Coated glazing material

• US 5,110,662 A
• Filed: 12/28/1989
• Issued: 05/05/1992
• Est. Priority Date: 01/05/1989
• Status: Expired due to Term

• Current Assignee: Glaverbel
• Original Assignee: Glaverbel
• Inventors: Hoyois, Jean-Claude, Depauw, Jean-Michel
• Primary Examiner(s): HERBERT JR, THOMAS
• Application Number:
  US07/458,386
• Time in Patent Office: 859 Days
• Field of Search: 428/469, 428/216, 428/336, 428/337, 428/192, 428/209, 428/343, 427/271, 204/192.27, 204/192.26
• US Class Current: 428/192
• CPC Class Codes: B60J 1/002 with means for clear vision, e.g. anti-frost or defog panes, rain shields window heating in H05B3/84, H05B3/86
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3663 specially adapted for use as mirrors
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: Y10T 428/24777 Edge feature
• CPC Class Codes: Y10T 428/24917 including metal layer
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/266 of base or substrate
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer

Abstract

A substrate of glazing material carries a multi-layer coating which comprises a reflective layer of silver sandwiched between a transparent undercoat and a transparent overcoat. The undercoat for the silver layer comprises at least one layer of a metal oxide selected from tin oxide, titanium dioxide, aluminium oxide, bismuth oxide and a mixture of two or more thereof, over which is deposited a layer of zinc oxide having a thickness not greater than 15 nm. The overcoat for the silver layer comprises a layer of an oxide of a sacrificial metal selected from the group consisting of titanium, aluminium, stainless steel, bismuth, tin and mixtures of two or more thereof, which is formed by initial deposition of the sacrificial metal and its conversion to oxide. For forming a low emissivity coating with good light transmission, the silver layer is 8 to 12 nm thick. A specific multi-layer low emissivity coating is formed by depositing the following layers, starting from the substrate surface:

Undercoat

3 nm titanium dioxide

20 nm tin oxide (SnO2)

13 nm zinc oxide

Reflective layer

10 nm silver

Overcoat

3.5 nm titanium for conversion to titanium dioxide

22 nm tin oxide

12 nm titanium dioxide.

Claims

1. An article, comprising:

a glazing material coated with a multi-layer coating comprised of a reflective layer of silver sandwiched between a transparent undercoat and a transparent overcoat,

wherein said transparent undercoat is provided on said glazing material and comprises at least one layer of at least one metal oxide selected from the group consisting of tin oxide, titanium dioxide, aluminium oxide, bismuth oxide, and mixtures thereof, over which is deposited a layer of zinc oxide having a thickness not greater than 15 nm, said layer of zinc oxide being in direct contact with said reflective layer of silver, and

wherein said transparent overcoat comprises a layer of an oxide of at least one sacrificial metal selected from the group consisting of titanium, aluminium, stainless steal, bismuth, tin, and mixtures thereof, formed by initial deposition of said at least one sacrificial metal and conversion of said initial deposition of said at least one sacrificial metal to said oxide.

2. The article recited in claim 1, wherein said glazing material is transparent.

3. The article recited in claim 1, wherein said transparent overcoat includes at least one further layer of at least one metal oxide selected from the group consisting of tin oxide, titanium dioxide, aluminium oxide, bismuth oxide, and mixtures thereof, said at least one further layer being deposited after said layer of an oxide of at least one sacrificial metal is deposited.

4. The article recited in claim 1, wherein the article has one face including a peripheral margin and a remainder area, and wherein a strip of adhesive is positioned around the peripheral margin of said one face and said multi-layer coating is provided on said remainder area of said one face.

5. The article recited in claim 1, wherein said layer of silver has a thickness ranging from 24 to 28 nm.

6. The article recited in claim 1, wherein said transparent undercoat and said transparent overcoat each have a total thickness ranging from 30 to 45 nm.

7. The article recited in claim 1 wherein said at least one sacrificial metal is titanium.

8. The article recited in claim 7, wherein said transparent undercoat comprises a first layer of titanium dioxide overcoated by a first layer of tin oxide in turn overcoated by said layer of zinc oxide having a thickness not greater than 15 nm, and wherein said transparent overcoat comprises a layer of titanium dioxide formed by initial deposition of titanium metal and conversion thereof to said oxide, a further layer of tin oxide, and a further layer of titanium dioxide.

9. The article recited in claim 8, wherein said first layer of tin oxide and said further layer of tin oxide each have a thickness ranging from 15 to 25 nm, and wherein said first layer of titanium dioxide and said layer of titanium dioxide have a thickness ranging from 2 to 14 nm.

10. The article recited in claim 1, wherein said layer of zinc oxide has a thickness ranging from 5 to 13 nm.

11. The article recited in claim 10, wherein said layer of zinc oxide has a thickness ranging from 10 to 13 nm.

12. The article recited in claim 1, wherein said layer of silver has a thickness ranging from 1 to 12 nm.

13. The article recited in claim 12, having an emissivity of less the 0.1 at its coated face.

14. The article recited in claim 1, wherein said initial deposition of said at least one sacrificial metal is to a thickness ranging from 2 to 15 nm.

15. The article recited in claim 14, wherein said initial deposition of said at least one sacrificial metal is to a thickness ranging from 2 to 4 nm.