Composite preforms and articles and methods for their manufacture

• US 5,112,545 A
• Filed: 02/14/1990
• Issued: 05/12/1992
• Est. Priority Date: 02/14/1990
• Status: Expired due to Fees

• Current Assignee: Airfoil Textron Incorporated (Textron Inc)
• Original Assignee: Airfoil Textron Incorporated (Textron Inc)
• Inventors: DeGrood, Susan M., Spain, Raymond G.
• Primary Examiner(s): Thibodeau, Paul J.
• Assistant Examiner(s): Weisberger, Richard C.
• Application Number:
  US07/480,061
• Time in Patent Office: 818 Days
• Field of Search: 264/122, 264/109, 264/56, 264/63, 264/257, 264/103, 264/137
• US Class Current: 264/103
• CPC Class Codes: C04B 2235/483 Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes
• CPC Class Codes: C04B 2235/5228 Silica and alumina, including aluminosilicates, e.g. mullite
• CPC Class Codes: C04B 2235/5244 Silicon carbide
• CPC Class Codes: C04B 2235/5252 having a specific pre-form
• CPC Class Codes: C04B 2235/5268 Orientation of the fibers
• CPC Class Codes: C04B 2235/95 Products characterised by their size, e.g. microceramics
• CPC Class Codes: C04B 35/14 based on silica
• CPC Class Codes: C04B 35/6269 Curing of mixtures
• CPC Class Codes: C04B 35/80 Fibres, filaments, whiskers, platelets, or the like
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

A multi-dimensional (e.g., 3D braided) preform formed of reinforcement strands or filaments is rigidized by impregnating the preform with a resin solution (e.g., silicone resin solution), curing the resin to impart a selected shape to the preform and then heating the shaped preform to convert the cured resin to inorganic solids (e.g., silica solids) so dispersed in an effective amount between the strands as to rigidize the preform. The rigidized preform is then infiltrated with an inorganic matrix (e.g., a ceramic material) to form a composite article.

Claims

1. A method of making a preform, comprising:

(a) forming a preform of reinforcement strands,

(b) impregnating the preform with a silicone resin solution comprising silicone solids thermally convertable to silica solids,

(c) curing the resin of the impregnated preform under conditions that a selected shape is imparted to said preform, and

(d) heating the shaped preform at a temperature effective to convert the cured silicone resin to silica solids in sufficient quantity to rigidize the shaped preform to allow subsequent handling and infiltration of the shaped preform with an inorganic matrix material.

2. The method of claim 1 wherein in step (a), the reinforcement strands are braided to form a three-dimensional preform.

3. The method of claim 1 wherein in step (c), the impregnated preform is subjected to pressure during heating to cure the resin.

4. The method of claim 1 wherein in step (d), the silica solids fill between the reinforcement strands without substantially bonding with said reinforcement strands.

5. The method of claim 1 including impregnating the preform in step (b) with a resin solution whose solids content is sufficient to yield at least about 6% by weight of inorganic solids in heat treated preform after step (d).

6. A method of making a reinforced composite article, comprising:

(a) forming a preform of reinforcement strands,

(b) impregnating the preform with a silicone resin solution comprising silicone solids thermally convertable to silica solids,

(c) curing the resin of the impregnated preform under conditions that a selected shape is imparted to said preform,

(d) heating the shaped preform at a temperature effective to convert the cured resin to silica solids in sufficient quantity to rigidize the shaped preform, and

(e) infiltrating the rigidized preform with an inorganic matrix material to form the filamentary reinforced article.

7. The method of claim 6 wherein in step (a), the reinforcement strands are braided to form three-dimensional preform.

8. The method of claim 6 wherein the inorganic matrix material comprises a ceramic material.