Resin composition

• US 5,112,914 A
• Filed: 01/30/1990
• Issued: 05/12/1992
• Est. Priority Date: 01/30/1989
• Status: Expired due to Fees

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Maruyama, Takashi, Mizuno, Yukio
• Primary Examiner(s): Ziegler, Jacob
• Application Number:
  US07/472,184
• Time in Patent Office: 833 Days
• Field of Search: 525/68, 525/134, 525/396, 525/397, 525/905, 525/393, 525/151
• US Class Current: 525/134
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 61/00 Compositions of condensation polymers of aldehydes or ketones with polyalcohols C08L59/00; with polynitriles C08L77/00; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 61/20 Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen with aminophenols C08L61/04
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 71/126 modified by chemical after-treatment
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

The present invention provides a resin composition excellent in solvent resistance, mechanical properties, heat resistance, and processability which comprises:

100 parts by weight of a composition comprising (A) 5-94 wt % of a modified polyphenylene ether resin and (B) 95-5 wt % of a thermoplastic polyester,

(C) 0-100 parts by weight of a rubber-like polymer, and

(D) 0.01-10 parts by weight of an amino resin obtained by modifying with an alcohol an addition reaction product of formaldehyde and at least one compound selected from the group consisting of melamine, guanamine and urea.

Claims

1. A resin composition which comprises:

100 parts by weight of a composition comprising (A) 5-95 wt.% of a modified polyphenylene ether resin and (B) 95-5 wt% of a thermoplastic polyester, and

(D) 0.01-10 parts by weight of an amino resin obtained by modifying with an alcohol an addition reaction product of formaldehyde and at least one compound selected from the group consisting of melamine, guanamine and urea.

2. A resin composition according to claim 1, wherein the modified polyphenylene ether resin (A) is one which is obtained by modifying polyphenylene ether with a polyfunctional compound (E) which has in its molecule at least one group selected from the group consisting of carboxyl group, acid anhydride group, acid amide group, imide group, carboxylic acid ester group, epoxy group, amino group and hydroxyl group, in the presence or absence of a radical initiator.

3. A resin composition according to claim 2, wherein the polyfunctional compound (E) is a compound (F) which has in its molecule both (a) carbon-carbon double bond or carbon-carbon triple bond and (b) at least one group selected from the group consisting of carboxyl group, acid anhydride group, acid amide group, imide group, carboxylic acid ester group, epoxy group, amino group and hydroxyl group.

4. A resin composition according to claim 2, wherein the polyfunctional compound (E) is a compound (G) selected from the group consisting of an aliphatic carboxylic acid, an acid ester and an acid amide represented by the formula:

(R^I O)mR(COOR^II)n(CONR^III R^IV)s wherein R represents a linear or branched saturated aliphatic hydrocarbon residue having 2-20 carbon atoms;

R^I each independently represents a hydrogen atom or an alkyl, aryl, acyl or carbonyldioxy group having 1-10 carbon atom;

R^II each independently represents a hydrogen atom or an alkyl or aryl group having 1-20 carbon atoms;

R^III and R^IV each independently represent a hydrogen atom or an alkyl or aryl group having 1-10 carbon atoms;

m, n, and s each represent 0 or an integer of 1 or more, and m+n+s≧

2, and a derivative thereof.

5. A resin composition according to claim 2, wherein the polyfunctional compound (E) is a compound (H) which has in its molecule both (a) acid halide group and (b) at least one functional group selected from the group consisting of carboxyl group, acid anhydride group, carboxylic acid ester group and acid amide group.

6. A resin composition according to claim 1, wherein the modified polyphenylene ether resin (A) is one which is obtained by modifying polyphenylene ether with an epoxy compound (J) comprising at least one compound selected from the group consisting of a compound having an oxirane ring in its molecule and a condensation-polymerized product of dihydric phenol and epichlorohydrin, in the presence or absence of a radical initiator.

7. A resin composition according to claim 1, wherein the modified polyphenylene ether resin (A) is one which is obtained by modifying polyphenylene ether with an organosilane compound (K) which has in its molecule simultaneously (a) at least one silicon atom which bonds to a carbon atom through oxygen atom, (b) carbon-carbon double bond or carbon-carbon triple bond and (c) at least one functional group selected from the group consisting of amino group, mercapto group, carboxyl group, acid anhydride group, acid amide group, carboxylic acid ester group, imide group and hydroxyl group, in the presence or absence of a radical initiator.

8. A resin composition according to claim 1, wherein the amino resin (D) is an amino resin represented by the following formula (I), (II) or (III):

##STR8## wherein R₁, R₂, R₃, R₄, R₅ and R₆ each represent a hydrogen atom, an alkyl group, an aryl group or a substituent denoted by the formula (I'"'"');

space="preserve" listing-type="equation">--CH.sub.2 --O) R.sub.7 (I'"'"')

wherein R₇ represents a hydrogen atom or an alkyl or cycloalkyl group of 1-10 carbon atoms, and at least one of R₁ -R₆ is a substituent denoted by the formula (I'"'"'), ##STR9## Wherein R₁₂ represents a hydrogen atom, an alkyl group, an alkoxy group or a aryl group, R₈, R₉, R₁₀ and R₁₁ each represent a hydrogen atom, an alkyl group, an aryl group or a substituent represented by the above-mentioned formula (I'"'"'), and at least one of R₈ -R₁₁ is a substituent represented by the formula (I'"'"'), ##STR10## wherein R₁₃, R₁₄, R₁₅ and R₁₆ each represent a hydrogen atom, an alkyl group, an aryl group or a substituent represented by the above-mentioned formula (I'"'"'), and at least one of R₁₃ -R₁₆ is a substituent represented by the formula (I'"'"').

9. A resin composition according to claim 1 which additionally comprises (M) an aromatic vinyl polymer or a copolymer of an aromatic vinyl compound and an other monomer.