Soil decontamination

• US 5,114,497 A
• Filed: 03/26/1991
• Issued: 05/19/1992
• Est. Priority Date: 03/26/1991
• Status: Expired due to Term

• Current Assignee: Board of Regents of the University of Texas System (University of Texas System)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Johnson, Paul C., Stearns, Stephen M., Deeley, George M., Byers, Dallas L., Colthart, James D., Chou, Charles C., Weingaertner, David A., Marsden, Arnold R. Jr., Otermat, Arthur L.
• Primary Examiner(s): Morris, Theodore
• Assistant Examiner(s): EL ARINI, ZEINAB
• Application Number:
  US07/675,377
• Time in Patent Office: 420 Days
• Field of Search: 166/248, 166/268, 166/272, 166/306, 210/922, 405/128, 405/129, 423/659, 423/DIG. 20, 134/21
• US Class Current: 134/21
• CPC Class Codes: B09C 1/06 thermally
• CPC Class Codes: B09C 2101/00 In situ
• CPC Class Codes: E21B 36/04 using electrical heaters
• CPC Class Codes: E21B 43/295 Gasification of minerals, e.g. for producing mixtures of combustible gases E21B43/243 takes precedence
• CPC Class Codes: Y10S 210/922 Oil spill cleanup, e.g. bacterial

Abstract

An improved process for the remediation of soil contaminated by the presence therein of organic or semi-volatile inorganic contaminants which comprises (1) supplying thermal energy to the soil at one or more locations under the surface of the soil, (2) collecting the vapors resulting from contaminant vaporization or decomposition under the influence of the thermal energy, after passage horizontally through the soil, at one or more locations under the surface of the soil and separating from the collected vapors the environmentally undesirable components thereof.

Claims

1. A process for the remediation of soil containing organic or semi-volatile inorganic contaminants which comprises the steps of:

applying thermal energy to said soil by a heating means;

transferring a portion of said thermal energy to one or more heat transfer means comprising soil-free vertical passages extending downwardly from the surface of said soil from about 1 foot to about 4 feet;

vaporizing a portion of said contaminants;

collecting the vapors resulting from the application of said thermal energy, said collecting being performed by one or more soil-free vertical passages extending upwardly through the soil from below the surface of the soil and removed from said heat transfer passages, said collecting passages operating at reduced pressure;

separating the environmentally undesirable portion of said collected vapors; and

passing the remainder of said collected vapors to the atmosphere at or above the surface of said soil.

2. The process of claim 1 wherein the environmentally unacceptable portion of the vapors are separated from the remainder of the vapors by passage through a scrubber or adsorber or by passage through a decomposition catalyst.

3. The process of claim 1 wherein the heating means is an electrically conductive metal connected to a source of electrical power which supplies electrical energy to the heating means.

4. The process of claim 1 wherein air heated by contact with the heating means is forced into said heat transfer means, the air subsequently flowing horizontally through the soil to the vapor collection means and vertically upward through the vapor collection means and through an opening in the heating means and then to a vapor separation means for separation of the environmentally unacceptable vapors before the remainder of the vapors are released to the atmosphere.

5. An apparatus for remediation of soil contaminated with organic or semi-volatile inorganic contaminants comprising:

heating means placed at the surface of the soil, wherein said heating means comprises an electrically conductive metal connected to a source of electrical power which supplies electrical energy to said heating means;

vapor-impermeable insulation means covering said heating means;

heat transfer means for transferring heat from said heating means to one or more locations below the surface of the soil, wherein said heat transfer means comprises one or more soil-free vertical passages extending downwardly from the surface of the soil from about 1 foot to about 4 feet;

vapor collection means, acting in cooperation with pressure reducing means, for collecting, at reduced pressure and under the surface of the soil, the vapors generated by said heating means, wherein said vapor collection means comprises soil-free vertical passages extending upwardly through the soil from below the surface of the soil; and

separation means to remove from the collected vapors the environmentally undesirable components thereof.

6. The apparatus of claim 5 wherein the separation means comprises a scrubber, an adsorber or a decomposition catalyst.

7. The apparatus of claim 5 which further includes means to force air over the heating means to said heat transfer means.