Real-time passive detection of humidity using vanillin

• US 5,112,768 A
• Filed: 06/18/1990
• Issued: 05/12/1992
• Est. Priority Date: 06/18/1990
• Status: Expired due to Fees

• Current Assignee: Patricia T. Carver
• Original Assignee: Patricia T. Carver
• Inventors: Carver, Patricia T.
• Primary Examiner(s): Hill, Jr., Robert J.
• Assistant Examiner(s): Chan, William K. Y.
• Application Number:
  US07/539,622
• Time in Patent Office: 694 Days
• Field of Search: 436/139, 436/169, 436/902, 422/56, 422/57, 422/87, 422/82.11, 73/23.2, 73/29.01, 73/29.02, 73/29.04, 252/963, 252/408.1, 116/206, 338/35
• US Class Current: 436/39
• CPC Class Codes: G01N 31/222 for investigating moisture content
• CPC Class Codes: Y10S 252/963 Humidity or moisture indicators
• CPC Class Codes: Y10S 436/902 Dosimeter

Abstract

A method and device involving use of the reaction product of an aldehyde acidified with sulfuric acid in acetone for sensing moisture. The reaction product is used as a coating for colorimetric detection of humidity, the color of the coating changing as a function of the humidity level. The coating is applied to a thin layer chromatography plate which is received in a badge housing to provide a real-time colorimetric dosimeter for monitoring humidity and indicating its presence.

Claims

1. A method for passive colorimetric detection of humidity comprising the steps of:

(a) providing a substrate coated with vanillin acidified with sulfuric acid in acetone; and

(b) exposing said substrate to a humid environment, said substrate changing from a first color to a second color as a function of the humidity to which said substrate has been exposed.

2. A method for passive colorimetric detection of humidity comprising the steps of:

(a) preparing a solution of vanillin that is acidified with sulfuric acid in acetone;

(b) coating a substrate with said solution, said coated substrate characterized by a first color; and

(c) exposing said substrate to a humid environment, said coated substrate changing from said first color to a second color as a function of the level of humidity to which said substrate has been exposed.

3. The method for passive colorimetric detection of humidity as claimed in claim 2 wherein said substrate is an optical wave guide.

4. The method for passive colorimetric detection of humidity as claimed in claim 2 wherein said substrate is a fibre optic probe.

5. The method for passive colorimetric detection of humidity as claimed in claim 2 wherein said substrate is a thin film chromatographic plate.

6. The method for passive colorimetric detection of humidity as claimed in claim 5 wherein said thin film chromatographic plate is a silica gel thin layer chromatographic plate having a plastic backing.

7. The method for passive colorimetric detection of humidity as claimed in claim 5 wherein said thin film chromatographic plate is a silca thin layer chromatographic glass plate.

8. The method as claimed in claim 2 wherein said solution consists essentially of one gram of vanillin, twenty-five milliliters of acetone and five to seven drops of sulfuric acid.

9. A method for passive colorimetric detection of humidity comprising the steps of:

(a) preparing a solution of vanillin that is acidified with sulfuric acid in acetone;

(b) coating a substrate with said solution, said coated substrate changing color as a function of humidity;

(c) exposing said substrate to a humid environment, said coated substrate changing from a first color to a second color as a function of the humidity level to which said substrate has been exposed; and

(d) comparing said second color to a color wheel means for determining the humidity level.

10. The method for passive colorimetric detection of humidity as claimed in claim 9 wherein said substrate is a thin film chromatographic plate.

11. The method for passive colorimetric detection of humidity as claimed in claim 9 wherein said substrate is a silica gel thin film chromatographic plate having a plastic backing.

14. The method for passive colorimetric detection of humidity as claimed in claim 9 wherein said color wheel means includes a plurality of color zones, each said color zone representing a selected level of humidity.

15. The method for passive colorimetric detection of humidity as claimed in claim 9 wherein said color change is reversible.

16. The method for passive colorimetric detection of humidity as claimed in claim 9 wherein said color change is instantaneous and reversible.

17. The method for passive colorimetric detection of humidity as claimed in claim 9 wherein said color is a deep purple in a dry environment and lightens to a bright lime green at high humidity levels.

18. The method as claimed in claim 9 wherein said solution consists essentially of one gram of vanillin, twenty-five milliliters of acetone and five to seven drops of sulfuric acid.

12. The method for passive colorimetric detection of humidity as claimed in 9, wherein said substrate is an optical wave guide.

13. The method for passive colorimetric detection of humidity as claimed in 9, wherein said substrate is an fibre optic probe.