 05/05/1992
• Est. Priority Date: 11/29/1985
• Status: Expired due to Term

• Current Assignee: Pechiney Plastic Packaging Incorporated (Rio Tinto Limited)
• Original Assignee: American National Can Company (Ball Corporation)
• Inventors: Genske, Roger P.
• Primary Examiner(s): BUFFALOW, EDITH
• Application Number:
  US07/681,752
• Time in Patent Office: 393 Days
• Field of Search: 428/461, 428/516, 428/518, 428/35.3, 428/475.8, 428/35.8
• US Class Current: 428/35.8
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 2205/03 containing three or more polymers in a blend
• CPC Class Codes: C08L 23/0861 Saponified vinylacetate
• CPC Class Codes: C08L 23/12 Polypropene
• CPC Class Codes: C08L 23/142 at least partially crystalline copolymers of propene with other olefins
• CPC Class Codes: C08L 23/22 Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
• CPC Class Codes: C08L 2310/00 Masterbatches
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: Y10T 428/1338 Elemental metal containing
• CPC Class Codes: Y10T 428/1355 Elemental metal containing [e.g., substrate, foil, film, coating, etc.]
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31743 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/3192 Next to vinyl or vinylidene chloride polymer

Abstract

This invention teaches using blends of polyisobutylene and polypropylene copolymer in the formation of single layer films and multiple layer sheet materials. The films and sheet materials are useful as flexible packaging materials. The multiple layer sheet materials may be entirely polymeric or may include layers having non-polymeric components, such as metal. The blends of polyisobutylene and polypropylene copolymer unexpectedly have the capability of being extruded through a slot die to form a film having a functionally useful mixture of its components. Thus the invention further includes methods of forming film-like layers of the blends of polyisobutylene and polypropylene copolymer.

Claims

1. A multiple layer sheet material, comprising:

(a) a first polypropylene-based layer having two opposing surfaces, said first layer being a blend of 35% to 90% by weight polypropylene copolymer and conversely 65% to 10% by weight polyisobutylene, said polypropylene copolymer comprising 70 to 98 mole percent propylene moieties and conversely 30 to 2 mole percent ethylene moieties, the overall composition of said blend comprising at least about 1.8 mole percent ethylene; and

(b) a second layer of a metal foil affixed on one said surface of said first layer.

2. multiple layer sheet material as in claim 1 wherein said blend in said first layer comprises 60% to 80% by weight polypropylene copolymer and 40% to 20% by weight polyisobutylene.

3. A multiple layer sheet material as in claim 1 wherein said polypropylene copolymer in said first layer comprises 92 to 98 mole percent propylene moieties and conversely 2 to 8 mole percent ethylene moieties.

4. A multiple layer sheet material as in claim 2 wherein said polypropylene copolymer in said first layer comprises 92 to 98 mole percent propylene moieties and conversely 2 to 8 mole percent ethylene moieties.

5. A multiple layer sheet material as in claim 1 wherein said first layer is adhered to said second layer by a polymeric adhesive, said adhesive being between said first and second layers.

6. A multiple layer sheet material as in claim 2 wherein said first layer is adhered to said second layer by a polymeric adhesive, said adhesive being between said first and second layers.

7. A multiple layer sheet material as in claim 5 wherein said second layer has two opposing surfaces, said polymeric adhesive being on one said surface and adhering said one surface to said first layer, and wherein an abuse resistant layer is adhered to the other said surface of said second layer of metal foil by an adhesive layer.

8. A multiple layer sheet material as in claim 7 wherein said abuse resistant layer is biaxially oriented nylon.

9. A multiple layer sheet material as in claim 8 wherein said blend in said first layer comprises 60% to 80% by weight polypropylene copolymer and 40% to 20% by weight polyisobutylene.

10. A multiple layer sheet material as in claim 8 wherein said polypropylene copolymer in said first layer comprises 92 to 98 mole percent propylene moieties and conversely 2 to 8 mole percent ethylene moieties.

11. A multiple layer sheet material as in claim 9 wherein said polypropylene copolymer in said first layer comprises 92 to 98 mole percent propylene moieties and conversely 2 to 8 mole percent ethylene moieties.

12. A multiple layer sheet material as in claim 1 wherein said first layer is adhered to said second layer by a layer of polypropylene copolymer therebetween.

13. A multiple layer sheet material as in claim 12 and including a primer between said second layer and said polypropylene copolymer layer, said primer comprising carboxy moieties.

14. A multiple layer sheet material as in claim 12 and wherein said second layer has two opposing surfaces, said polypropylene copolymer layer being on one said surface and adhering said one surface to said first layer, and wherein an abuse resistant layer is adhered to the other said surface of said second layer of metal foil.

15. A multiple layer sheet material as in claim 13 wherein said second layer has two opposing surfaces, said polypropylene copolymer layer being on one said surface and adhering said one surface to said first layer, and wherein an abuse resistant layer is adhered to the other said surface of said second layer of metal foil.

16. A multiple layer sheet material as in claim 14 wherein said abuse resistant layer is biaxially oreinted nylon.

17. A multiple layer sheet material as in claim 15 wherein said abuse resistant layer is biaxially oreinted nylon.

18. A multiple layer sheet material as in claim 12 wherein said layer of polypropylene copolymer includes carboxy moieties.

19. A package made from sheet material of claim 1.

20. A package made from sheet material of claim 4.

21. A package made from sheet material of claim 5.

22. A package made from sheet material of claim 6.

23. A package made from sheet material of claim 7.

24. A package made from sheet material of claim 11.

25. A package made from sheet material of claim 12.

26. A package made from sheet material of claim 13.

27. A package made from sheet material of claim 15.

28. A package made from sheet material of claim 18.